US3836375A
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TiO{11 {13 P{11 O{11 {13 Na{11 O{13 WO{11 {11 OPTICAL GLASSES AND METHOD
Assignee: Ernst Leitz Wetzlar GmbH
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Filing: 1973-03-26
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Granted: 1974-09-17
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Expires: 1993-03-26
Abstract
Abstract Optical glasses of a high index of refraction ne between 1.74 and 1.90, a high dispersion Nu e between 25 and 17, and a high positive anomalous partial dispersion are prepared. The essential components of the melt mixture are phosphorus compounds, sodium oxide, titanium dioxide, and tungsten oxide. If desired, said essential components have admixed thereto other glass-forming oxides and phosphates.
Inventors
- 👤 H Broemer
- 👤 J Spicic
- 👤 W Huber
- 👤 N Meinert
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 17:34
CPC Classifications
C; C03; C03C; C03C3/00; C03C3/12; C03C3/16; C03C3/21; Y; Y10; Y10S; Y10S501/00; Y10S501/90; Y10S501/901; Y10S501/903
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
96 words
The optical glass of claim 1 additionally containing at least one of the following components: 0 to 5.2 percent, by weight, of lithium oxide, 0 to 10.4 percent, by weight, of potassium oxide, 0 to 6.6 percent, by weight, of magnesium oxide, 0 to 11.3 percent, by weight, of calcium oxide, 0 to 15.6 percent, by weight, of barium oxide, 0 to 12.2 percent, by weight of lead monoxide, 0 to 7.8 percent, by weight, of boron trioxide, 0 to 1.9 percent, by weight, of aluminum oxide, 0 to 21.0 percent, by weight, of niobium pentoxide.
Claim 2
Dependent Claim
63 words
The optical glass of claim 1 being composed of 32.3 percent, by weight, of phosphorus pentoxide, 17.7 percent, by weight, of sodium oxide, 30.0 percent, by weight, of titanium dioxide, and 20.0 percent, by weight, of tungsten oxide, said glass having an ne of 1.8012, a Nu e of 20.8, a Delta Nu e of + 18.7, a specific gravity of 3.33 g./cc.
Claim 3
Dependent Claim
65 words
The optical glass of claim 1 being composed of 32.3 percent, by weight, of phosphorus pentoxide, 17.7 percent, by weight, of sodium oxide, 5.0 percent, by weight, of lead monoxide, 10.0 percent, by weight, of titanium dioxide, 15.0 percent, by weight, of niobium pentoxide, 20.0 percent, by weight, of tungsten trioxide, ne: 1.7447 Nu e: 24.9 Delta Nu e: + 14.7 specific gravity: 3.53 g./cc.
Claim 4
Dependent Claim
65 words
The optical glass of claim 1 being composed of 28.7 percent, by weight, of phosphorus pentoxide, 3.0 percent, by weight, of boron trioxide, 16.3 percent, by weight, of sodium oxide, 19.5 percent, by weight, of titanium dioxide, 15.0 percent, by weight, of niobium pentoxide, 17.5 percent, by weight, of tungsten trioxide, ne: 1.8051 Nu e: 21.6 Delta Nu e: + 21.5 specific gravity: 2.87 g./cc.
Claim 5
Dependent Claim
58 words
The optical glass of claim 1 being composed of 32.3 percent, by weight, of phosphorus pentoxide, 17.7 percent, by weight, of sodium oxide, 30.0 percent, by weight, of titanium dioxide, 7.5 percent, by weight, of niobium pentoxide, 12.5 percent, by weight, of tungsten trioxide, ne: 1.8191 Nu e: 20.4 Delta Nu e: + 15.2 specific gravity: 3.29 g./cc.
Claim 6
Dependent Claim
53 words
The optical glass of claim 1 being composed of 35.7 percent, by weight, of phosphorus pentoxide, 7.7 percent, by weight, of sodium oxide, 6.6 percent, by weight, of magnesium oxide, 30.0 percent, by weight, of titanium dioxide, 20.0 percent, by weight, of tungsten trioxide, ne: 1.8640 Nu e: 19.2 specific gravity: 3.43 g./cc.
Claim 7
Dependent Claim
53 words
The optical glass of claim 1 being composed of 27.0 percent, by weight, of phosphorus pentoxide, 10.8 percent, by weight, of sodium oxide, 12.2 percent, by weight, of lead monoxide, 30.0 percent, by weight, of titanium dioxide, 20.0 percent, by weight, of tungsten trioxide, ne: 1.8975 Nu e: 18.5 specific gravity: 3.72 g./cc.
Claim 8
Dependent Claim
110 words
In a process of producing an optical glass of high index of refraction ne between 1.74 and 1.90, high dispersion Nu e between 25 and 17, and high positive anomalous partial dispersion, said process comprising the step of melting a mixture of glass components consisting of between 35.0 and 50.0 percent, by weight, of sodium metaphosphate, between 0 and 15.0 percent, by weight, of sodium pyrophosphate, between 20.0 and 30.0 percent, by weight, of titanium dioxide, and between 20.0 and 30.0 percent, by weight, of tungsten trioxide at a temperature between about 1,200* C. and about 1,300* C., while stirring, to form a glass melt of the above given composition.
Claim 9
Dependent Claim
274 words
In a process of producing an optical glass of high index of refraction ne between 1.74 and 1.90, high dispersion Nu e between 25 and 17, and high positive anomalous partial dispersion, said process comprising the step of melting a mixture of glass components consisting of between 10.0 and 50.0 percent, by weight, at least one of an alkali metal phosphate compound selected from the group consisting an alkali metal metaphosphate and an alkali metal pyrophosphate with the proviso that the content of lithium metaphosphate, sodium metaphosphate, or potassium metaphosphate is between 0 and 50 percent, by weight; between 10.0 and 30.0 percent, by weight, of titanium dioxide; between 12.5 and 30.0 percent, by weight, of a tungsten compound selected from the group consisting of tungsten trioxide and sodium tungstate with the proviso that the content of sodium tungstate is between 12.5 and 26.3 percent, by weight; between 0 and 40.0 percent, by weight, of a metaphosphate selected from the group consisting of magnesium metaphosphate, calcium metaphosphate, and barium metaphosphate with the proviso that the content of magnesium metaphosphate or barium metaphosphate is between 0 and 30 percent, by weight; between 0 and 10.0 percent, by weight, of aluminum metaphosphate; between 0 and 20.0 percent, by weight, of lead metaphosphate; between 0 and 5.0 percent, by weight, of lead monoxide; between 0 and 21.0 percent, by weight, of niobium pentoxide; between 0 and 5.7 percent, by weight, of boron trioxide; and between 0 and 12.0 percent, by weight, of sodium metaborate at a temperature between about 1,200* C. and about 1,300* C., while stirring, to form a glass melt of the above given composition.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1977-09-16 | 1978-03-18 | 1978-09-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1981-09-16 | 1982-03-18 | 1982-09-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1985-09-16 | 1986-03-18 | 1986-09-17 | $7700.00 | Window Closed / Lapsed |