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US3832411A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for the depolymerization of polytetrafluoroethylene

Assignee: Zeneca Inc
•
Filing: 1971-02-02
•
Granted: 1974-08-27
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Expires: 1991-02-02
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Abstract

Abstract High yield monomeric tetrafluoroethylene may be recovered from polytetrafluoroethylene and polytetrafluoroethylene composites by pyrolyzing the polymer in the presence of high temperature steam. The steam acts as a condensable carrier gas for the low molecular weight pyrolysis products and should be present in an amount such that the mole ratio of steam to pyrolysis products is at least one to one. The steam also acts as a means for heating the polymer to the necessary decomposition temperatures.

Inventors

  • 👤 B Arkles
  • 👤 R Bonnett

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 08:57
CPC Classifications
C; C07; C07C; C07C17/00; C07C17/361; C07C17/367

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 21 words
A method according to claim 1 wherein the polymeric tetrafluoroethylene is heated to a temperature of between about 780*F. and 1,400*F.
Claim 2
Dependent Claim 41 words
A method according to claim 1 wherein the polymeric tetrafluoroethylene is heated to a temperature of between about 800*F. and 1,100*F., and the mole ratio of steam to said pyrolysis products is between about 10 to 1 and 40 to 1.
Claim 3
Dependent Claim 21 words
A method according to claim 1 wherein the polymeric tetrafluoroethylene is heated by steam having a temperature of at least 950*F.
Claim 4
Dependent Claim 85 words
In a method for depolymerizing polymeric tetrafluoroethylene by pyrolysis, the improvement comprising heating polymeric tetrafluoroethylene at a pressure of at least atmospheric pressure and in the presence of high temperature steam sufficient to heat said polymeric tetrafluoroethylene to a temperature of at least about 780* F., said steam being present in an amount such that the mole ratio of steam to pyrolysis products is at least about 4 to 1, condensing the steam froM the mixture of pyrolysis products, and collecting the resulting pyrolysis products.
Claim 5
Dependent Claim 18 words
A method according to claim 5 wherein said steam has a temperature of between about 950*F. and 1,800*F.
Claim 6
Dependent Claim 26 words
A method according to claim 5 wherein the mole ratio of steam to said pyrolysis products is between about 10 to 1 and 40 to 1.
Claim 7
Dependent Claim 15 words
A method according to claim 5 wherein said polymeric tetrafluoroethylene is recycled scrap containing fillers.

References Cited (Backward Citations)

US2394581A Cited
US2406153A Cited
DE1003700B Cited
GB960309A Cited
US3284169A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-08-26 1978-02-25 1978-08-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-08-26 1982-02-25 1982-08-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-08-26 1986-02-25 1986-08-27 $7700.00 Window Closed / Lapsed

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