Bis-quaternary cyclic thiazines

Abstract

Abstract BIS-QUATERNARY CYCLIC THHIAZINES AS ILLUSTRATED BY THE FORMULA BIS(-N(+)(-R'')<(-C(-R)2-C(-R)2-Z-C(-R)2-C(-R)2-))-A- 2X(-) WHERE THE R''S ARE HYDROGEN OR A SUBSTITUTED GROOUP SUCH AS A HYDROCARBON GROUP, I.E., ALKYL, ETC., AND Z IS S, S-> O, O <-S-> O AND X IS AN ANION. THESE COMPOSITIONS MAY BE LINEAR SUCH AS WHERE A IS ALKYLENE, ALKENYLENE, ALKYNYLENE, ARYLENE, ALKARYLENEALKYL, OXYALKYLENE, FOR EXAMPLE AS (CH2)N OR BRANCHED ALKYLENE, 1,4-PHENYLENE, -CH2-1,4-PHENYLENE-CH2- POLYALKYLENE OXIDE SUCH AS -A-(OA)N- FOR EXAMPLE WHERE A IS ALKYLENE DERIVED FROM ETHYLENE, PROPYLENE BUTYLENE, ETC., OXIDES -CH2CH2(O-CH2CH2)N-, ETC., AND R'' IS ALKYL, HYDROXYALKYL, ARYL, CYCLOALKYL, ARALKYL, ETC. IN ADDITION, BOTH A AND R''''S MAY BE PART OF A CYCLIC STRUCTURE, FOR EXAMPLE 1,4-BIS(<(-C(-R)2-C(-R)2-Z-C(-R)2-C(-R)2-))-PIPERAZINE 2+ 2X(-) THESE COMPOSITIONS ARE PREPARED BY REACTING 1 MOLE OF A DI-SECONDARY AMINE SALT WITH 2 MOLE OF A DIVINYL SULFUR COMPOUND. THE PRODUCTS HAVE A WIDE VARIETY OF USES INCLUDING THEIR USE AS MICROBIOCIDES ETC.

Inventors

• 👤 P Quinlan

Bibliographic Details