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US3826074A Expired / Lapsed US ⏱️ 0.0 years remaining

Glass fiber reinforced elastomers

Assignee: Owens Corning
•
Filing: 1972-03-01
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Granted: 1974-07-30
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Expires: 1992-03-01
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Abstract

Abstract This invention is addressed to the treatment of glass fibers for use as reinforcement with elastomeric materials, and particular compositions used in the treatment of glass fibers, wherein the composition contains a resorcinol-aldehyde resin, an incompatible wax and a graft polymer formed of a monomer of vinyl chloride, vinylidene chloride, chloroprene and combinations thereof grafted onto a vinyl pyridine-butadiene-styrene terpolymer backbone.

Inventors

  • 👤 W Uffner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 03:29
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/04; C08J5/06; C08J5/08; C08J2321/00; Y; Y10; Y10S; Y10S57/00; Y10S57/902; Y10T; Y10T428/00; Y10T428/249921; Y10T428/249924; Y10T428/24994; Y10T428/249942; Y10T428/249946; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/2938; Y10T428/2964; Y10T428/31504; Y10T428/31551; Y10T428/31627; Y10T428/31641; Y10T428/31645; Y10T428/31649

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 36 words
A composition as defined in claim 1 wherein the monomer grafted onto the terpolymer is present in an amount sufficient to provide a graft polymer having a chlorine content of 1 to 20 percent by weight.
Claim 2
Dependent Claim 46 words
A composition as defined in claim 1 wherein the components are present within the range of 4 to 8 percent by weight of the resorcinol-aldehyde resin, 35 to 50 parts by weight of the graft polymer and 8 to 20 percent by weight of the wax.
Claim 3
Dependent Claim 20 words
A composition as defined in claim 1 which includes from 1 to 5 parts by weight of an anchoring agent.
Claim 4
Dependent Claim 74 words
A glass fiber bundle comprising a plurality of glass fibers and an impregnant in the bundle, said impregnant comprising 2 to 10 parts by weight of a resorcinol-aldehyde resin, 20 to 60 parts by weight of a graft polymer formed of a monomer selected from the group consisting of vinyl chloride, vinylidene chloride, chloroprene and combinations thereof grafted onto a vinyl pyridine-butadiene-styrene terpolymer, and 5 to 25 parts by weight of an incompatible wax.
Claim 5
Dependent Claim 38 words
A glass fiber bundle as defined in claim 5 wherein the monomer grafted onto the terpolymer is present in an amount sufficient to provide a graft polymer having a chlorine content of 1 to 20 percent by weight.
Claim 6
Dependent Claim 23 words
A glass fiber bundle as defined in claim 5 wherein the impregnant includes 0.1 to 5 parts by weight of an anchoring agent.
Claim 7
Dependent Claim 25 words
A glass fiber bundle as defined in claim 5 wherein the impregnant constitutes from 5 to 30 percent by weight of the glass fiber bundle.
Claim 8
Dependent Claim 27 words
A glass fiber bundle as defined in claim 5 wherein the individual glass fibers forming the bundle have a thin size coating on the individual surfaces thereof.
Claim 9
Dependent Claim 22 words
A glass fiber bundle as defined in claim 5 wherein the bundle is in the form of a strand of glass fibers.
Claim 10
Dependent Claim 26 words
A glass fiber bundle as defined in claim 5 wherein the bundle is in the form of two or more strands of glass fibers plied together.
Claim 11
Dependent Claim 17 words
A glass fiber bundle as defined in claim 11 wherein the strands are plied and twisted together.
Claim 12
Dependent Claim 65 words
Glass fibers having a thin coating thereon, said coating comprising 2 to 10 parts by weight of a resorcinolaldehyde resin, 20 to 60 parts by weight of a graft polymer formed of a monomer selected from the group consisting of vinyl chloride, vinylidene chloride, chloroprene and combinations thereof grafTed onto a vinyl pyridine-butadiene-styrene terpolymer, and 5 to 25 parts by weight of an incompatible wax.
Claim 13
Dependent Claim 36 words
Glass fibers as defined in claim 13 wherein the monomer grafted onto the terpolymer is present in an amount sufficient to provide a graft polymer having a chlorine content of 1 to 20 percent by weight.
Claim 14
Dependent Claim 21 words
Glass fibers as defined in claim 13 wherein the coating includes 0.1 to 5 parts by weight of an anchoring agent.
Claim 15
Dependent Claim 98 words
In a glass fiber-reinforced elastomeric product in which an elastomeric material constitutes a continuous phase in which glass fibers are distributed, the improvement in the bonding relationship of the glass fibers with the elastomeric material comprising a coating on the glass fibers comprising 2 to 10 parts by weight of a resorcinol-aldehyde resin, 20 to 60 parts by weight of a graft polymer formed of a monomer selected from the group consisting of vinyl chloride, vinylidene chloride, chloroprene and combinations thereof grafted onto a vinyl pyridine-butadiene-styrene terpolymer, and 5 to 25 parts by weight of an incompatible wax.
Claim 16
Dependent Claim 37 words
An elastomeric product as defined in claim 16 wherein the monomer grafted onto the terpolymer is present in an amount sufficient to provide a graft polymer having a chlorine content of 1 to 20 percent by weight.
Claim 17
Dependent Claim 15 words
An elastomeric product as defined in claim 16 wherein the coating includes an anchoring agent.
Claim 18
Dependent Claim 33 words
An elastomeric product as defined in claim 16 wherein the glass fibers are distributed in the elastomeric material in the form of individual filaments and the coating is a coating on the filaments.
Claim 19
Dependent Claim 35 words
An elastomeric product as defined in claim 16 wherein the glass fibers are distributed in the elastomeric material in the form of bundles of glass fibers and the coating is an impregnant in the bundle.
Claim 20
Dependent Claim 23 words
An elastomeric product as defined in claim 20 wherein the individual fibers forming the bundles contain a size coating on the surfaces thereof.
Claim 21
Dependent Claim 28 words
An elastomeric product as defined in claim 20 wherein the fiber bundle is in the form of a cord formed of a plurality of strands of glass fibers.
Claim 22
Dependent Claim 19 words
An elastomeric product as defined in claim 22 wherein the strands forming the cords are twisted and plied together.

References Cited (Backward Citations)

US3567671A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-07-29 1978-01-28 1978-07-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-07-29 1982-01-28 1982-07-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-07-29 1986-01-28 1986-07-30 $7700.00 Window Closed / Lapsed

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