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US3821056A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of bonding hydroxyl containing substrates

Assignee: EIDP Inc
•
Filing: 1972-04-07
•
Granted: 1974-06-28
•
Expires: 1992-04-07
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Abstract

Abstract Method of bonding together two substrate surfaces each having a chemical composition containing free hydroxyl groups such as cellulose or fiber glass-reinforced polyester in which (1) each substrate surface is coated with a polyisocyanate such as the reaction product of toluene diisocyanate and trimethylol propane, (2) applying between and in contact with the coated surfaces a layer of thermoplastic adhesive composition comprising thermoplastic segmented copolyester elastomer, and (3) applying heat to the area of the bond.

Inventors

  • 👤 J Reardon

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 12:41
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/12; C08J5/124; C08J5/128; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/28; C08G18/40; C08G18/42; C08G18/4244; C08G18/4247; C08G18/4252; C09; C09J; C09J167/00; C09J167/02; C09J167/025; C09J175/00; C09J175/04; C09J5/00; C09J5/02; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31536; Y10T428/31551; Y10T428/31565

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 61 words
applying between and in contact with the coated surfaces a layer of thermoplastic adhesive composition comprising thermoplastic segmented copolyester elastomer consisting essentially of a multiplicity of recurring short chain ester units and long chain ester units joined through ester linkages, said short chain ester units amounting to 15 to 65 percent by weight of said copolyester and being of the formula
Claim 2
Dependent Claim 12 words
The method of claim 1 in which the substrate surfaces are cellulose.
Claim 3
Dependent Claim 66 words
The method of claim 2 in which the thermoplastic adhesive composition also contains up to 85 percent by weight of low molecular weight thermoplastic resin which forms compatible mixtures with the segmented copolyester, is thermally stable at 150* C., and has a melt viscosity of less than 10,000 centipoises at 200* C., based on the total thermoplastic segmented copolyester elastomer and low molecular weight thermoplastic resin.
Claim 4
Dependent Claim 30 words
applying heat to the area of the bond to cause a thermosetting reaction between the hydroxyl groups of the substrate surfaces and the isocyanate groups of the polyisocyanate reaction product.
Claim 5
Dependent Claim 39 words
The method of claim 3 in which the low molecular weight thermoplastic resin is selected from the group consisting of hydrocarbon resins, bituminous asphalts, coal tar pitches, rosins, phenolic resins, chlorinated aliphatic hydrocarbon waxes, and chlorinated polynuclear aromatic hydrocarbons.
Claim 6
Dependent Claim 54 words
The method claim 4 in which the dicarboxylic acid is aromatic dicarboxylic acid of 8 to 16 carbon atoms, the low molecular weight diol is aliphatic diol of 2 to 8 carbon atoms, and the long chain glycol is poly(alkylene ether) glycol in which the alkylene group is of 2 to 9 carbon atoms.
Claim 7
Dependent Claim 14 words
The method of claim 1 in which the substrate surfaces are fiber glass-reinforced polyester.
Claim 8
Dependent Claim 66 words
The method of claim 6 in which the thermoplastic adhesive composition also contains up to 85 percent by weight of low molecular weight thermoplastic resin which forms compatible mixtures with the segmented copolyester, is thermally stable at 150* C., and has a melt viscosity of less than 10,000 centipoises at 200* C., based on the total thermoplastic segmented copolyester elastomer and low molecular weight thermoplastic resin.
Claim 9
Dependent Claim 39 words
The method of claim 7 in which the low molecular weight thermoplastic resin is selected from the group consisting of hydrocarbon resins, bituminous asphalts, coal tar pitches, rosins, phenolic resins, chlorinated aliphatic hydrocarbon waxes, and chlorinated polynuclear aromatic hydrocarbons.
Claim 10
Dependent Claim 55 words
The method of claim 8 in which the dicarboxylic acid is aromatic dicarboxylic acid of 8 to 16 carbon atoms, the low molecular weight diol is aliphatic diol of 2 to 8 carbon atoms, and the long chain glycol is poly(alkylene ether) glycol in which the alkylene group is of 2 to 9 carbon atoms.
Claim 11
Dependent Claim 19 words
The method of claim 9 in which the polyisocyanate reaction product is derived from toluene diisocyanate and trimethylol propane.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-06-27 1977-12-27 1978-06-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-06-27 1981-12-27 1982-06-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-06-27 1985-12-27 1986-06-28 $7700.00 Window Closed / Lapsed

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