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US3814404A Expired / Lapsed US ⏱️ 0.0 years remaining

Blast furnace and method of operating the same

Assignee: Kaiser Steel Corp
•
Filing: 1972-01-31
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Granted: 1974-06-04
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Expires: 1992-01-31
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Abstract

Abstract A blast furnace of improved and more readily controllable operation which comprises three sets of tuyeres, i.e., the normal or primary tuyeres at the base or melting zone of the furnace, a second set disposed in the bosh or second zone, preferably above the middle thereof and below the mantel, and a third set of tuyeres disposed in a third zone above the bosh zone and preferably just above the mantel. The second and third tuyere sets are used to introduce reducing gas which mixes with that generated in the furnace to create, limit and control the second and third zones. The furnace atmosphere and operation are controlled and temperatures regulated in each zone to improve permeability of the burden, rate and completion of the reduction and smelting of ore to hot metal and improved utilization of the burden coke by controlled introduction of increments of reducing gases into each of the second and third sets of tuyeres and thence to the furnace zones so formed. Means of re-forming offtake stack gases and of generating reducing gas from a low cost source to provide reducing gases for such introduction are associated with the blast furnace in an advantageous embodiment. A method of operation in reducing ores, for example iron ores, and a system for such operation with production of suitable reducing gases are also provided.

Inventors

  • 👤 H Claflin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 19:07
CPC Classifications
C; C21; C21B; C21B5/00; C21B5/001; Y; Y02; Y02P; Y02P10/00; Y02P10/20

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 363 words
Method of reducing iron ores to form metallic iron comprising: a. preparing and introducing a charge of iron oxide-providing material, fluxing agents and coke into the top of a blast furnace having a tertiary zone, a secondary zone and a primary zone wherein combustion occurs; b. passing said charge downwardly through said furnace and through said tertiary zone that comprises a preheating and reducing area of constantly increasing temperature but of less than about 1000*C; c. introducing a controlled flow of a heated gaseous reducing agent into said zone to combine with reducing gases from the secondary and primary zones and to pass up through said zone and into intimate contact with said charge to effect a reduction of the major portion of the iron oxide of the charge and to form carbon oxide and a first mixture of metallic iron, iron oxide, slag, coke and residual charge; d. passing said first mixture downwardly through said furnace to said secondary zone comprising a bosh area, having a temperature of about 1000*C at the top, and having, in the lower portion thereof and adjacent to a primary zone, a consumable carbon grate constantly formed from Coke in said first mixture; e. passing hot combustion gases from said primary zone upwardly into said secondary zone to form molten metal and slag; f. introducing into said secondary zone a heated gaseous reducing agent which combines with the hot combustion gases to reduce their temperature and to assist in reducing additional iron oxide with the formation of carbon oxide; g. passing said molten materials downwardly through said carbon grate into a primary zone that comprises a hearth area in which combustion occurs and which is maintained at a still higher temperature than said secondary zone, injecting a mixture of air and oxygen as an oxidizing gas into said primary zone and bringing said gas into intimate contact with coke from the charge, the adiabatic flame temperature in said zone being at least about 1860*C, forming carbon oxide by combustion and passing said hot combustion gases upwardly through the blast furnace; and h. withdrawing said molten metallic iron and said molten slag from the base of the furnace.
Claim 2
Dependent Claim 363 words
Method of reducing iron ores to form metallic iron comprising: a. preparing and introducing a charge of iron oxide-providing material, fluxing agents and coke into the top of a blast furnace having a tertiary zone, a secondary zone and a primary zone wherein combustion occurs; b. passing said charge downwardly through said furnace and through said tertiary zone that comprises a preheating and reducing area of constantly increasing temperature but of less than about 1000*C; c. introducing a controlled flow of a heated gaseous reducing agent into said zone to combine with reducing gases from the secondary and primary zones and to pass up through said zone and into intimate contact with said charge to effect a reduction of the major portion of the iron oxide of the charge and to form carbon oxide and a first mixture of metallic iron, iron oxide, slag, coke and residual charge; d. passing said first mixture downwardly through said furnace to said secondary zone comprising a bosh area, having a temperature of about 1000*C at the top, and having, in the lower portion thereof and adjacent to a primary zone, a consumable carbon grate constantly formed from Coke in said first mixture; e. passing hot combustion gases from said primary zone upwardly into said secondary zone to form molten metal and slag; f. introducing into said secondary zone a heated gaseous reducing agent which combines with the hot combustion gases to reduce their temperature and to assist in reducing additional iron oxide with the formation of carbon oxide; g. passing said molten materials downwardly through said carbon grate into a primary zone that comprises a hearth area in which combustion occurs and which is maintained at a still higher temperature than said secondary zone, injecting a mixture of air and oxygen as an oxidizing gas into said primary zone and bringing said gas into intimate contact with coke from the charge, the adiabatic flame temperature in said zone being at least about 1860*C, forming carbon oxide by combustion and passing said hot combustion gases upwardly through the blast furnace; and h. withdrawing said molten metallic iron and said molten slag from the base of the furnace.
Claim 3
Dependent Claim 371 words
Method of operating a blast furnace to form metallic iron comprising: a. charging into the top of said blast furnace a burden comprising iron ore, sinter, pellets or other material with a metallic content, limestone or other fluxes and coke; b. passing said burden downwardly through a preliminary preheating and reducing zone in said furnace of constantly increasing temperature; c. constantly controlling the temperature of the zone by selectively introducing adjacent the lower end of said zone a flow of a heated gaseous carbonaceous reducing agent and blending said agent with the stream of heated gas moving up through said zone, bringing said now blended stream into intimate contact with said burden and reacting said gaseous agent and said burden to preheat and reduce the major portion of said iron ore to form metallic iron and a gaseous product and a first solids mixture of metallic iron, coke, slag and residual charge without causing a solution loss and without premature melting of the burden materials; d. passing said first mixture further downwardly through a second zone in said furnace that comprises a bosh area, having in the lower portion thereof and adjacent said primary zone a consumable carbon grate constantly formed from coke in said first mixture; e. passing hot combustion gases from said primary zone upwardly into said secondary zone to form molten metal and slag; f. introducing into said secondary zone a heated carbonaceous reducing agent which combines with the hot combustion gases to reduce their temperature and to assist in reducing additional iron oxide; g. passing said molten materials downwardly through said carbon grate into a primary zone that comprises a hearth area in which combustion occurs and which is maintained at a still higher temperature than said secondary zone, injecting a mixture of air and oxygen as an oxidizing gas into said primary zone and bringing said gas into intimate contact with coke from the charge, the adiabatic flame temperature in said zone being at least about 1860*C, forming carbon oxide by combustion and passing said hot combustion gases upwardly through the blast furnace; h. separately recovering molten metallic iron and molten slag; and withdrawing exhaust gases containing CO2 and H2O from the top of said furnace.
Claim 4
Dependent Claim 371 words
Method of operating a blast furnace to form metallic iron comprising: a. charging into the top of said blast furnace a burden comprising iron ore, sinter, pellets or other material with a metallic content, limestone or other fluxes and coke; b. passing said burden downwardly through a preliminary preheating and reducing zone in said furnace of constantly increasing temperature; c. constantly controlling the temperature of the zone by selectively introducing adjacent the lower end of said zone a flow of a heated gaseous carbonaceous reducing agent and blending said agent with the stream of heated gas moving up through said zone, bringing said now blended stream into intimate contact with said burden and reacting said gaseous agent and said burden to preheat and reduce the major portion of said iron ore to form metallic iron and a gaseous product and a first solids mixture of metallic iron, coke, slag and residual charge without causing a solution loss and without premature melting of the burden materials; d. passing said first mixture further downwardly through a second zone in said furnace that comprises a bosh area, having in the lower portion thereof and adjacent said primary zone a consumable carbon grate constantly formed from coke in said first mixture; e. passing hot combustion gases from said primary zone upwardly into said secondary zone to form molten metal and slag; f. introducing into said secondary zone a heated carbonaceous reducing agent which combines with the hot combustion gases to reduce their temperature and to assist in reducing additional iron oxide; g. passing said molten materials downwardly through said carbon grate into a primary zone that comprises a hearth area in which combustion occurs and which is maintained at a still higher temperature than said secondary zone, injecting a mixture of air and oxygen as an oxidizing gas into said primary zone and bringing said gas into intimate contact with coke from the charge, the adiabatic flame temperature in said zone being at least about 1860*C, forming carbon oxide by combustion and passing said hot combustion gases upwardly through the blast furnace; h. separately recovering molten metallic iron and molten slag; and withdrawing exhaust gases containing CO2 and H2O from the top of said furnace.
Claim 5
Dependent Claim 58 words
A method as set forth in claim 2 wherein the temperature in said preliminary reducing and preheating zone is controlled to avoid solution loss and premature melting and does not exceed 1000*C., the temperature in said bosh area is at least 1000*C., and there is developed in said primary zone an adiabatic flame temperature of at least 1860*C.
Claim 6
Dependent Claim 23 words
A method as set forth in claim 2 wherein there are developed adiabatic flame temperatures of at least 1860*C. in said primary zone.
Claim 7
Dependent Claim 23 words
A method as set forth in claim 2 wherein said oxidizing gas in Oxygen-enriched air containing at least about 25 percent added oxygen.
Claim 8
Dependent Claim 22 words
A method as set forth in claim 2 wherein said gaseous reducing agent consists essentially of an admixture of CO and H2.
Claim 9
Dependent Claim 48 words
A method as set forth in claim 2 wherein a portion of said gases withdrawn from the top of said furnace are reacted with a carbonaceous reducing agent to re-form carbon monoxide and hydrogen and said re-formed gases are recycled to said zones as said gaseous reducing agent.
Claim 10
Independent Claim 200 words
A system for reducing iron ores to form metallic iron and gaseous products of reduction including carbon dioxide and water comprising a modified blast furnace including a primary set of tuyeres disposed in the hearth zone of said furnace, a secondary set of tuyeres disposed around the upper portion of the bosh zone of said furnace and a tertiary set of tuyeres disposed around the upper portion of said furnace near the base of its reducing zone, means for introducing a gaseous reducing agent into said secondary and said tertiary sets of tuyeres, means for separately withdrawing top gases, molten iron products and molten slag from said blast furnace, a gas converter having means to hold a bed of hot solid carbonaceous reducing agent and means to draw off molten materials from said converter, means for withdrawing a portion of the gaseous products of reduction from said blast furnace and for conducting said products to said converter for direct contact with said carbonaceous reducing agent, means for withdrawing gases from said gas converter and means for introducing such withdrawn gases into each tuyere of said secondary and tertiary sets of blast furnace tuyeres as gaseous reducing and process control agents.
Claim 11
Independent Claim 200 words
A system for reducing iron ores to form metallic iron and gaseous products of reduction including carbon dioxide and water comprising a modified blast furnace including a primary set of tuyeres disposed in the hearth zone of said furnace, a secondary set of tuyeres disposed around the upper portion of the bosh zone of said furnace and a tertiary set of tuyeres disposed around the upper portion of said furnace near the base of its reducing zone, means for introducing a gaseous reducing agent into said secondary and said tertiary sets of tuyeres, means for separately withdrawing top gases, molten iron products and molten slag from said blast furnace, a gas converter having means to hold a bed of hot solid carbonaceous reducing agent and means to draw off molten materials from said converter, means for withdrawing a portion of the gaseous products of reduction from said blast furnace and for conducting said products to said converter for direct contact with said carbonaceous reducing agent, means for withdrawing gases from said gas converter and means for introducing such withdrawn gases into each tuyere of said secondary and tertiary sets of blast furnace tuyeres as gaseous reducing and process control agents.
Claim 12
Dependent Claim 29 words
The system as in claim 8 wherein separate means are provided for each of said secondary and said tertiary sets of tuyeres for introducing gaseous reducing agents thereinto separately.
Claim 13
Dependent Claim 25 words
A system as in claim 8 wherein said secondary set of tuyeres is disposed adjacent the top of said bosh zone and below the mantel.
Claim 14
Dependent Claim 33 words
A system as in claim 8 wherein said converter has a plurality of gas tuyeres and includes means to conduct said top gases to said gas converter and through each gas converter tuyere.
Claim 15
Dependent Claim 27 words
A system as in claim 8 including means to conduct gases from said gas converter to each tuyere of said secondary and said tertiary sets of tuyeres.
Claim 16
Dependent Claim 25 words
A system as set forth in claim 8, including means for supplying CO and other basic oxygen steel furnace gas constituents to said gas converter.
Claim 17
Dependent Claim 19 words
A system as set forth in claim 8 wherein said last mentioned means comprises a basic oxygen steel furnace.
Claim 18
Dependent Claim 17 words
A system as set forth in claim 8 wherein said gas converter comprises a blast furnace-like device.

References Cited (Backward Citations)

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US2420398A Cited
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US2952533A Cited
US2811435A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-06-03 1977-12-03 1978-06-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-06-03 1981-12-03 1982-06-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-06-03 1985-12-03 1986-06-04 $7700.00 Window Closed / Lapsed

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