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US3812653A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for reducing the arsenic content of gaseous hydrocarbon streams by use of supported copper or copper oxide

Assignee: Chevron USA Inc
•
Filing: 1972-04-27
•
Granted: 1974-05-28
•
Expires: 1992-04-27
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Abstract

Abstract A process for reducing the arsenic content of a gaseous hydrocarbon stream by contacting the stream with a sorbent comprising copper or an oxide of copper dispersed upon a supporting material.

Inventors

  • 👤 F Massoth
  • 👤 J Young

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 07:42
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; C; C07; C07C; C07C7/00; C07C7/148

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 25 words
A process as recited in claim 1 wherein said supporting material is a refractory metal oxide having a surface area of greater than 50 m2/g.
Claim 2
Dependent Claim 22 words
A process as recited in claim 2 wherein said hydrocarbons in said feedstream have from one to five carbon atoms per molecule.
Claim 3
Dependent Claim 22 words
A process as recited in claim 3 wherein said hydrocarbon feedstream includes olefins and water vapor and is substantially free of acetylenes.
Claim 4
Dependent Claim 22 words
A process as recited in claim 4 wherein said contacting takes place at a temperature in the range of 50*F. to 400*F.
Claim 5
Dependent Claim 74 words
A process for reducing the arsenic content of a gaseous hydrocarbon feedstream having greater than 20 ppb of arsenic to produce a product having less than 10 ppb of arsenic which comprises contacting said feedstream with a sorbent dispersed on a refractory metal oxide having a surface area of greater than 50 m2/g, said sorbent consisting essentially of copper or an oxide of copper and having an oxygen uptake value of at least 20.
Claim 6
Dependent Claim 22 words
A process as recited in claim 6 wherein said hydrocarbons in said feedstream have from one to five carbon atoms per molecule.
Claim 7
Dependent Claim 22 words
A process as recited in claim 7 wherein said contacting takes place at a temperature in the range of 80*F. to 250*F.
Claim 8
Dependent Claim 22 words
A process in accordance with claim 1 wherein said sorbent consists of copper having an oxygen uptake value of at least 40.
Claim 9
Dependent Claim 23 words
A process as recited in claim 9 wherein said supporting material is an alumina having a surface area of greater than 50 m2/g.
Claim 10
Dependent Claim 22 words
A process as recited in claim 10 wherein said hydrocarbons in said feedstream have from one to five carbon atoms per molecule.
Claim 11
Dependent Claim 25 words
A process in accordance with claim 1 wherein said sorbent consists of an oxide of copper having an oxygen uptake value of at least 40.
Claim 12
Dependent Claim 23 words
A process as recited in claim 12 wherein said supporting material is an alumina having a surface area of greater than 50 m2/g.
Claim 13
Dependent Claim 22 words
A process as recited in claim 13 wherein said hydrocarbons in said feedstream have from one to five carbon atoms per molecule.
Claim 14
Dependent Claim 89 words
A process for reducing the arsenic content of a gaseous hydrocarbon feedstream containing arsenic in amounts in excess of 20 ppb and being substantially free of acetylenes to produce a product having less than 10 ppb of arsenic, which process comprises contacting said feedstream with a sorbent dispersed on a supporting material, said sorbent consisting of copper or an oxide of copper and having an oxygen uptake value of at least 20. 16 A process as recited in claim 15 wherein said hydrocarbon feedstream includes olefins and water vapor.
Claim 15
Dependent Claim 23 words
A process as recited in claim 16 wherein said supporting material is an alumina having a surface area of greater than 50 m2/g.

References Cited (Backward Citations)

US2779715A Cited
US2781297A Cited
US3501897A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-05-27 1977-11-26 1978-05-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-05-27 1981-11-26 1982-05-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-05-27 1985-11-26 1986-05-28 $7700.00 Window Closed / Lapsed

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