Abstract A p-n junction laser device having a central lasing region paralleled by p-type regions which serve to suppress transverse lasing modes is prepared from an n-type gallium arsenide crystal by the selective diffusion of zinc, employing a three-layer masking system. The first layer is phosphorus-doped SiO2, substantially impermeable to zinc, patterned to preserve n-type conductivity between the mode-suppressing regions and the central p-type region. The second and third masking layers are SiO2 patterned to reduce excessive build-up of dopant concentrations at the semiconductor surface, and to control the diffusion rates so that the mode-suppressing regions are diffused deeper than the central p-type region.
A method as defined by claim 1 wherein said semiconductor crystal is selected from the group consisting of gallium arsenide, gallium antimonide, indium phosphide, indium arsenide, indium antimonide, and mixed crystals including any two of said compounds.
Claim 2
Dependent Claim
24 words
A method as defined by claim 1 wherein step (b) includes exposure of said masked crystal to a vaporous mixture of ZnAs2 and Ga2S3.
Claim 3
Independent Claim
227 words
A method for the fabrication of a p-n junction device comprising: a. depositing a first diffusion masking layer, substantially impermeable to a selected conductivity type producing impurity, on a surface of a direct band gap semiconductor crystal of opposite conductivity type; b. selectively removing a portion of said first masking layer to leave on said crystal a substantially parallel pair of masking strips; c. depositing a second diffusion masking layer on said crystal surface and on said strips; d. selectively removing a portion of said second masking layer to leave on said crystal a layer covering said elongated strips and covering at least a portion of the area of said crystal surface lying between said strips; e. depositing a third diffusion masking layer on said crystal surface covering said second masking layer and covering at least a portion of the remainder of said crystal surface; and f. exposing said crystal to said selected impurity, at diffusion conditions, whereby selective diffusion of said impurity into said crystal occurs through said second and third masking layers, but not through said first masking layer, and at a relatively greater rate into the regions of said crystal covered by said third masking layer only than into the region covered by both said second and third masking layers, thereby forming a relatively shallow p-n junction spaced between two relatively deeper p-n junctions.
Claim 4
Dependent Claim
30 words
A method as defined by claim 4 wherein said crystal is of n-type conductivity, said first masking layer is phosphorus-doped SiO2, and said impurity is Zn or a compound thereof.
Claim 5
Dependent Claim
40 words
A method as defined by claim 5 wherein said phosphorus-doped SiO2 layer is deposited to a thickness of at least 2,000 angstroms, and said second and third masking layers are SiO2 having a thickness of about 200 to 500 angstroms.
Claim 6
Dependent Claim
15 words
A method as defined by claim 6 wherein the diffusion source includes ZnAs2 plus Ga2S3.