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US3793015A Expired / Lapsed US ⏱️ 0.0 years remaining

Dispersion of particles in an organic liquid

Assignee: Agfa Gevaert NV
•
Filing: 1971-04-02
•
Granted: 1974-02-19
•
Expires: 1991-04-02
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Abstract

Abstract A developing liquid for developing electrostatic images in electrophotographic reproduction in which electrostatically attractable pigment particles are dispersed in a non-polar, substantially water-immiscible organic liquid using as the dispersion assistant a bivalent or trivalent metal salt of a phosphorus oxyacid containing at least one organic residue having four or more carbon atoms. Preferred metal cations of the salt are zinc, cadmium, copper, aluminum and iron. The organic residue can be an aliphatic radical with a branched structure being preferred, and from 10 to 18 carbon atoms is an optimum range.

Inventors

  • 👤 B Tavernier
  • 👤 A Poot
  • 👤 Engeland J Van
  • 👤 Volder N De

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 12:22
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/12; G03G9/135; G03G9/1355

Claims Analysis

Total Claims: 31
Claim 1
Independent Claim 39 words
The method of claim 1 wherein a resin binding agent is incorporated in said developer dispersion and said phosphorus oxyacid salt is used in a ratio of about 10-200 mg per g. of said pigment particles to be dispersed.
Claim 2
Dependent Claim 1 words
MeII(RPO4)
Claim 3
Dependent Claim 11 words
MeIII(R2PO2)3, and D. Esters of phosphonates having any of the formulae:
Claim 4
Dependent Claim 26 words
MeIII(R2PO3)3 wherein: MeII is a bivalent metal cation, MeIII is a trivalent metal cation, and R is an organic radical containing at least four carbon atoms.
Claim 5
Dependent Claim 1 words
MeII(RHPO3)2
Claim 6
Dependent Claim 1 words
Me2III(RPO3)3
Claim 7
Dependent Claim 1 words
MeII(RHPO4)2
Claim 8
Dependent Claim 39 words
The method of claim 1 wherein said phosphorus oxyacid salt also functions as the essential binder agent for the particles and is used in a ratio of about 500-5000 mg. per g. of said pigment particles to be dispersed.
Claim 9
Dependent Claim 28 words
The method of claim 1 wherein said liquid developer dispersion has incorporated therein a polarity control agent to adjust the magnitude of the charge of said charged partIcles.
Claim 10
Dependent Claim 1 words
MeII(R2PO4)2
Claim 11
Dependent Claim 8 words
MeIII(RHPO3)3 C. Phosphinates having any of the formulae:
Claim 12
Dependent Claim 1 words
MeII(R2P2O7)
Claim 13
Dependent Claim 23 words
The method of claim 1 wherein said organic residue of said phosphorus oxyacid salt has a branched structure containing about 10-18 carbon atoms.
Claim 14
Dependent Claim 94 words
A liquid electrophoretic developer dispersion for the development of electrostatic images consisting essentially of a nonpolar organic liquid hydrocarbon substantially immiscible with water and having a boiling point within the range of about 150*-220*C, and positively charged electrostatically attractable finely divided particles dispersed in said liquid in the amount of about 0.1-1 gm/liter and having absorbed thereon as a dispersing agent for conferring said positive charge to said particles a bivalent or trivalent metal salt of an oxyacid derived from phosphorus containing at least one organic residue having at least about four carbon atoms.
Claim 15
Dependent Claim 1 words
MeIII(RPO3)3
Claim 16
Dependent Claim 1 words
Me2III(RPO4)3
Claim 17
Dependent Claim 29 words
A developer dispersion according to claim 6 wherein the said composition also contains a control agent which adjusts the magnitude of the charge on the dispersed positively charged particles.
Claim 18
Dependent Claim 78 words
A liquid developer dispersion according to claim 6 wherein the said metal salt is a salt of: a. a monoester or diester of an oxyacid derived from phosphorus, b. an oxyacid derived from phosphorus and containing one or two of said organic radicals linked to the phosphorus atom with a carbon atoms, or c. an oxyacid derived from phosphorus and containing an ester group and said organic radical is linked with a carbon atom to the phosphorus atom.
Claim 19
Dependent Claim 1 words
MeIII(RHPO4)3
Claim 20
Dependent Claim 1 words
MeIII(R2PO4)3
Claim 21
Dependent Claim 20 words
A developer dispersion according to claim 6 wherein the said salt is a zinc, cadmium, copper, aluminum or iron salt.
Claim 22
Dependent Claim 22 words
A developer dispersion according to claim 6 wherein the salt comprises at least one organic residue containing 10 to 18 carbon atoms.
Claim 23
Dependent Claim 8 words
Me2III(R2P2O7)3 B. Phosphonates having any of the formulae:
Claim 24
Dependent Claim 15 words
A developer dispersion according to claim 6 wherein the organic residue has a branched structure.
Claim 25
Dependent Claim 25 words
A developer dispersion according to claim 6 wherein the organic residue is an aliphatic radical having a branched structure or substituted with an hydrophobic radical.
Claim 26
Dependent Claim 26 words
A developer dispersion according to claim 6 wherein the non-polar organic liquid is a mixture of aliphatic hydrocarbons containing only a minor amount of aromatic hydrocarbons.
Claim 27
Dependent Claim 18 words
A developer dispersion according to claim 6 wherein the positively charged particles also include a resin fixing agent.
Claim 28
Dependent Claim 16 words
A developer dispersion according to claim 6 wherein the said particles are positively charged carbon particles.
Claim 29
Dependent Claim 31 words
A developer dispersion according to claim 6 wherein the bivalent or trivalent salt is one selected from the group consisting of: A. hypo-, ortho-, and pyrophosphates having any of the formulae:
Claim 30
Dependent Claim 16 words
A developer dispersion according to Claim 6 wherein the bivalent metal salt is zinc monotridecyl phosphate.
Claim 31
Dependent Claim 15 words
A developer dispersion according to claim 6 wherein the bivalent metal salt is zinc(2-butyl)-octyl phosphate.

References Cited (Backward Citations)

US2228671A Cited
US2228659A Cited
US2616904A Cited
US3402188A Cited
US3484505A Cited
US3362907A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-02-18 1977-08-20 1978-02-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-02-18 1981-08-20 1982-02-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-02-18 1985-08-20 1986-02-19 $7700.00 Window Closed / Lapsed

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