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US3791914A Expired / Lapsed US ⏱️ 0.0 years remaining

Laminated glass articles

Assignee: PPG Industries Inc
•
Filing: 1972-01-26
•
Granted: 1974-02-12
•
Expires: 1992-01-26
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Abstract

Abstract This invention relates to polyurethane resins having reduced adhesion to other materials. It particularly pertains to polyurethane interlayers, especially interlayers utilized in laminated safety glass articles. More particularly, this invention relates to polyurethane compositions comprising the reaction product of an organic polyisocyanate and an organic polyol which has reduced adhesion to other materials due to the inclusion therein of a proton containing compound of phosphorus, preferably acid organic phosphorus compounds.

Inventors

  • 👤 V Ammons
  • 👤 M Dufala

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 13:48
CPC Classifications
B; B32; B32B; B32B17/00; B32B17/06; B32B17/10; B32B17/10005; B32B17/1055; B32B17/1077; B32B17/10688; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31598; Y10T428/31601

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 28 words
The laminated window of claim 1 wherein the alkyl acid phosphorus ester has a molecular weight of less than about 1,000 per acid hydrogen present in the ester.
Claim 2
Dependent Claim 19 words
The laminated window of claim 1 wherein the alkyl acid phosphorus ester has an acid number above about 50.
Claim 3
Dependent Claim 17 words
The laminated window of claim 1 wherein the alkyl acid phosphorus ester is an alkyl acid phosphate.
Claim 4
Dependent Claim 15 words
The laminated window of claim 4 wherein the alkyl acid phosphate is methyl acid phosphate.
Claim 5
Dependent Claim 17 words
The laminated window of claim 1, wherein the alkyl acid phosphorus ester is an alkyl acid phosphite.
Claim 6
Dependent Claim 148 words
A safety glass laminate of a plurality of solid glass sheets having disposed between adjacent sheets an adherent, transparent, solid interlayer material bonding said sheets of glass together, said interlayer material comprising a polyurethane resin derived from an organic polyisocyanAte and an organic polyol, and containing about 0.01 to about 3.0 per cent by weight of an alkyl acid phosphorus ester; said percentage of alkyl acid phosphorus ester being sufficient to reduce the normal adhesiveness of the polyurethane to glass in the laminated glass window and to increase its impact resistance such that when the polyurethane is adhered to and sandwiched between two 1/8-inch thick, 12 by 12-inch glass sheets to form a laminate, and the laminate is held rigid and the polyurethane layer is approximately 0.030 inch thick the laminate retains a 5 pound steel ball dropped perpendicularly from a distance greater than 17 feet at 76*F.
Claim 7
Dependent Claim 29 words
The safety glass laminate of claim 7 wherein the alkyl acid phosphorus ester has a molecular weight of less than about 1,000 per acid hydrogen present in the ester.
Claim 8
Dependent Claim 19 words
The safety-glass laminate of claim 7 wherein the alkyl acid phosphorus ester has an acid number above about 50.
Claim 9
Dependent Claim 18 words
The safety glass laminate of claim 7 wherein the alkyl acid phosphorus ester is an alkyl acid phosphate.
Claim 10
Dependent Claim 18 words
The safety glass laminate of claim 7 wherein the alkyl acid phosphorus ester is an alkyl acid phosphite.
Claim 11
Dependent Claim 15 words
The safety glass laminate of claim 10 wherein the alkyl phosphate is stearyl acid phosphate.
Claim 12
Dependent Claim 15 words
The safety glass laminate of claim 10 wherein the alkyl phosphate is octylphenyl acid phosphate.
Claim 13
Dependent Claim 15 words
The safety glass laminate of claim 10 wherein the alkyl phosphate is isooctyl acid phosphate.
Claim 14
Dependent Claim 15 words
The safety glass laminate of claim 10 wherein the alkyl phosphate is methyl acid phosphate.
Claim 15
Dependent Claim 15 words
The safety glass laminate of claim 10 wherein the alkyl phosphate is butyl acid phosphate.
Claim 16
Dependent Claim 16 words
The safety glass laminate of claim 10 wherein the alkyl acid phosphate is lauryl acid phosphate.
Claim 17
Dependent Claim 16 words
The safety glass laminate of claim 4 wherein the alkyl acid phosphate is lauryl acid phosphate.

References Cited (Backward Citations)

US2836575A Cited
US2864780A Cited
GB873697A Cited
GB919067A Cited
US3179625A Cited
US3214394A Cited
US3214395A Cited
US3214396A Cited
US3468819A Cited
US3509015A Cited
US3505160A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-02-11 1977-08-13 1978-02-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-02-11 1981-08-13 1982-02-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-02-11 1985-08-13 1986-02-12 $7700.00 Window Closed / Lapsed

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