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US3791446A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for stimulating well production

Assignee: Texaco Inc
•
Filing: 1971-06-25
•
Granted: 1974-02-12
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Expires: 1991-06-25
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Abstract

Abstract The production of hydrocarbons from a subterranean hydrocarbonbearing formation containing acid-soluble components, such as one composed at least in part of dolomite or limestone, is stimulated by injecting into the formation a composition comprising an aqueous solution of a mineral acid having dissolved therein a vinylpyrrolidone polymer. The increase in the permeability and porosity of the formation achieved utilizing the method of invention results in a substantial improvement in hydrocarbon recovery.

Inventors

  • 👤 J Tate

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 16:14
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/60; C09K8/62; C09K8/72; C09K8/74; C09K8/84; C09K8/86; C09K8/88; C09K8/882; Y; Y10; Y10S; Y10S507/00; Y10S507/933

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 13 words
The method of claim 1, wherein the said formation is a hydrocarbon-bearing formation.
Claim 2
Dependent Claim 38 words
The method of claim 1, wherein the said composition is injected down the well bore penetrating said formation under a pressure greater than the formation pressure but less than the pressure required to create fractures in the formation.
Claim 3
Independent Claim 113 words
A method of increasing the production of fluids from a subterranean fluid bearing formation having present therein acid-soluble components and being without water-sensitive shales or clays comprising injecting down the well bore penetrating said formation and injecting therefrom into said formation under a pressure greater than the formation pressure an aqueous well acidizing composition comprising an aqueous solution of a mineral acid having dissolved therein a vinylpyrrolidone polymer present in a concentration of from about 0.1 to about 10 percent by weight, the said acid being present in an amount capable of reacting with the acid-soluble components of a subterranean fluid-bearing formation and wherein the said polymer comprises recurring units of the formula:
Claim 4
Independent Claim 139 words
A method of increasing the production of fluids from a subterranean calcareous fluid-bearing formation having present therein acid-soluble components and being without water-sensitive shales or clays comprising injecting down the well bore penetrating said formation and injecting therefrom into said formation under a pressure greater than the formation pressure an aqueous well acidizing composition comprising about 3 to about 30 percent by weight of hydrochloric acid having dissolved therein from about 0.1 to about 10 percent by weight based on the total weight of the composition of polyvinylpyrrolidone having an average molecular weight of about 100,000 to about 400,000, maintaining said composition in contact with the formation for a time sufficient for the acid to chemically react with the acid-soluble components of the formation to etch passageways therethrough thereby increasing substantially the flow capacity of the said subterranean formation.
Claim 5
Independent Claim 139 words
A method of increasing the production of fluids from a subterranean limestone fluid-bearing formation having present therein acid-soluble components and being without water-sensitive shales or clays comprising injecting down the well bore penetrating said formation and injecting therefrom into said formation under a pressure greater than the formation pressure an aqueous well acidizing composition comprising about 3 to about 30 percent by weight of hydrochloric acid having dissolved therein from about 0.1 to about 10 percent by weight based on the total weight of the composition of polyvinylpyrrolidone having an average molecular weight of about 100,000 to about 400,000, maintaining said composition in contact with the formation for a time sufficient for the acid to chemically react with the acid-soluble components of the formation to etch passageways therethrough thereby increasing substantially the flow capacity of the said subterranean formation.

References Cited (Backward Citations)

US2763326A Cited
US3179171A Cited
US3252904A Cited
US3294729A Cited
US3294765A Cited
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US3434971A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-02-11 1977-08-13 1978-02-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-02-11 1981-08-13 1982-02-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-02-11 1985-08-13 1986-02-12 $7700.00 Window Closed / Lapsed

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