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US3787307A Expired / Lapsed US ⏱️ 0.0 years remaining

Sensing element to sense ions in liquids

Assignee: Pfaudler GmbH
•
Filing: 1971-10-13
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Granted: 1974-01-22
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Expires: 1991-10-13
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Abstract

Abstract A mechanically stable, solid, rod-like metallic carrier body has a base enamel layer fused thereover, on a portion of which a glass electrode is fused as a top cover; a top enamel layer is fused to the remainder of the base enamel layer, the base enamel layer can be of sufficient conductivity so that an electric potential can be sensed from the metallic body, or an electrical conductor, in contact with the glass, which can be fused between the enamel layers. A plurality of glass electrodes, of different response to ions can be placed on the same enameled metal carrier and separately connected to sensing apparatus.

Inventors

  • 👤 A Schwab
  • 👤 R Ehret

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 04:56
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/28; G01N27/30; G01N27/36

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 41 words
Element according to claim 1, wherein the base enamel layer (2) is essentially electrically insulating; and said electrical conductive means comprises an electrical conductor (5, 6) melted into the enamel layers (2, 3) and in contact with the glass electrode (4).
Claim 2
Dependent Claim 18 words
Element according to claim 2, wherein said metallic carrier body is electrically grounded to form an electrical shield.
Claim 3
Dependent Claim 24 words
Element according to claim 1, wherein a plurality of glass electrodes (4) are fused to the base enamel layer (2) insulated from each other.
Claim 4
Dependent Claim 35 words
Element according to claim 4, wherein said electrical conductive means comprises a plurality of electrical conductors (5, 6) melted into the enamel layers, one conductor each being in electrical contact with a glass electrode (4).
Claim 5
Dependent Claim 36 words
Element according to claim 4, wherein the base enamel layer (2) is essentially electrically insulating; and the electrically conductive means (5, 6) are in contact with the electrodes and accessible from outside of the sensing element.
Claim 6
Dependent Claim 67 words
Element according to claim 4, including means forming a chamber (9a) having a diaphragm (11) at least in part defining a limit of the chamber, the diaphragm (11) separating the inside of the chamber (9a) from the liquid (10), the ions of which are to be sensed; a reference liquid (9) in the chamber; and one of the electrodes (4) being in contact with the reference liquid.
Claim 7
Dependent Claim 49 words
Element according to claim 1, wherein the enamel glass of the electrode (4) comprises SiO2 - 60 - 75 Mol percent; Na2O - 15 - 25 Mol percent; CaO - 5 - 15 Mol percent; Li2O - 0 - 5 Mol percent; ZnO - 0 - 2 Mol percent.
Claim 8
Dependent Claim 49 words
Element according to claim 1, wherein the enamel glass of the electrode (4) comprises SiO2 - 60 - 75 Mol percent; Na2O - 10 - 25 Mol percent; CaO - 0 - 3 Mol percent; B2O3 - 0 - 15 Mol percent; A12O3 - 0 - 12 Mol percent.
Claim 9
Dependent Claim 35 words
Element according to claim 1, wherein the base enamel layer (2) is non-insulating at least in the region beneath the glass electrode (4); and means connecting the metallic carrier body (1) into an electrical circuit.
Claim 10
Dependent Claim 26 words
Element according to claim 10, wherein the base enamel layer comprises an additive of 30 - 50 percent (by weight) of powdered silver or noble metal.
Claim 11
Dependent Claim 12 words
Element according to claim 1, wherein the carrier body (1) comprises steel.
Claim 12
Dependent Claim 28 words
Element according to claim 1, wherein the base enamel layer (2) is essentially electrically insulating; and said metallic carrier body is electrically grounded to form an electrical shield.

References Cited (Backward Citations)

US2117596A Cited
GB492936A Cited
GB495303A Cited
GB509555A Cited
US2462843A Cited
US3306837A Cited
US3498901A Cited
US3357909A Cited
US3458422A Cited
US3649506A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-01-21 1977-07-23 1978-01-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-01-21 1981-07-23 1982-01-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-01-21 1985-07-23 1986-01-22 $7700.00 Window Closed / Lapsed

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