Solid washing compositions

Claim 2

A perfumed washing composition according to claim 2 wherein said compound has the formula M(OR)4 and wherein M is titanium.

Claim 3

A perfumed washing composition according to claim 2 wherein M is titanium; wherein at least one of said monomeric esters contains two groups R and wherein the remaining two valencies of M are satisfied by bonding to different oxygen atoms in a single molecule of a difuctional organic compound selected from the group consisting of diols, hydroxyacids and alkylolamines.

Claim 4

A perfumed washing composition according to claim 1 wherein said compound has the formula M(OR)4, wherein M is titanium and R is the residue of at least one compound selected from the group consisting of vanillin, eugenol; ethylvanillin; monovanillin; isoeugenol; methyl-iso-eugenol; benzyl-iso-eugenol; thymol, p-tert-butyl phenol, terpineol; linalol; Beta -phenyl ethanol; citronellol; geraniol; nerol; benzyl alcohol; cinnamyl alcohol and 2-amyl -cinnamyl alcohol.

Claim 5

A perfumed washing composition according to claim 3 which also contains at least one perfumery component other than said monomeric titanium esters and said monomeric titanium esters are from 1-98 percent by weight of the total weight of perfumery components in said washing composition.

Claim 6

A perfumed washing composition according to claim 6 wherein said monomeric titanium esters are from 2-70 percent by weight of the total weight of perfumery components in said washing composition and wherein said total perfumery components are from 0.02-15 percent by weight of the said washing composition.

Claim 7

A perfumed washing composition according to claim 5 which also contains at least one perfumery component other than said monomeric titanium esters and said monomeric titanium esters are from 1-98 percent by weight of the total weight of perfumery components in said washing composition.

Claim 8

A perfumed washing composition according to claim 8 wherein said monomeric titanium esters are from 2-70 percent by weight of the toal weight of perfumery components in said washing composition and wherein said total perfumery components are from 0.02-15 percent by weight of the said washing composition.

Claim 9

A perfumed washing composition according to weight of 9 wherein said monomeric titanate esters are present in an amount of from 0.01-20 percent by weightof said washing composition.

Claim 10

A perfumed washing composition according to claim 8 which contains a plurality of said titanate or zirconate esters having differing rates of hydrolysis in water at a given temperature.

Claim 11

Solid perfumed washing compositions contain-one at least one washing adjuvant selected from the group consisting of solid soaps, sodium carbonate, sodium sesquicarbonate, sodium perborate, sodium phosphate, sodium chloride, ammonium carbonate, borax, sodium hexametaphosphate, surfactants, sodium tripolyphosphate, sodium nitrilotriacetate, sodium metasilicate and sodium pyrophosphate and containing as a perfumery component at least one compound selected from the group consisting of perfumery monomeric titanium and zirconium esters containing at least one group of the formula M-O-R wherein M is titanium or zirconium and R is the residue of a perfumery alcohol or phenol.

Claim 12

A perfumed washing composition according to claim 12 wherein said perfumery alcohol or phenol is selected from the group consisting of linalol; Beta -phenyl ethyl alcohol; benzyl alcohol; menthol; n-hexanol; Alpha -terpineol; eugenol; cis-hex-3-en-l-ol; n-nonahol; citronellol; n-decanol; geraniol; nerol; myrcenol; dihydrocitronellol; dihydrolinalol; dihydrogeraniol; isoborneol; pelargol; or 2,6-dimethyloctan-8-ol; farnesol; dihydrofarnesol; nerolidol; gamma -phenyl-n-propyl alcohol; gamma -phenyl-n-butyl alcohol; epsilon -phenyl-n-amyl alcohol; cinnamyl alcohol; 2-amyl-cinnamyl alcohol phenylethylene glycol; anisyl alcohol; dimethylbenzyl; carbinol; phenylethyldimethyl carbinol; methylphenyl carbinol; dimethylphenyl carbinol; trichloromethyl phenylcarbinol; ethylbenzylcarbinol; methylbenzylcarbinol; isopropyl-benzyl carbinol; ethyl-n-amylcarbinol; methyl-n-amyl-carbinol, omega -hydroxymethyllongifolene; 6-and 10-hydroxymethyl-1,8-p-methadiene; epsilon -camphene carbinol; 2-hydroxy- gamma -pinene; verbenol; carveol; 2-hydroxy-6-p-menthene; 5-hydroxy-3-p-menthene; 3-hydroxy-2,5-dimethyl-1,4,6-octatriene; 6,8-dihydroxy-1-p-menthene; 1-hydroxy-2-p-menthene; 4-hydroxy-2-p-menthene; piperitol; carvitol; 3-hydroxy-1,1,2,3-tetramethyl-4-cyclohexene; 3-hydroxy-2-methyl-6-methylene-1,7-octadiene; 1-hydroxy-2-methyl-6-methylene-2,7-octadiene; 3-hydroxy-2-dimethyl-1,7-octadiene; 1-hydroxy-2,6-dimethyl-2,6-octadiene; ambrettolide; exaltolide; dihydroambrettolide; vanillin; eUgenol; ethylvanillin; homovanillin; isoeugenol; methyliso-eugenol; benzyl-iso-eugenol; thymol and p-tert-butylphenol.

Claim 13

A perfumed washing composition according to claim 12 wherein said compound has the formula M(OR)4 and wherein M is titanium.

Claim 14

A perfumed are composition according to claim 12 wherein M is titanium; wherein at least one of said monomeric esters contains two groups R and wherein the remaining two valencies of M re satisfied by bonding to different oxygen atoms in a single molecule of a difunctional organic ompound selected from the group consisting of diols, hydroxyacids and alkylolamines.

Claim 15

A perfumed washing composition according to claim 12 wherein said compound has the formula M(OR)4, wherein M is titanium snd R is the residue of at least one compound selected from the group consisting of vanillin, eugenol; ethylvanillin; monovanillin, isoeugenol; methyl-iso-eugenol; benzyl-iso-eugenol; thymol; p-tert-butyl phenol; terpineol; linalol; Beta -phenyl ethanol; citronellol; geraniol; nerol; benzyl alcohol; cinnamyl alcohol and 2-amyl-cinnamyl alcohol.

Claim 16

A perfumed washing composition according to claim 12 which also contains a mixture of oligomeric titanate or zirconate esters of the formula A3M(OMA2)nA, wherein n is an integer and the groups A are the same or different organic groups, at least one of which has the formula (-OR), said mixture having been formed by hydrolysis of a monomeric titanate or zirconate ester, MA4 with from 50 to 90 moles water per 100 moles of ester MA4.

Claim 17

A perfumed washing composition according to claim 14 which also contains at least one perfumery component other than said monomeric titanium esters and said monomeric titanium esters are from 1-98 percent by weight of the total weight of perfumery components in said washing composition.

Claim 18

A perfumed washing composition according to claim 18 wherein was monomeric titanium esters are from 2-70 percent by weight of the total weight of perfumery components in said washing composition and wherein said total perfumery components are from 0.02-15 percent by weight of the said washing composition.

Claim 19

A perfumed washing composition according to claim 16 which also contains at least one perfumery component other than said monomeric titanium esters and said monomeric titanium esters are from 1-98 percent by weight of the total weight of perfumery components in said washing composition.

Claim 20

A perfumed washing composition according to claim 20 wherein said monomeric titanium esters are from 2-70 percent by weight of the total weight of perfumery components in said washing composition and wherein said total perfumery components are from 0.02-15 percent by weight of the said washing composition.

Claim 21

A perfumed washing composition according to claim 21 wherein said monomeric titanium esters are from 2-70 percent by weight of the total weight of perfumery components in said washing composition.

Claim 22

A perfumed washing composition according to claim 22 wherein the total perfumery components are from 0.02-15 percent by weight of said solid washing composition.

Claim 23

A perfumed washing composition according to claim 18 wherein said monomeric titanate esters are present in an amount of 0.01-20 percent by weight of said washing composition.

Claim 24

A perfumed washing composition according to claim 18 which also contains a plurality of titanate or zirconate esters having differing rates of hydrolysis in water at a given temperature.

Claim 25

A perfumed washing composition according to claim 20which also contains a plurality of titanate or zirconate esters hvaing differing rates of hydrolysis in water at a given temperature.