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US3778243A Expired / Lapsed US ⏱️ 0.0 years remaining

Metal oxide coated glass blocks

Assignee: Pittsburgh Corning LLC
•
Filing: 1971-11-10
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Granted: 1973-12-11
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Expires: 1991-11-10
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Abstract

Abstract The method of preparing transparent metal oxide coated glass blocks includes forming the blocks in halves by positioning a molten mass of glass in a suitable mold that has a fixed bottom plate and a vertical exterior forming shell. A plunger is inserted into the mold to shape the molten mass of glass into a half of a glass block with an upwardly extending rectangular edge portion. While at an elevated temperature of above 1,000* F. the rectangular edge portions of two block halves are positioned in overlying abutting relation and are flame sealed. While still at an elevated forming temperature of between about 900* F. and 1,150* F. the sealed block is sprayed with a heat decomposable metal organic salt in organic solution to form a metal oxide coating on the block exterior surface. After spraying at this elevated forming temperature the block is annealed in a conventional manner. Another embodiment includes spraying the inside surface of the block halves at this elevated temperature immediately after forming and prior to sealing. Still another embodiment includes spraying the outside surface of the block halves immediately after forming and prior to sealing while at the elevated temperature of between about 900* and 1,150* F.

Inventors

  • 👤 W Johnston

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 20:39
CPC Classifications
C; C03; C03C; C03C17/00; C03C17/22; C03C17/23; C03C17/25; C03B; C03B23/00; C03B23/20; C03B23/24; C03C2217/00; C03C2217/20; C03C2217/21; C03C2217/229; C03C2218/00; C03C2218/10; C03C2218/11; C03C2218/112

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 49 words
A method for making metal oxide coated glass blocks as set forth in claim 1 which includes, while at a temperature of about 1,100* F. positioning a pair of glass block halves in abutting relation to each other, and flame sealing the edge portions of said glass block halves.
Claim 2
Dependent Claim 48 words
A method for making metal oxide coated glass blocks as set forth in claim 1 which includes, spraying a surface of certain of said glass block halves with a liquid metal oxide film forming composition while said glass block halves are at a temperature of about 1,000* F.
Claim 3
Dependent Claim 42 words
A method for making metal oxide coated glass blocks as set forth in claim 2 which includes, spraying a portion of the exterior surface of said glass block with a liquid metal oxide film forming composition after flame sealing said block halves.
Claim 4
Dependent Claim 36 words
A method for making metal oxide coated glass blocks as set forth in claim 1 which includes, spraying an inner surface of certain of said glass block halves with a liquid metal oxide film forming composition.
Claim 5
Dependent Claim 39 words
A method for making metal oxide coated glass blocks as set forth in claim 1 in which, said metal acetylacetonate is selected from the group consisting of iron, chromium, magnesium, vanadium, cobalt, copper and nickel acetylacetonates and metals thereof.
Claim 6
Dependent Claim 37 words
A method for making metal oxide coated glass blocks as set forth in claim 6 in which, said metal oxide forming composition comprises a liquid that includes a polar organic solvent and a non-polar organic aromatic solvent.
Claim 7
Dependent Claim 34 words
A method for making metal oxide coated glass blocks as set forth in claim 7 in which, said polar organic solvent is selected from the group consisting of methanol, ethanol, propanol and mixtures thereof.
Claim 8
Dependent Claim 34 words
A method for making metal oxide coated glass blocks as set forth in claim 7 in which, said non-polar organic solvent is selected from the group consisting of benzene, toluene, xylene and mixtures thereof.

References Cited (Backward Citations)

US2297337A Cited
US2430520A Cited
US2795084A Cited
US2877605A Cited
US3004875A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-12-10 1977-06-11 1977-12-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-12-10 1981-06-11 1981-12-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-12-10 1985-06-11 1985-12-11 $7700.00 Window Closed / Lapsed

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