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US3773679A Expired / Lapsed US ⏱️ 0.0 years remaining

Sodium dithionite solution stabilization

Assignee: Hoechst Celanese Chemical Co
•
Filing: 1972-01-14
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Granted: 1973-11-20
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Expires: 1992-01-14
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Abstract

Abstract Sodium dithionite in solution is widely used in bleaching and vat dyeing of textiles. Unfortunately, however, losses occur not only through decomposition during dissolving of the salt in question, but also during storage of the solution. To avoid decomposition of such solutions, the presence of sulfite ion is introduced by sodium sulfite, or a comparable variant compound preferably with a pH adjustment under either aerobic or anaerobic conditions. The effect hereof in protecting the sodium dithionite against aerobic decomposition is at 7 percent to 45 percent of the decomposition rate for unprotected systems. With air exclusion, the rate in the protected system is at 2 percent to 71 percent that for the unprotected system. As indicated, mixtures of sodium sulfite or sodium bicarbonate with sodium bisulfite (anhydrous) have likewise been found effective as a stabilizing media for the sodium dithionite solution, all by virtue of the sulfite ion concentration increase therein.

Inventors

  • 👤 M Kise
  • 👤 L Ellis

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 19:24
CPC Classifications
C; C01; C01B; C01B17/00; C01B17/64; C01B17/66; C01B17/665

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 33 words
The method according to claim 1, wherein the concentration of the sulfite ion is effected by the addition of sodium sulfite in a small but effective amount not to exceed 1.0 percent strength.
Claim 2
Dependent Claim 28 words
The method according to claim 1, wherein the concentration of the sulfite ion is effected by the addition of anhydrous sodium bisulfite in a small but effective amount.
Claim 3
Dependent Claim 34 words
The method according to claim 1, wherein the concentration of the sulfite ion is effected by the addition of a mixture of sodium sulfite and anhydrous sodium bisulfite in a small but effective amount.
Claim 4
Dependent Claim 39 words
The method according to claim 1, wherein the concentration of the sulfite ion is effected by the addition of a mixture of sodium bicarbonate and anhydrous sodium bisulfite in a small but effective amount not to exceed 1.0 percent.
Claim 5
Dependent Claim 38 words
The method according to claim 1, wherein the increased concentration is effected by simultaneous admixture and agitation of a sulfite ion additive with the sodium dithionite, the proportion of additive to solution being a small but effective amount.
Claim 6
Dependent Claim 40 words
A reaction product for bleaching including a low concentration aqueous solution of sodium dithionite, falling within the range of 4.6 percent to 15 percent and a sulfite ion additive having a concentration not to exceed the extreme of 1.0 percent.
Claim 7
Dependent Claim 12 words
The product of claim 7 in which the additive comprises sodium sulfite.
Claim 8
Dependent Claim 13 words
The product of claim 7 in which the additive comprises anhydrous sodium bisulfite.
Claim 9
Dependent Claim 18 words
The product of claim 7 in which the additive comprises sodium sulfite and anhydrous sodium bisulfite in admixture.
Claim 10
Dependent Claim 23 words
The product of claim 7 in which the additive comprises sodium bicarbonate and anhydrous sodium bisulfite not to exceed in admixture 1.0 percent.

References Cited (Backward Citations)

No citation records indexed.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-11-19 1977-05-21 1977-11-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-11-19 1981-05-21 1981-11-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-11-19 1985-05-21 1985-11-20 $7700.00 Window Closed / Lapsed

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