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US3770416A Expired / Lapsed US ⏱️ 0.0 years remaining

Treatment of zinc rich steel mill dusts for reuse in steel making processes

Assignee: Michigan Technological University
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Filing: 1972-04-17
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Granted: 1973-11-06
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Expires: 1992-04-17
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Abstract

Abstract Crush-resistant, metallized agglomerates, containing substantially no zinc or lead and capable of being charged to various steel-making furnaces, are produced from dust recovered from the fumes of a basic oxygen or open hearth steel-making furnace by forming a moistened mixture of (a) the dust (b) finely divided solid carbonaceous material containing sufficient carbon to make the total equivalent fixed carbon content of the mixture about 5 to about 25 weight percent, based on the dry weight of the mixture, (e) a bonding agent in the range of about 5 to about 25 weight percent, based on the dry weight of the mixture, and (d) one or more additional strengthening agents in minor amounts; forming the resultant mixture into green agglomerates; hydrothermally hardening partially dried or dried agglomerates at a temperature substantially below the combustion or decomposition temperature of the carbonaceous material; and then heating the hardened agglomerates at an elevated temperature for a sufficient time to reduce the iron oxide to metallic iron and to reduce and volatilize the zinc, lead and other reducible impurities therein.

Inventors

  • 👤 M Goksel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 00:13
CPC Classifications
C; C22; C22B; C22B1/00; C22B1/14; C22B1/24; C22B1/2406; C21; C21B; C21B13/00; C21B13/0046; C21B13/006; Y; Y10; Y10S; Y10S75/00; Y10S75/961

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 40 words
The method according to claim 1 further comprising the step of: e. heating said hardened agglomerates to a temperature within the range of about 1,900*F to about 2,400*F for a sufficient time to remove substantially all of the zinc therein.
Claim 2
Dependent Claim 20 words
The method according to claim 1 wherein said waste dust is recovered from the fumes from a basic oxygen furnace.
Claim 3
Dependent Claim 37 words
The method according to claim 3 wherein said mixture includes at least one other finely divided iron containing waste material selected from the group consisting of open hearth dust, scarfer grit, mill scale, and spark box fines.
Claim 4
Dependent Claim 19 words
The method according to claim 1 wherein said bonding agent is calcium oxide, calcium hydroxide, or a mixture thereof.
Claim 5
Dependent Claim 71 words
The method according to claim 5 wherein said mixture includes a siliceous material seleCted from the group consisting of bentonite, diatomaceous earth, fuller''s earth, portland cement, sodium silicate, pyrogenic silicas, hydrated silicas, calcium silicate, magnesium silicate, aluminum silicate, ground quartz, silica sand and mixtures thereof in an amount within the range of about 0.1 to about 10 weight percent, based on the total weight of the dry solids in said mixture.
Claim 6
Dependent Claim 32 words
The method according to claim 6 wherein step (b) is carried out in a moist atmosphere at a temperature of about 80*F to about 90*C for about 12 to about 24 hours.
Claim 7
Dependent Claim 32 words
The method according to claim 6 wherein step (d) is carried out in the presence of a saturated steam atmosphere at a temperature in the range of about 200*F to about 550*F.
Claim 8
Dependent Claim 31 words
The method according to claim 8 including the step of drying said agglomerates to reduce the moisture content thereof to a maximum of about 3 weight percent prior to step (d).
Claim 9
Dependent Claim 34 words
The method according to claim 9 including the step of drying said hardened agglomerates immediately after step (d) at a temperature of about 175*F to about 250*F for about 5 to about 60 minutes.
Claim 10
Dependent Claim 73 words
The method according to claim 5 wherein said mixture includes silica in an amount within the range of about 0.1 to about 3 weight percent, said bonding agent in an amount within the range of about 1 to about 15 weight percent, and said carbonaceous material in an amount within the range of about 10 to about 15 weight percent, all based on the total weight of the dry solids in said mixture.

References Cited (Backward Citations)

US2417493A Cited
US3313617A Cited
US3524743A Cited
US3567428A Cited
US3653874A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-11-05 1977-05-07 1977-11-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-11-05 1981-05-07 1981-11-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-11-05 1985-05-07 1985-11-06 $7700.00 Window Closed / Lapsed

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