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US3767547A Expired / Lapsed US ⏱️ 0.0 years remaining

Photopolymerization using triorgano-substituted phosphine and sulfonyl halides as a photoinitiator

Assignee: SCM Corp
•
Filing: 1971-10-21
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Granted: 1973-10-23
•
Expires: 1991-10-21
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Abstract

Abstract An improved process for polymerizing a vinyl monomer in the presence of a photoinitiator by irradiating the vinyl monomer with a beam of wave energy is set forth. The improvement comprises using an effective amount of a triorgano-substituted phosphine and a sulfonyl halide in combination as the photosensitizer.

Inventors

  • 👤 H Puhk

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 17:25
CPC Classifications
C; C08; C08F; C08F20/00; C08F20/02; C08F20/10; C08F20/12; C08F2/00; C08F2/46; C08F283/00; C08F283/01; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/122; Y10S525/00; Y10S525/904

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 21 words
The process of claim 1 wherein the molar ratio of Tri-organo-substituted phosphine to arylsulfonyl chloride is from about 0.25:0.75 to 0.75:0.25.
Claim 2
Dependent Claim 11 words
The process of claim 1, wherein said triorgano-phosphine is triphenyl phosphine.
Claim 3
Dependent Claim 20 words
The process of claim 1, wherein said lower alkyl ester is a hydroxy alkyl ester of acrylic or methacrylic acid.
Claim 4
Dependent Claim 14 words
The process of claim 1, wherein said aryl sulfonyl chloride is benzene sulfonyl chloride.
Claim 5
Dependent Claim 14 words
The process of claim 1, wherein said aryl sulfonyl chloride is para-toluene sulfonyl chloride.
Claim 6
Dependent Claim 13 words
The process of claim 1, wherein said aryl sulfonyl chloride is 2-naphthylsulfonyl chloride.

References Cited (Backward Citations)

US3331761A Cited
US3531282A Cited
US3547633A Cited
US3579095A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-10-22 1977-04-23 1977-10-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-10-22 1981-04-23 1981-10-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-10-22 1985-04-23 1985-10-23 $7700.00 Window Closed / Lapsed

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