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US3767488A Expired / Lapsed US ⏱️ 0.0 years remaining

Pressure sensitive explosive with organosilane coating

Assignee: United States Department of the Army
•
Filing: 1972-02-15
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Granted: 1973-10-23
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Expires: 1992-02-15
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Abstract

Abstract A pressure sensitive explosive composition is provided which is rendered insensitive to water or water vapor by means of a coating of an organofunctional silane capable of polymerization on contact with water or water vapor. Additionally, a method is provided of coating such a composition by the use of the abovementioned silane in a halocarbon solvent having a relatively low vapor pressure at ambient conditions. The composition may be a mixture of an inorganic oxidizer and fuel such as potassium chlorate, red phosphorous and ground glass or a mixture of a primary explosive such as lead azide and a secondary explosive such as RDX, either mixture being coated with a silane such as gamma ( Beta aminoethyl) aminopropyl trimethoxy silane applied from a volatile halocarbon liquid such as 1,1,2 trichloro-1,2,2 trifluoro ethane. The silane, after evaporation of the liquid, coats the composition and polymerizes on contact with water or water vapor to form a water impermeable film and this renders the composition insensitive to water deactivation.

Inventors

  • 👤 W Seals

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 11:12
CPC Classifications
C; C06; C06B; C06B45/00; C06B45/18

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 23 words
A composition as defined in claim 1 wherein said inorganic oxidizer is selected from the group consisting of potassium chlorate and potassium perchlorate.
Claim 2
Dependent Claim 65 words
A composition as defined in claim 1 wherein said organo-functional silane monomer has the general formula R(4 n) - Si - R''n wherein R is a radical selected from the group consisting of halogen, amino, alkoxy and arlyoxy, R'' is a radical selected from the group consisting of alkyl, aryl, aminoalkyl, aminoaryl, alkylamino and arylamino, and n is an integer from 1 to 3 inclusive.
Claim 3
Dependent Claim 41 words
A composition as defined in claim 3 wherein said organo-functional silane monomer is selected from the group consisting of gamma ( Beta aminoethyl) aminopropyl trimethoxy silane; gamma aminopropyl triethoxysilane, methyl triethoxysilane, phenyltrichlorosilane, n butyl trichlorosilane, dimethyl dichlorosilane and methyl phenyl dichlorosilane.
Claim 4
Dependent Claim 27 words
A composition as defined in claim 3, wherein the amount of said monomer is between about 1 percent and 5 percent by weight of said explosive composition.

References Cited (Backward Citations)

US27025A Cited
US1287819A Cited
US2146033A Cited
GB528299A Cited
US2999744A Cited
US3112233A Cited
US3190775A Cited
US3340808A Cited
US3332311A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-10-22 1977-04-23 1977-10-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-10-22 1981-04-23 1981-10-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-10-22 1985-04-23 1985-10-23 $7700.00 Window Closed / Lapsed

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