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US3761707A Expired / Lapsed US ⏱️ 0.0 years remaining

Stigmatically imaging double focusing mass spectrometer

Assignee: Max-Planck-Gesellschaft zur Förderung der Wissenschaften eV
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Filing: 1971-06-21
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Granted: 1973-09-25
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Expires: 1991-06-21
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Abstract

Abstract To provide for better energy definition in a stigmatically focussing mass spectrometer with directional and energy focussing, the ions to be analysed travel consecutively through an entry diaphragm, a first analyser, a diaphragm to limit the energy range (''''energy diaphragm''''), a second analyser, (the energy dispersion factor of which is equal but opposite to that of the first analyser) and an exit diaphragm. One analyser is a momentum analyser operating with a wedge-shaped magnetic field, and the other analyser is an energy analyser operating with an electric field. The momentum analyser comprises a magnet having mutually opposite plane pole-piece surfaces which are mutually inclined and have straight edges which are located at the interval Ao parallel to the intersection line of the planes containing the pole-piece surfaces. A device is provided for adjusting the magnetic field intensity BA at the interval A 2.10Ao from the intersection line to the value BA 1.35 p/Ae (e charge of the ions; p momentum of the ions to be detected). The diaphragms between which the impulse analyser is placed are arranged on the intersection line with a mutual interval of approximately 1.28 A, and the energy analyser, which forms a stigmatic image of the entry side one of the two diaphragms between which it is arranged upon the exit side one of the two said diaphragms, contains a spherical condenser or a cylindrical condenser through which the ions travel in planes which pass through the cylinder axis.

Inventors

  • 👤 H Liebl

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 19:23
CPC Classifications
H; H01; H01J; H01J49/00; H01J49/26; H01J49/28; H01J49/32

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 264 words
Stigmatically imaging mass spectrometer with directional and energy focussing, comprising consecutively positioned with respect to ion travel: an entry diaphragm (24); a first analyzer; an energy diaphragm (28) to limit the energy range; a second analyzer having an energy dispersion factor which is equal to and opposite to that of the first analyzer; and an exit diaphragm (14); one of the analyzers being a momentum analyzer having a wedgeshaped magnetic field, and the other analyzer being an energy analyzer having an electric field; the momentum analyzer comprising a magnet having mutually opposite plane pole-piece surfaces (11) which are mutually inclined and have straight edges which are parallel and spaced by a distance Ao from the intersection line (10) of the planes containing the pole-piece surfaces (11) and parallel to said intersection line, and the magnetic field intensity BA at the distance interval being defined by A 2.10Ao from the intersection line (10) being adjusted to the value BA 1.35p/Ae, wherein e charge of the ions; p momentum of the ions to be detected; the diaphragms (14, 28) between which the momentum analyzer is placed are arranged on the intersection line (10) with a mutual spacing interval of approximately 1.28 A; the energy analyzer, which forms a stigmatic image of the diaphragm (24) at the entry side thereof on the diaphragm (28) located at the exit side thereof, including a spherical condenser (15, 15'') or a cylindrical condenser (15''''), the ions travelling through the condenser in planes which pass through the cylinder axis (34), ions of equal energy being focussed on the energy diaphragm (28).
Claim 2
Dependent Claim 264 words
Stigmatically imaging mass spectrometer with directional and energy focussing, comprising consecutively positioned with respect to ion travel: an entry diaphragm (24); a first analyzer; an energy diaphragm (28) to limit the energy range; a second analyzer having an energy dispersion factor which is equal to and opposite to that of the first analyzer; and an exit diaphragm (14); one of the analyzers being a momentum analyzer having a wedgeshaped magnetic field, and the other analyzer being an energy analyzer having an electric field; the momentum analyzer comprising a magnet having mutually opposite plane pole-piece surfaces (11) which are mutually inclined and have straight edges which are parallel and spaced by a distance Ao from the intersection line (10) of the planes containing the pole-piece surfaces (11) and parallel to said intersection line, and the magnetic field intensity BA at the distance interval being defined by A 2.10Ao from the intersection line (10) being adjusted to the value BA 1.35p/Ae, wherein e charge of the ions; p momentum of the ions to be detected; the diaphragms (14, 28) between which the momentum analyzer is placed are arranged on the intersection line (10) with a mutual spacing interval of approximately 1.28 A; the energy analyzer, which forms a stigmatic image of the diaphragm (24) at the entry side thereof on the diaphragm (28) located at the exit side thereof, including a spherical condenser (15, 15'') or a cylindrical condenser (15''''), the ions travelling through the condenser in planes which pass through the cylinder axis (34), ions of equal energy being focussed on the energy diaphragm (28).
Claim 3
Dependent Claim 49 words
Mass spectrometer according to claim 1, wherein the spherical condenser (15) is a symmetrically grounded 90* condenser (15) having an entry axis, said entry axis being oriented at the distance L 1.03A to be parallel to the intersection line (10) of the planes passing through the pole-piece surfaces (11).
Claim 4
Dependent Claim 29 words
Mass spectrometer according to claim 1 wherein the energy analyzer includes a 45* spherical condenser (15'') and a circular ion lens (30) located in advance of said spherical condenser.
Claim 5
Dependent Claim 112 words
Mass spectrometer according to claim 1, wherein the energy analyzer includes a cylindrical condenser (15'''') having an axis, an outer cylinder (40) and an inner cylinder (38), the axis (34) subtending an angle theta of 42.3* with the axis (36) of the entering ion beam; wherein the radius -a- of the inner cylinder (38) is equal to 0.274A, and wherein the energy of the entering ions and the voltage of the outer cylinder, and its radius have the relationship: (Uo/Ub) log (b/a) 1.31, wherein Uo volt energy of an entering ion Ub voltage of the outer cylinder (40) -a- radius of the inner cylinder (38) b radius of the outer cylinder (40).

References Cited (Backward Citations)

US3445650A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-09-24 1977-03-26 1977-09-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-09-24 1981-03-26 1981-09-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-09-24 1985-03-26 1985-09-25 $7700.00 Window Closed / Lapsed

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