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US3760033A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyester resin compositions

Assignee: Berger Jenson and Nicholson Ltd
•
Filing: 1971-03-10
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Granted: 1973-09-18
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Expires: 1991-03-10
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Abstract

Abstract Curable coating compositions based on unsaturated polyester resin and styrene, particularly those in which the polyester resin has a high degree of unsaturation and/or of chain branching, may be difficult to thin to application viscosity without hazing or phase separation. This problem is solved by adding a minor proportion of an unsaturated hydroxy-ester, particularly Beta -hydroxyethyl methacrylate or Beta hydroxypropyl methacrylate.

Inventors

  • 👤 K Arbuckle
  • 👤 D Lazarus

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 09:53
CPC Classifications
C; C08; C08F; C08F283/00; C08F283/01

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 51 words
A composition as claimed in claim 1, wherein the copolymerizable monomeric unsaturated ester containing a hydroxyl group in its molecule has the general formula: CH2:CR.COOR1 where R is a hydrogen atom or a methyl or ethyl group, and R1 is a hydroxy-substituted alkyl group having from one to 16 carbon atoms.
Claim 2
Dependent Claim 41 words
A composition as claimed in claim 1, wherein the copolymerizable monomeric unsaturated ester containing a hydroxyl group in its molecule is present in a proportion of from 2 TO 15 percent by weight on the weight of the unsaturated polyester resin.
Claim 3
Dependent Claim 180 words
A curable composition as claimed in claim 1 comprising a mixture of i. an unsaturated polyester resin having an acid value of not more than 50, in which resin the unsaturated component is an Alpha - Beta -ethylenically unsaturated dicarboxylic acid, the molar ratio of Alpha - Beta -ethylenically unsaturated acid to all other dicarboxylic components being at least 1.3:1, and in which a tri- or poly-functional component is present in a molar proportion of at least 2.0 percent, and ii. styrene or vinyl toluene, in a proportion of not more than 500 percent by weight on the weight of the unsaturated polyester resin and, iii. from 1 to 50 percent, by weight on the weight of the unsaturated polyester resin, of a copolymerizable monomeric unsaturated ester having the formual CH2:CR.COOR1 where R is a hydrogen atom or a methyl or ethyl group, and R1 is a hydroxy-substitiute alkyl group having from one to 16 carbon atoms, the composition being thinnable with styrene or vinyl toluene to a viscosity of 4.0 poise without passing the haze point of the mixture.

References Cited (Backward Citations)

DE1301511B Cited
CH481151A Cited
US3455801A Cited
FR2001985A1 Cited
DE1929108A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-09-17 1977-03-19 1977-09-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-09-17 1981-03-19 1981-09-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-09-17 1985-03-19 1985-09-18 $7700.00 Window Closed / Lapsed

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