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US3760023A Expired / Lapsed US ⏱️ 0.0 years remaining

Hydrodealkylation process with promoted group vib metals and promoters

Assignee: Ashland LLC
•
Filing: 1971-04-26
•
Granted: 1973-09-18
•
Expires: 1991-04-26
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Abstract

Abstract A process for the hydrodealkylation of alkyl-substituted aromatic hydrocarbons, including contacting the alkyl-substituted aromatic hydrocarbons with a catalyst comprising a metal of Group VIB of the Periodic System, such as chromium, molybdenum, and tungsten, and mixtures thereof, in an amount of about 5 to 15 per cent by weight of the finished catalyst, and a promoter selected from the group consisting of alkali metals, alkaline earth metals, rare earth metals, and mixtures thereof, such as potassium, rubidium, cesium, calcium, strontium, barium, cerium, thorium, etc., in an amount between about 1 to 10 percent by weight of the finished catalyst, at a temperature of about 1,050* to 1,200*F, a pressure of about 100 to 1,000 psig., a liquid hourly space velocity of about 0.1 to 5, and a hydrogento-hydrocarbon mole ratio between about 3 and 15 to 1.

Inventors

  • 👤 S Kovach
  • 👤 R Patrick
  • 👤 R Kmecak

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 17:30
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/16; B01J23/24; C; C07; C07C; C07C4/00; C07C4/08; C07C4/12; C07C4/14; C07C4/18; C07C2521/00; C07C2521/02; C07C2521/04; C07C2523/00; C07C2523/02; C07C2523/04; C07C2523/12; C07C2523/16; C07C2523/24

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 13 words
A process in accordance with claim 1 wherein the promoter metal is calcium.
Claim 2
Dependent Claim 13 words
A process in accordance with claim 1 wherein the promoter metal is strontium.
Claim 3
Dependent Claim 13 words
A process in accordance with claim 1 wherein the promoter metal is barium.
Claim 4
Dependent Claim 13 words
A process in accordance with claim 1 wherein the promoter metal is thorium.
Claim 5
Dependent Claim 13 words
A process in accordance with claim 1 wherein the promoter metal is rubidium.
Claim 6
Dependent Claim 13 words
A process in accordance with claim 1 wherein the promoter metal is cesium.
Claim 7
Dependent Claim 15 words
A process in accordance with claim 1 wherein the alumina carrier is a gamma alumina.

References Cited (Backward Citations)

US2734929A Cited
US2963518A Cited
US2958643A Cited
US2858348A Cited
US2895905A Cited
US3153675A Cited
US3193592A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-09-17 1977-03-19 1977-09-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-09-17 1981-03-19 1981-09-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-09-17 1985-03-19 1985-09-18 $7700.00 Window Closed / Lapsed

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