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US3755264A Expired / Lapsed US ⏱️ 0.0 years remaining

Maleic anhydride copolymers and method of making

Assignee: WR Grace and Co Conn
•
Filing: 1971-07-30
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Granted: 1973-08-28
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Expires: 1991-07-30
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Abstract

Abstract Copolymer of 99 to 85 mol percent of maleic anhydride with from 1 to 15 mol percent of acrylic acid, vinyl acetate, styrene, or mixtures thereof, and hydrolyzed analogous copolymers of maleic acid or maleic salts are highly effective chelating agents. They are made by slowly combining a solution containing the acrylic acid, vinyl acetate, or styrene and a large amount of free radical initiator with a solution containing the maleic anhydride.

Inventors

  • 👤 A Testa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 18:17
CPC Classifications
C; C08; C08F; C08F22/00; C08F22/04; C02; C02F; C02F5/00; C02F5/08; C02F5/10; C08F8/00

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 14 words
A copolymer as claimed in claim 1 in which said member is acrylic acid.
Claim 2
Dependent Claim 14 words
A copolymer as claimed in claim 1 in which said member is vinyl acetate.
Claim 3
Dependent Claim 13 words
A copolymer as claimed in claim 1 in which said member is styrene.
Claim 4
Dependent Claim 17 words
A copolymer as claimed in claim 1 in which the mol percent is from 85 to 95.
Claim 5
Dependent Claim 119 words
A process for making a copolymer as claimed in claim 1 in which process comprises providing a solution of maleic anhydride in an anhydrous liquid organic solvent, mixing with said solution slowly, over a period of at least 3 hours, a solution containing in an anhydrous liquid organic solvent miscible with said first solvent a free-radical generator and a member of the group consisting of acrylic acid, vinyl acetate, styrene and mixtures thereof, the amount of said free-radical generator being at least 6 percent by weight of the total monomer and the amount of said member being from 1 to 15 mol percent of the total monomer, while maintaining the temperature of said mixed solution at 100* to 145*C.
Claim 6
Dependent Claim 14 words
A process as claimed in claim 6 in which said member is scrylic acid.
Claim 7
Dependent Claim 14 words
A process as claimed in claim 6 in which said member is vinyl acetate.
Claim 8
Dependent Claim 13 words
A process as claimed in claim 6 in which said member is styrene.

References Cited (Backward Citations)

US2971939A Cited
US3388106A Cited
US3359246A Cited
US3635915A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-08-27 1977-02-26 1977-08-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-08-27 1981-02-26 1981-08-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-08-27 1985-02-26 1985-08-28 $7700.00 Window Closed / Lapsed

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