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US3755090A Expired / Lapsed US ⏱️ 0.0 years remaining

A method of providing a surface of a steel substrate with an aluminum coating

Assignee: British Steel Corp
•
Filing: 1972-03-27
•
Granted: 1973-08-28
•
Expires: 1992-03-27
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Abstract

Abstract The invention concerns a method of providing a surface of a steel substrate with an aluminum coating consisting essentially of the steps of electrolytically coating the said surface with a layer of iron, wetting the iron layer with a film of an aqueous solution consisting essentially of water and an alkali metal silicate, coating the said wetted layer of iron with a layer of aluminum powder which forms an alloy with the steel substrate when heat treated at a temperature of 502* - 600* C, compacting the said layers to the surface of the steel substrate at a temperature below the sintering temperature whereby the particles of aluminum powder in the compacted layer thereof are compacted to each other and to the steel substrate without sintering occurring, and heat treating the compacted steel substrate at a temperature of 502* - 600* C over a period of time whereby sintering and bonding of the particles to each other and to the steel substrate occurs, the said iron layer serving to control nucleation of said alloy during the heat treatment and having a thickness varying from a minimum of about 0.5 micron when the heat treatment is at 502* C to a minimum of about 3.5 microns when the heat treatment is at 600* C.

Inventors

  • 👤 A Jackson
  • 👤 E Williams

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 11:42
CPC Classifications
C; C25; C25D; C25D5/00; C25D5/48; C25D5/50

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 20 words
A method as claimed in claim 1 in which the heat treatment is in the range 502* - 575* C.
Claim 2
Dependent Claim 20 words
A method as claimed in claim 1 in which the heat treatment is in the range 502* - 525* C.
Claim 3
Dependent Claim 20 words
A method as claimed in claim 3 in which the thickness of the iron layer is at least 1.5 microns.
Claim 4
Dependent Claim 22 words
A method as claimed in claim 1 in which the compacted steel substrate is heat treated for about 15 - 20 hours.
Claim 5
Dependent Claim 25 words
A method as claimed in claim 1 in which the aluminum powder particles are applied to the wetted iron layer in an electrostatically charged condition.
Claim 6
Dependent Claim 27 words
A method as claimed in claim 1 in which the substrate is a moving steel strip each of whose opposite sides is provided with an aluminum coating.
Claim 7
Dependent Claim 39 words
A method as claimed in claim 1 in which the surface of the steel substrate is subjected to pickling in an acid, the electrolyte employed during the said electrolytic coating being derived from liquor resulting from the said pickling.
Claim 8
Dependent Claim 37 words
A method as claimed in claim 8 in which any remaining acid in the pickle liquor is neutralised with scrap iron, and the pickle liquor is diluted with water prior to its being used as the electrolyte.
Claim 9
Dependent Claim 14 words
A method as claimed in claim 8 in which the acid is hydrochloric acid.
Claim 10
Dependent Claim 57 words
A method as claimed in claim 1 in which the steel substrate, immediately after receiving the electrolytic coating, is dried so as to solidify any electrolyte on the steel substrate, the solidifed electrolyte being thereafter removed by washing with water, and the steel substrate being then wetted with the said aqueous solution of an alkali metal silicate.
Claim 11
Dependent Claim 20 words
A method as claimed in claim 11 in which the drying is effected by directing air onto the steel substrate.
Claim 12
Dependent Claim 123 words
A method as claimed in claim 7 in which the steel strip is passed, with a predetermined surface thereof lowermost, through at least one first plating bath, and is then passed, with the opposite surface thereof lowermost, through at least one second plating bath, each of the first and second plating baths being provided with an iron anode above which the steel strip is passed and the said at least one second plating bath being provided with an auxiliary anode disposed above the steel strip, the auxiliary anode being insoluble in the electrolyte in the second plating bath and being operated at a low voltage which cathodically polarises the steel strip and ensures that the latter is not pickled by the said electrolyte.
Claim 13
Dependent Claim 30 words
A method as claimed in claim 13 in which the auxiliary anode is a titanium anode and is operated at a current density of about 5 amperes per square foot.
Claim 14
Dependent Claim 28 words
A method as claimed in claim 1 in which the electrolyte employed in the electrolytic coating has a ferrous iron content of at least 70 grams per litre.
Claim 15
Dependent Claim 24 words
A method as claimed in claim 1 in which the temperature of the electrolyte employed in the electrolytic coating is at least 70* C.
Claim 16
Dependent Claim 39 words
A method as claimed in claim 1 in which, immediately prior to the electrolytic coating, the steel substrate is wetted with a liquid whose pH is substantially the same as that of the electrolyte employed in the electrolytic coating.
Claim 17
Dependent Claim 18 words
A method as claimed in claim 17 in which the electrolyte itself is employed as the said liquid.
Claim 18
Dependent Claim 30 words
A method as claimed in claim 1 in which the aluminum coated steel substrate is cold reduced and then annealed at a temperature within the range 500* - 525* C.

References Cited (Backward Citations)

CA748381A Cited
US2484118A Cited
US2978361A Cited
GB773722A Cited
US3085900A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-08-27 1977-02-26 1977-08-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-08-27 1981-02-26 1981-08-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-08-27 1985-02-26 1985-08-28 $7700.00 Window Closed / Lapsed

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