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US3753680A Expired / Lapsed US ⏱️ 0.0 years remaining

Arylidene semicarbazones and their utility as herbicides

Assignee: Zeneca Inc
•
Filing: 1970-05-14
•
Granted: 1973-08-21
•
Expires: 1990-05-14
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Abstract

Abstract Substituted-arylidene semicarbazone having the formula: IN WHICH Z represents oxygen, X represents halogen, lower alkoxy, lower alkyl, hydroxyl, nitro, cyano, N-allylcarbamoyloxy, lower-dialkylthiophos-phoryloxy, N-lower alkylcarbamoyloxy, lower dialkylamino, or (CH3)3N I ; n represents an integer of from 0 to 3, inclusive; R represents hydrogen or lower alkyl; R1 represents hydrogen or lower alkyl; R2 represents, lower alkyl or allyl; R3 represents hydrogen, alkyl, allyl, furfuryl, tetrahydrofurfuryl, lower alkoxy lower alkyl, cyclohexyl, 2-chloroallyl, phenyl, benzyl, or substituted-phenyl in which the substituents are chloro or nitro; R2 and R3 when taken together represent an alkylene containing four to six carbon atoms, inclusive or lower alkyl substituted alkylene containing five to eight carbon atoms, inclusive. The compounds are useful as herbicides.

Inventors

  • 👤 H Tilles

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 06:15
CPC Classifications
C; C07; C07D; C07D307/00; C07D307/02; C07D307/34; C07D307/56; C07D307/66; C07D307/04; C07D307/18; C07D307/22; C07F; C07F9/00; C07F9/02; C07F9/06; C07F9/16; C07F9/165; C07F9/18

Claims Analysis

Total Claims: 33
Claim 1
Independent Claim 30 words
A method according to claim 1 in which X is lower alkyl, R is hydrogen, R1 is lower alkyl, R2 is hYdrogen, R3 is lower alkyl and n is 1.
Claim 2
Dependent Claim 18 words
A method according to claim 2 in which X is 4-methyl, R1 is methyl and R3 is n-butyl.
Claim 3
Dependent Claim 18 words
A method according to claim 2 in which X is 4-methyl, R1 is methyl and R3 is t-butyl.
Claim 4
Dependent Claim 18 words
A method according to claim 2 in which X is 4-methyl, R1 is methyl and R3 is methyl.
Claim 5
Dependent Claim 18 words
A method according to claim 2 in which X is 4-methyl, R1 is methyl and R3 is ethyl.
Claim 6
Dependent Claim 18 words
A method according to claim 2 in which X is 4-methyl, R1 is methyl and R3 is isopropyl.
Claim 7
Dependent Claim 18 words
A method according to claim 2 in which X is 2-methyl, R1 is methyl and R3 is isopropyl.
Claim 8
Dependent Claim 18 words
A method according to claim 2 in which X is 2-methyl, R1 is methyl and R3 is t-butyl.
Claim 9
Dependent Claim 26 words
A method according to claim 1 in which n is 0, R is hydrogen, R1 is lower alkyl, R2 is hydrogen and R3 is lower alkyl.
Claim 10
Dependent Claim 15 words
A method according to claim 10 in which R1 is methyl and R3 is t-butyl.
Claim 11
Dependent Claim 15 words
A method according to claim 10 in which R1 is methyl and R3 is t-butyl.
Claim 12
Dependent Claim 29 words
A method according to claim 1 in which X is chlorine, R is hydrogen, R1 is lower alkyl, R2 is hydrogen, R3 is lower alkyl and n is 1.
Claim 13
Dependent Claim 21 words
A method according to claim 13 in which the chlorine is in the 4-position, R1 is methyl and R3 is methyl.
Claim 14
Dependent Claim 21 words
A method according to claim 13 in which the chlorine is in the 4-position, R1 is methyl and R3 is t-butyl.
Claim 15
Dependent Claim 21 words
A method according to claim 13 in which the chlorine is in the 2-position, R1 is methyl and R3 is t-butyl.
Claim 16
Dependent Claim 21 words
A method according to claim 13 in which the chlorine is in the 4-position, R1 is methyl and R3 is isopropyl.
Claim 17
Dependent Claim 21 words
A method according to claim 13 in which the chlorine is in the 2-position, R1 is methyl and R3 is isopropyl.
Claim 18
Dependent Claim 21 words
A method according to claim 13 in which the chlorine is in the 3-position, R1 is methyl and R3 is t-butyl.
Claim 19
Dependent Claim 21 words
A method according to claim 13 in which the chlorine is in the 3-position, R1 is methyl and R3 is isopropyl.
Claim 20
Dependent Claim 21 words
A method according to claim 13 in which the chlorine is in the 2-position, R1 is methyl and R3 is ethyl.
Claim 21
Dependent Claim 21 words
A method according to claim 13 in which the chlorine is in the 2-position, R1 is methyl and R3 is methyl.
Claim 22
Dependent Claim 21 words
A method according to claim 13 in which the chlorine is in the 2-position, R1 is methyl and R3 is n-propyl.
Claim 23
Dependent Claim 21 words
A method according to claim 13 in which the chlorine is in the 2-position, R1 is methyl and R3 is n-butyl.
Claim 24
Dependent Claim 21 words
A method according to claim 13 in which the chlorine is in the 2-position, R1 is n-butyl and R3 is isopropyl.
Claim 25
Dependent Claim 21 words
A method according to claim 13 in which the chlorine is in the 2-position, R1 is n-butyl and R3 is t-butyl.
Claim 26
Dependent Claim 21 words
A method according to claim 13 in which the chlorine is in the 2-position, R1 is n-butyl and R3 is methyl.
Claim 27
Dependent Claim 30 words
A method according to claim 1 in which X is lower alkoxy, R is hydrogen, R1 is lower alkyl, R2 is hydrogen, R3 is lower alkyl and n is 1.
Claim 28
Dependent Claim 18 words
A method according to claim 2 in which X is 4-methoxy, R1 is methyl and R3 is t-butyl.
Claim 29
Dependent Claim 18 words
A method according to claim 28 in which X is 4-methoxy, R1 is methyl, and R3 is isopropyl.
Claim 30
Dependent Claim 18 words
A method according to claim 28 in which X is 2-methoxy, R1 is methyl and R3 is t-butyl.
Claim 31
Dependent Claim 30 words
A method according to claim 1 in which X is lower alkoxy, R is hydrogen, R1 is lower alkyl, R2 is hydrogen, R3 is lower alkyl and n is 2.
Claim 32
Dependent Claim 18 words
A method according to claim 32 in which X is 3,4-dimethoxy, R1 is methyl and R3 is t-butyl
Claim 33
Dependent Claim 18 words
A method according to claim 32 in which X is 3,4-dimethoxy, R1 is methyl and R3 is isopropyl.

References Cited (Backward Citations)

US3125601A Cited
US2412510A Cited
US3031292A Cited
US3182082A Cited
US3194835A Cited
US3419659A Cited
US3382061A Cited
US3591636A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-08-20 1977-02-19 1977-08-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-08-20 1981-02-19 1981-08-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-08-20 1985-02-19 1985-08-21 $7700.00 Window Closed / Lapsed

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