US3748625A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Moisture sensing element and method of making same
Assignee: THUNDER SCIENT CORP
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Filing: 1972-01-06
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Granted: 1973-07-24
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Expires: 1992-01-06
Abstract
Abstract A moisture sensing element includes a pair of electrodes held spaced apart by a crystal lattice. The crystal lattice has interstitial spaces formed therein and is electrically neutral so that molecules of atmosphere having water ions therein randomly drift in and out of the crystal interstices. The resistance of the sensing element varies as a function of the per cent of water vapor present in the interstices of the crystal lattice. The sensing element may be formed by embedding platinum-iridium wires in a Cr2O3 - V2O5 mixture and baking the mixture in the presence of Al2O3 doping chips.
Inventors
- 👤 P Bennewitz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 13:28
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/02; G01N27/04; G01N27/12; G01N27/121; H; H01; H01H; H01H35/00; H01H35/42; Y; Y10; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002; Y10T29/49082
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
30 words
The invention defined in claim 1, wherein said electrodes are positioned a predetermined distance apart alongside each other in a substantially mutually parallel relationship to extend away from each other.
Claim 2
Independent Claim
95 words
A method of making a moisture sensing element, comprising the steps of: mixing the compounds Cr2O3 and V2O5 into a substantially homogenous mixture; embedding a pair of straight electrodes in a predetermined shaped quantity of said Cr2O3 - V2O5 mixture to form a sensing element, said electrodes being positioned in said mixture a predetermined distance apart alongside each other to extend away from each other in a substantially mutually parallel relationship; baking said sensing element to form between said electrodes a crystal lattice having interstitial spaces therein; and cooling said sensing element to ambient temperature.
Claim 3
Dependent Claim
24 words
The mEthod defined in claim 3, wherein said compounds Cr2O3 and V2O5 are mixed in a ratio of approximately one to one by weight.
Claim 4
Dependent Claim
47 words
The method defined in claim 3, wherein said sensing element is baked at a temperature within the range of 1,100* C up to the melting point of the crystal lattice being formed therein for a period of time in the range of 10 minutes to 2 hours.
Claim 5
Dependent Claim
28 words
The method defined in claim 3, wherein said sensing element is cooled to ambient temperature by first lowering its temperature to approximately 860* C and then quenching it.
Claim 6
Dependent Claim
15 words
The method defined in claim 3, wherein said electrodes are measured lengths of platinium-iridium wire.
Claim 7
Dependent Claim
19 words
The method defined in claim 3, wherein said sensing elements are baked in the presence of Al2O3 doping chips.
Claim 8
Dependent Claim
15 words
The method defined in claim 7 wherein the electrodes are spaced apart approximately 5 mils.
Claim 9
Independent Claim
174 words
A method of making a moisture sensing element, comprising the steps of: mixing the compounds Cr2O3 and V2O5 in approximately a 1 to 1 ratio by weight into a substantially homogeneous mixture; aging said Cr2O3-V2O5 mixture for at least two weeks; embedding a pair of platinium-iridium wires in a predetermined shaped quantity of said mixture to form a sensing element, said wires being positioned in said mixture a predetermined distance apart alongside each other to extend away from each other in a substantially mutually parallel relationship; air drying the sensing element for at least 12 hours; baking said sensing element to form between said wires a crystal lattice having interstitial spaces therein, said sensing element being baked at a temperature within the range of 1, 100* C up to the melting point of the crystal lattice being formed therein for a period of time in the range of 10 minutes to 2 hours; and cooling said sensing element to ambient temperature by first lowering its temperature to approximately 860* C and then quenching it.
Claim 10
Dependent Claim
69 words
The method defined in claim 10, wherein: said platinium-iridium wires are measured lengths of annealed platinium-10 percent iridium 4 mil wire, are embedded in said mixture approximately 5 mils apart and are positioned to have a side by side length alongside each other of approximately 75 mils; and said sensing element is baked in the presence of Al2O3 doping chips for 30 minutes at a temperature of 1,550* C.
Claim 11
Dependent Claim
175 words
The method defined in claim 11, wherein: the compounds Cr2O3 and V2O5 are ground into powders and are mixed by grinding; said sensing element is baked in a furnace, said sensing element being placed in said furnace when said furnace is at ambient temperature and the temperature of said furnace being increased to 1,550* C by injecting nitrogen gas under pressure into said furnace and supplying heat to increase the temperature of said furnace at the rate of 10* C per minute for forty minutes, exhausting said nitrogen gas, pumping dry air into said furnace and supplying heat to continue increasing the temperature of said furnace at the rate of 10* C per minute until the temperature of 860* C is reached, and then supplying heat to increase the temperature of said furnace at the rate of 20* C per minute until the baking temperature of 1,550* C is reached; and said sensing elements are cooled after baking to approximately 860* C by stopping the supply of heat to said furnace and cooling said furnace.
Claim 12
Dependent Claim
103 words
A moisture sensing element comprising a pair of electrodes held spaced apart by a crystal lattice formed by baking a mixture of V2O5 and Cr2O3, said crystal lattice being made of a subsTantially electrically neutral material and having interstitial spaces formed therein between said electrodes, said interstitial spaces being formed in said crystal lattice so that the molecules of atmosphere being monitored may randomly drift in and out of said crystal interstices whereby the volumetric resistance of said sensing element between said electrodes varies as a function of the percent of water vapor present in the molecules of atmosphere within said crystal interstices.
Claim 13
Dependent Claim
22 words
The invention defined in claim 13, wherein said mixture of V2O5 and Cr2O3 is baked in the presence of Al2O3 doping chips.
Claim 14
Dependent Claim
12 words
The invention defined in claim 13, wherein said electrodes are platinium-iridium wires.
Claim 15
Dependent Claim
174 words
A moisture sensing element comprising a pair of electrodes held spaced apart by a crystal lattice formed by baking a mixture of V2O5 and Cr2O3 in the presence of Al2O3 doping chips, said electrodes being annealed platinum - 10 percent iridium 4 mil wires which are positioned a predetermined distance apart alongside each other in a substantially mutually parallel realtionship to extend away from each other and have a side by side length alongside each other of approximately 75 mils, said electrodes being held spaced apart by approximately one layer of the crystals forming said crystal lattice, said crystal lattice being made of a substantially electrically neutral material and having interstitial spaces formed therein between said electrodes, said interstitial spaces being formed in said crystal lattice so that the molecules of atmosphere being monitored may randomly drift in and out said crystal interstices whereby the volumetric resistance of said sensing element between said electrodes varies as a function of the percent of water vapor present in the molecules of atmosphere within said crystal interstices.
Claim 16
Dependent Claim
21 words
The invention defined in claim 16 including a coating of glass frit formed around the body portion of said sensing element.
Claim 17
Dependent Claim
120 words
A moisture sensing element comprising a pair of electrodes held spaced apart by a crystal lattice, said crystal lattice having interstitial spaces formed therein between said electrodes and being made of a substantially electrically neutral semi-conducting solid state type material having a Fermi level approximately neutral so that water ions in the atmosphere are not attracted into nor repelled from said crystal interstices, said interstitial spaces being formed in said crystal lattice so that the molecules of atmosphere being monitored may randomly drift in and out said crystal interstices whereby the volumetric resistance of said sensing element between said electrodes varies as a function of the percent of water vapor present in the molecules of atmosphere within said crystal interstices.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1976-07-23 | 1977-01-22 | 1977-07-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1980-07-23 | 1981-01-22 | 1981-07-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1984-07-23 | 1985-01-22 | 1985-07-24 | $7700.00 | Window Closed / Lapsed |