Surface fluorinated hydrogen containing material and process for making

Abstract

Abstract A MANUFACTURED MATERIAL AND A PROCESS FOR MAKING THE MATERIAL IS DISCLOSED. THE MANUFACTURED MATERIAL IS A HYDROGEN CONTAINING SUBSTANCE HAVING A FLUORINATED SURFACE AND IN WHICH HYDROGEN ATOMS, WHICH MAY BE PRESENT IN HYDROXYL RADICALS ATTACHED TO A CARBON ATOM CHAIN, HAVE BEEN REPLACED IN THE SURFACE OF THE MATERIAL BY FLUORINE ATOMS OR RADICALS, AND WITH SUCH FLUORINATED SURFACE OF THE MATERIAL CONTAINING AT LEAST ABOUT 2 MICROGRAMS OF SUCH FLUORINE PER CM.2 OF SURFACE AREA. THE PROCESS FOR MAKING SUCH A MATERIAL INCLUDES THE STEPS OF SELECTING A SUBSTRATE CONTAINING HYDROGEN ATOMS WHICH MAY BE PRESENT IN HYDROXYL RADICALS ATTACHED TO A CARBON ATOM CHAIN, SELECTING A GAS CONTAINING FLUORINE ATOMS OR RADICALS, PLACING THE SELECTED SUBSTRATE BETWEEN ELECTRODES IN A FLOWING ATMOSPHERE OF THE SELECTED GAS AT SUBATMOSPHERIC PRESSURE, AND SUBJECTING THE SUBSTRATE TO AN ELECTROLESS DISCHARGE OF AT LEAST ABOUT 0.2 KWH./YARD2 TO CHEMI- CALLY ACTIVATE BOTH THE SURFACE OF THE SUBSTRATE AND THE GAS, AND EXCHANGE THE FLUORINE ATOMS OR RADICALS FOR SURFACE HYDROGEN ATOMS OR RADICALS TO PRODUCE A MATERIAL WITH A SURFACE, WHICH COMPARED TO THE SUBSTRATE BEFORE THIS PROCESS TREATMENT, IS MORE WATER REPELLENT (WITHOUT SEALING PORES), IS MORE CORROSION AND SOIL RESISTANT, MORE CHEMICALLY INERT, AND MORE LIKE THE RELATIVELY EXPENSIVE POLYTETRAFLUOROETHYLENE. WHEN THE SUBSTRATE IS A MATERIAL HAVING A RELATIVELY INERT SURFACE, SUCH AS POLYETHYLENE, THE PROCESS IS DISCLOSED AS INCLUDING AN INITIAL TREATMENT STEP THAT INVOLVES ION BOMBARDMENT OF THE SUBSTRATE IN HELIUM GAS TO ACTIVATE THE SURFACE BEFORE THE SURFACE IS TREATED IN THE FLUORINE CONTAINING GAS.

Inventors

• 👤 J Manion
• 👤 D Davies

Bibliographic Details