← Back to Patent Explorer
US3733476A Expired / Lapsed US ⏱️ 0.0 years remaining

Means and method for automatically controlling the hydrogen to hydrocarbon mole ratio during the conversion of a hydrocarbon

Assignee: Texaco Development Corp
•
Filing: 1972-05-30
•
Granted: 1973-05-15
•
Expires: 1992-05-30
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract In a hydrocarbon converting unit in a petroleum refinery, the hydrogen to hydrocarbon mole ratio is controlled in accordance with the following equation: WHERE VH is the volume percent hydrogen in recycle gas, Gg is the specific gravity of the recycle gas, Fg is the flow rate of the recycle gas, Gc is the specific gravity of charge oil, Fc is the charge oil flow rate, Mc is the average molecular weight of the charge oil and the term 13261.21 is a conversion factor. Signal means sample the charge oil and the recycle gas and provide signals corresponding to the specific gravity of the charge oil Gc and of the recycle gas Gg, the average molecular weight Mc of the charge oil and the quantity of hydrogen VH in the recycle gas. Flow transmitters sense the flow rates Fc and Fg of the charge oil and the recycle gas, respectively, and provide corresponding signals. An analog computer computes the hydrogen to hydrocarbon mole ratio in accordance with the aforementioned equation and the signals from the signal means and the flow transmitters and provides an output corresponding thereto. An error signal is developed using an output from the analog computer and a reference signal corresponding to a desired value for the hydrogen to hydrocarbon mole ratio. The error signal is used to control the hydrogen entering the hydrocarbon converting unit so as to maintain the hydrogen to hydrocarbon mole ratio at the desired value.

Inventors

  • 👤 W Hopkins
  • 👤 W White
  • 👤 L Champion

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 10:07
CPC Classifications
C; C10; C10G; C10G35/00; C10G35/24; Y; Y10; Y10S; Y10S208/00; Y10S208/01

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 308 words
A system for controlling the hydrogen to hydrocarbon mole ratio during the operation of a hydrocarbon converting unit, comprising means for sensing the flow rate Fc of the hydrocarbon and providing a corresponding signal, a pair of meters receiving some of the hydrocarbon, one meter providing a signal corresponding to the boiling point of the hydrocarbon, the other meter providing a signal corresponding to the API gravity of the hydrocarbon, means connected to the one meter for converting the signal from the one meter to a signal corresponding to the 50 percent boiling point of the hydrocarbon, computing means connected to the other meter and to the converting means for providing signal corresponding to the specific gravity Gc and the average molecular weight Mc of the hydrocarbon in accordance with the output from the other meter and from the converting means and the following equations: Gc (141.5/API + 131.5) Mc X + Y(API30) + Z(API-30)2, X 10(1.60783 .0016007(50%BP) .45(10 )(50%BP) ) Y 10( .4244 .00152X .45 )X) , Z -.0133+.516(10 4)(50% BP), where API is the API gravity, means for sensing hydrogen entering the hydrocarbon converting unit and providing corresponding signals, means connected to the computing means and to the hydrocarbon sensing means for providing a ratio signal corresponding to the hydrogen to hydrocarbon mole ratio in accordance with the signals from the hydrogen sensing means and the computing means, means for providing a reference signal corresponding to a predetermined hydrogen to hydrocarbon mole ratio, means connected to the ratio signal means and to the reference signal means for providing a signal corresponding to the difference between the ratio signal and the reference signal, and means connected to the signal difference means for controlling one of the entrants to the hydrocarbon converting unit in accordance with the signal so as to control the hydrogen to hydrocarbon mole ratio.
Claim 2
Independent Claim 308 words
A system for controlling the hydrogen to hydrocarbon mole ratio during the operation of a hydrocarbon converting unit, comprising means for sensing the flow rate Fc of the hydrocarbon and providing a corresponding signal, a pair of meters receiving some of the hydrocarbon, one meter providing a signal corresponding to the boiling point of the hydrocarbon, the other meter providing a signal corresponding to the API gravity of the hydrocarbon, means connected to the one meter for converting the signal from the one meter to a signal corresponding to the 50 percent boiling point of the hydrocarbon, computing means connected to the other meter and to the converting means for providing signal corresponding to the specific gravity Gc and the average molecular weight Mc of the hydrocarbon in accordance with the output from the other meter and from the converting means and the following equations: Gc (141.5/API + 131.5) Mc X + Y(API30) + Z(API-30)2, X 10(1.60783 .0016007(50%BP) .45(10 )(50%BP) ) Y 10( .4244 .00152X .45 )X) , Z -.0133+.516(10 4)(50% BP), where API is the API gravity, means for sensing hydrogen entering the hydrocarbon converting unit and providing corresponding signals, means connected to the computing means and to the hydrocarbon sensing means for providing a ratio signal corresponding to the hydrogen to hydrocarbon mole ratio in accordance with the signals from the hydrogen sensing means and the computing means, means for providing a reference signal corresponding to a predetermined hydrogen to hydrocarbon mole ratio, means connected to the ratio signal means and to the reference signal means for providing a signal corresponding to the difference between the ratio signal and the reference signal, and means connected to the signal difference means for controlling one of the entrants to the hydrocarbon converting unit in accordance with the signal so as to control the hydrogen to hydrocarbon mole ratio.
Claim 3
Dependent Claim 27 words
A system as described in claim 1 in which the controlled entrant is the hydrogen and is a constituent of a gas entering the hydrocarbon converting unit.
Claim 4
Dependent Claim 139 words
A system as described in claim 2 in which the hydrogen sensing means includes means connected to the ratio signal means for sensing the flow rate Fg of the gas containing the hydrogen and providing a corresponDing signal to the ratio signal means, chromatographic means for sampling the gas and providing signals corresponding to the percent volumes of different constituents of the gas, means connected to the chromatograph means and to the ratio signal means for conducting the signal corresponding to the percent volume of hydrogen VH in the gas from the chromatographic means to the ratio signal means, and first computing means connected to the chromatographic means and to the ratio signal for providing a signal corresponding to the specific gravity Gg of the gas in accordance with the signals from the chromatographic means and the following equation:
Claim 5
Dependent Claim 101 words
A system as described in claim 3 in which the ratio signal means provides the ratio signal in accordance with the signal from the hydrocarbon flow rate sensing means, the gas flow rate sensing means and the first and second computing means and the following equation: where VH is the percentage volume of hydrogen in the gas, Gg is the specific gravity of the gas, Fg is the rate of flow of the gas, Gc is the specific gravity of the hydrocarbon, Fc is the rate of flow of the hydrocarbon, and Mc is the average molecular weight of the hydrocarbon.
Claim 6
Independent Claim 253 words
A method for controlling the hydrogen to hydrocarbon mole ratio in a hydrocarbon converting unit, which comprises providing signals corresponding to hydrogen entering the hydrocarbon converting unit, sensing the flow rate Fc of hydrocarbon entering the hydrocarbon converting unit, providing a signal corresponding to the sensed hydrocarbon flow rate Fc, sensing the boiling point of the hydrocarbon, providing a signal corresponding to the 50 percent boiling point in accordance with the sensed boiling point, sensing the API gravity of the hydrocarbon, providing a signal corresponding to the sensed API gravity, providing a signal corresponding to the specific gravity Gc of the hydrocarbon in accordance with the API gravity signal in the following equation: Gc (141.5/API+131.5) where API is the API gravity, providing a signal corresponding to the average molecular weight Mc of the hydrocarbon in accordance with the API gravity signal, the 50 percent boiling point and the following equations: Mc X + Y(API-30)+Z(API-30)2 , X 10(1.60783 .0016007(50%) .45(10 )(50%) ) , Y 10( .4244 .00152X .45(10 )X ) , Z .0133+.516(10 4)(50%) determining the ratio of hydrogen to hydrocarbon in accordance with the sensed hydrogen signals, the hydrocarbon flow rate Fc signal and the hydrocarbon specific gravity Gc and molecular weight Mc signals; providing a reference signal corresponding to a predetermined hydrogen to hydrocarbon mole ratio, providing an error signal corresponding to the difference between the ratio signal and the reference signal; and controlling the quantity of one of the entrants to the hydrocarbon converting unit in accordance with the error signal.
Claim 7
Independent Claim 253 words
A method for controlling the hydrogen to hydrocarbon mole ratio in a hydrocarbon converting unit, which comprises providing signals corresponding to hydrogen entering the hydrocarbon converting unit, sensing the flow rate Fc of hydrocarbon entering the hydrocarbon converting unit, providing a signal corresponding to the sensed hydrocarbon flow rate Fc, sensing the boiling point of the hydrocarbon, providing a signal corresponding to the 50 percent boiling point in accordance with the sensed boiling point, sensing the API gravity of the hydrocarbon, providing a signal corresponding to the sensed API gravity, providing a signal corresponding to the specific gravity Gc of the hydrocarbon in accordance with the API gravity signal in the following equation: Gc (141.5/API+131.5) where API is the API gravity, providing a signal corresponding to the average molecular weight Mc of the hydrocarbon in accordance with the API gravity signal, the 50 percent boiling point and the following equations: Mc X + Y(API-30)+Z(API-30)2 , X 10(1.60783 .0016007(50%) .45(10 )(50%) ) , Y 10( .4244 .00152X .45(10 )X ) , Z .0133+.516(10 4)(50%) determining the ratio of hydrogen to hydrocarbon in accordance with the sensed hydrogen signals, the hydrocarbon flow rate Fc signal and the hydrocarbon specific gravity Gc and molecular weight Mc signals; providing a reference signal corresponding to a predetermined hydrogen to hydrocarbon mole ratio, providing an error signal corresponding to the difference between the ratio signal and the reference signal; and controlling the quantity of one of the entrants to the hydrocarbon converting unit in accordance with the error signal.
Claim 8
Dependent Claim 29 words
A method as described in claim 5 in which the controlled entrant is the hydrogen and the hydrogen is a constituent of a gas entering the hydrocarbon converting unit.
Claim 9
Dependent Claim 109 words
A method as described in claim 6 in which the step of providing signals corresponding to the hydrogen entering the hydrocarbon converting unit includes sensing the flow rate Fg of the gas containing the hydrogen, providing a signal corresponding to the sensed flow rate Fg of the gas, sensing the percent volume of different constituents of the gas, providing a signal corresponding to the sensed percent volume VH of hydrOgen in the gas, providing signals corresponding to the percent volumes of the other constituents of the gas, providing a signal corresponding to the specific gravity Gg of the gas in accordance with the constituents signals and the following equation:
Claim 10
Independent Claim 281 words
A device adapted to receive oil and to receive voltages for providing signals substantially corresponding to the molecular weight and to the specific gravity of the oil, comprising means for sensing the 50 percent boiling point and the API gravity of the received oil and providing signals thereto, a pair of sample and hold circuits, connected to the sensing means and controlled by a received voltage, one sample and hold circuit periodically samples and holds the signal from the sensing means corresponding to the 50 percent boiling point of the oil to provide an output, while the other sample and hold circuit periodically samples and holds the signal from the sensing means corresponding to API gravity of the oil to provide an output, and a computing network connected to the pair of sample and hold circuits for providing the signal substantially corresponding to the molecular weight Mc of the received oil in accordance with the outputs from the sample and hold circuits, some of the received voltages and the following equations: Mc X + Y(API-30) + Z(API-30)2 Z -.0133 + .0000516(50%) X 10(1.60783 .0016007(50%) .45(10 )(50%) ), and Y 10( .4244 .00152X .45(10 )X ) where API is the API gravity of the received oil, and 50 percent is the 50 percent boiling point of the received oil; and a second computing network connected to the other sample and hold circuit for a signal corresponding to the specific gravity Gc of the oil in accordance with the output corresponding to the API gravity from the other sample and hold circuit, some of the received voltages and the following equation: Gc (141.5/API+131.5) . where API is the API gravity of the hydrocarbon.
Claim 11
Independent Claim 281 words
A device adapted to receive oil and to receive voltages for providing signals substantially corresponding to the molecular weight and to the specific gravity of the oil, comprising means for sensing the 50 percent boiling point and the API gravity of the received oil and providing signals thereto, a pair of sample and hold circuits, connected to the sensing means and controlled by a received voltage, one sample and hold circuit periodically samples and holds the signal from the sensing means corresponding to the 50 percent boiling point of the oil to provide an output, while the other sample and hold circuit periodically samples and holds the signal from the sensing means corresponding to API gravity of the oil to provide an output, and a computing network connected to the pair of sample and hold circuits for providing the signal substantially corresponding to the molecular weight Mc of the received oil in accordance with the outputs from the sample and hold circuits, some of the received voltages and the following equations: Mc X + Y(API-30) + Z(API-30)2 Z -.0133 + .0000516(50%) X 10(1.60783 .0016007(50%) .45(10 )(50%) ), and Y 10( .4244 .00152X .45(10 )X ) where API is the API gravity of the received oil, and 50 percent is the 50 percent boiling point of the received oil; and a second computing network connected to the other sample and hold circuit for a signal corresponding to the specific gravity Gc of the oil in accordance with the output corresponding to the API gravity from the other sample and hold circuit, some of the received voltages and the following equation: Gc (141.5/API+131.5) . where API is the API gravity of the hydrocarbon.

References Cited (Backward Citations)

US3213014A Cited
US3497449A Cited
US3539784A Cited
US3540996A Cited
US3520800A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-05-14 1976-11-13 1977-05-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-05-14 1980-11-13 1981-05-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-05-14 1984-11-13 1985-05-15 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag