US3728116A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Instant access one-layer color photography
Assignee: GAF Corp
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Filing: 1971-06-15
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Granted: 1973-04-17
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Expires: 1991-06-15
Abstract
Abstract An improved instant access diffusion transfer process for photographic materials in which multicolor dye images are produced in a transfer sheet by exposing a panchromatically sensitized silver halide emulsion through a single multicolor screening layer and subsequently developing the emulsion at a high pH and transferring it to an unsensitized receiving sheet.
Inventors
- 👤 B Waxman
- 👤 R Shannahan
- 👤 F Viro
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 02:13
CPC Classifications
G; G03; G03C; G03C8/00; G03C8/30; Y; Y10; Y10S; Y10S430/00; Y10S430/142
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
349 words
An instant access multicolor reproduction process utilizing a photographic element carrying on a suitable transparent base in the following order a single red, green and blue screen layer in contiguous contact with a panchromatic silver halide emulsion layer, said process comprising (1) imagewise exposing to actinic light the panchromatically sensitized silver halide emulsion layer through the red, green, blue multi-colored screen layer, said screen layer being made up of three separate oil droplet dispersions, each containing a non-diffusible filter dye having one of the primary colors red, green or blue and containing in addition a color former which becomes diffusible at a pH of at least 12.5 and which is capable of reacting with the oxidation products of a paraphenylenediamine color developer to form a non-diffusible dye complementary in color to the primary color of the dye in the oil droplet, said color formers being free from water solubilizing groups but sufficiently oil soluble to be incorporated in an oily packet but containing a group which at a pH of at least 12.5 is capable of rendering the color former soluble in the developer solution, the imagewise exposure being sufficient to ensure maximum density in the silver halide emulsion upon color development in those areas of the emulsion receiving maximum exposure (2) color developing the emulsion in a paraphenylenediamine developer solution of a pH below 12.5 to produce maximum image density with complete conversion of the color formers to non-diffusible dye images in the areas of maximum density to pressing the negative photosensitive element into contact with a receiving sheet in the contiguous presence of an alkaline color developer solution of pH of at least 12.5, the higher alkalinity causing diffusion of the color formers from the oil droplets into the emulsion layer, thereby imagewise immobilizing the color formers in the exposed areas by coupling action with oxidized developer, and permitting the diffusion of the residual non-coupled color former and developer solution into an unsensitized image receiving layer which contains an encapsulated oxidizer thus permitting oxidation of developer and coupler to form a positive dye image in the layer.
Claim 2
Dependent Claim
29 words
The process of claim 1 wherein the exposed element and the receiving sheet are presoaked for a short time in said developer solution before being pressed into physical contact.
Claim 3
Dependent Claim
30 words
The process of claim 2 wherein the exposed element and the receiving sheet are presoaked for a short time in said developer solution before being prEssed into intimate physical contact.
Claim 4
Dependent Claim
16 words
The process of claim 3 wherein said developer solution has a pH of 12.5 - 13.
Claim 5
Dependent Claim
16 words
The process of claim 3 wherein said developer solution has a pH of 12.5 - 13.
Claim 6
Dependent Claim
12 words
The process of claim 3 wherein the presoak time is 3-5 seconds.
Claim 7
Dependent Claim
12 words
The process of claim 4 wherein the presoak time is 3-5 seconds.
Claim 8
Dependent Claim
12 words
The process of claim 1 wherein developer contact time is 1 minute.
Claim 9
Dependent Claim
12 words
The process of claim 2 wherein developer contact time is 1 minute.
Claim 10
Dependent Claim
158 words
A light sensitive photographic material carrying on a transparent film base in the following order a colloidal layer having dispersed therein an encapsulated oxidizing agent, followed by a second colloidal layer to serve as a receiving layer, said receiving layer being overcoated by a peelable polymer layer of polyvinyl alcohol capable of delaminating from the receiving layer at the end of processing, said peelable layer being overcoated by a panchromatically sensitized silver halide emulsion layer which is in contiguous contact with a multicolor screening layer made of red, green and blue colored oil droplets, each droplet containing a non-diffusing dye having one of the primary colors in addition to a color former which becomes diffusing at a pH of at least 12.5 and is capable of forming upon coupling with the oxidation products of a paraphenylenediamine color developer a non-diffusing dye complementary in color to the dye of the oil droplet in which said color former was contained.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1976-04-16 | 1976-10-16 | 1977-04-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1980-04-16 | 1980-10-16 | 1981-04-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1984-04-16 | 1984-10-16 | 1985-04-17 | $7700.00 | Window Closed / Lapsed |