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US3726710A Expired / Lapsed US ⏱️ 0.0 years remaining

Silicon paper release compositions

Assignee: Union Carbide Corp
•
Filing: 1970-09-02
•
Granted: 1973-04-10
•
Expires: 1990-09-02
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Abstract

Abstract Curable silicone release compositions comprising a crosslinkable olefinic containing organopolysiloxane compound and a photosensitizer and a paper substrate coated therewith; a process for preparing silicone paper release articles comprising subjecting said compositions coated on a paper substrate to high intensity predominantly continuum light radiation in order to crosslink the siloxane; and the silicone paper release articles obtained by said process.

Inventors

  • 👤 S Berger
  • 👤 T Williams

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 05:11
CPC Classifications
B; B44; B44C; B44C1/00; B44C1/16; B44C1/165; B44C1/17; B44C1/1708; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31652; Y10T428/31663

Claims Analysis

Total Claims: 29
Claim 1
Independent Claim 40 words
A composition as defined in claim 1 wherein R is a member selected from the group consisting of alkyl and phenyl radicals and wherein the olefinic radical is selected from the group consisting of vinyl, allyl, cyclohexenyl and methacryloxypropyl radicals.
Claim 2
Dependent Claim 31 words
A composition as defined in claim 1 wherein the organopolysiloxane consists essentially of dimethyl siloxy units and at least two methylvinyl siloxy units per polymer molecule and terminal trimethyl siloxy units.
Claim 3
Dependent Claim 18 words
A composition as defined in claim 1, wherein an inert organic solvent is present as an additional ingredient.
Claim 4
Dependent Claim 12 words
A composition as defined in claim 1, wherein the photosensitizer is benzophenone.
Claim 5
Dependent Claim 15 words
A composition as defined in claim 1, wherein the olefinic radical is a vinyl radical.
Claim 6
Dependent Claim 15 words
A paper substrate coated with a curable silicone release composition as defined in claim 1.
Claim 7
Dependent Claim 15 words
A paper substrate coated with a curable silicone release composition as defined in claim 2.
Claim 8
Dependent Claim 15 words
A paper substrate coated with a curable silicone release composition as defined in claim 3.
Claim 9
Dependent Claim 15 words
A paper substrate coated with a curable silicone release composition as defined in claim 4.
Claim 10
Dependent Claim 15 words
A paper substrate coated with a curable silicone release composition as defined in claim 5.
Claim 11
Dependent Claim 15 words
A paper substrate coated with a curable silicone release composition as defined in claim 6.
Claim 12
Dependent Claim 101 words
A process for preparing silicone paper release articles comprising applying the release composition as defined in claim 1, to a paper substrate and exposing the composition to high intensity predominantly continuum light radiation having a source intensity of at least about 350 watts per square centimeter steradian when integrated throughout the entire spectral range of said continuum light radiation with a positive amount of up to 30 percent of the total light radiated at wavelengths shorter than 4,000 Angstrom units and at least 70 percent of the light radiated at wavelengths longer than 4,000 Angstrom units to crosslink the siloxane compound.
Claim 13
Dependent Claim 24 words
A process as defined in claim 13, wherein the source of said high intensity predominantly continuum light radiation is a swirl-flow plasma arc means.
Claim 14
Dependent Claim 100 words
A process for preparing silicone paper release articles comprising applying the release composition as defined in claim 2, to a paper substrate and exposing the composition to high intensity predominantly continuum light radiation having a source intensity of at least about 350 watts per square centimeter steradian when integrated throughout the entire spectral range of said continuum light radiation with a positive amount of up to 30 percent of the light radiated at wavelengths shorter than 4,000 Angstrom units and at least 70 percent of the light radiated at wavelengths longer than 4,000 Angstrom units to crosslink the siloxane compound.
Claim 15
Dependent Claim 24 words
A process as defined in claim 15, wherein the source of said high intensity predoMinately continuum light radiation is a swirl-flow plasma arc means.
Claim 16
Dependent Claim 100 words
A process for preparing silicone paper release articles comprising applying the release composition as defined in claim 3, to a paper substrate and exposing the composition to high intensity predominantly continuum light radiation having a source intensity of at least about 350 watts per square centimeter steradian when integrated throughout the entire spectral range of said continuum light radiation with a positive amount of up to 30 percent of the light radiated at wavelengths shorter than 4,000 Angstrom units and at least 70 percent of the light radiated at wavelengths longer than 4,000 Angstrom units to crosslink the siloxane compound.
Claim 17
Dependent Claim 24 words
A process as defined in claim 17, wherein the source of said high intensity predominantly continuum light radiation is a swirl-flow plasma arc means.
Claim 18
Dependent Claim 100 words
A process for preparing silicone paper release articles comprising applying the release composition as defined in claim 4, to a paper substrate and exposing the composition to high intensity predominantly continuum light radiation having a source intensity of at least about 350 watts per square centimeter steradian when integrated throughout the entire spectral range of said continuum light radiation with a positive amount of up to 30 percent of the light radiated at wavelengths shorter than 4,000 Angstrom units and at least 70 percent of the light radiated at wavelengths longer than 4,000 Angstrom units to crosslink the siloxane compound.
Claim 19
Dependent Claim 24 words
A process as defined in claim 19, wherein the source of said high intensity predominantly continuum light radiation is a swirl-flow plasma arc means.
Claim 20
Dependent Claim 99 words
A process for preparing silicone paper release articles comprising applying the release composition as defined in claim 5, to a paper substrate and exposing the composition to high intensity predominantly continuum light radiation having a source intensity of at least about 350 watts per square centimeter steradian when integrated throughout the entire spectral range of said continuum light radiation with a positive amount of up to 30 percent of the light radiated at wavelengths shorter than 4,000 Angstrom units and at least 70 percent of the light-radiated at wavelengths longer than 4,000 Angstrom units to crosslink the siloxane compound.
Claim 21
Dependent Claim 24 words
A process as defined in claim 21 wherein the source of said high intensity predominantly continuum light radiation is a swirl-flow plasma arc means.
Claim 22
Dependent Claim 100 words
A process for preparing silicone paper release articles comprising applying the release composition as defined in claim 6, to a paper substrate and exposing the composition to high intensity predominantly continuum light radiation having a source intensity of at least about 350 watts per square centimeter steradian when integrated throughout the entire spectral range of said continuum light radiation with a positive amount of up to 30 percent of the light radiated at wavelengths shorter than 4,000 Angstrom units and at least 70 percent of the light radiated at wavelengths longer than 4,000 Angstrom units to crosslink the siloxane compound.
Claim 23
Dependent Claim 24 words
A process as defined in claim 23, wherein the source of said high intensity predominantly continuum light radiation is a swirl-flow plasma arc means.
Claim 24
Dependent Claim 15 words
A silicone paper release article prepared according to the process as defined in claim 14.
Claim 25
Dependent Claim 15 words
A silicone paper release article prepared according to the process as defined in claim 15.
Claim 26
Dependent Claim 15 words
A silicone paper release article prepared according to the process as defined in claim 17.
Claim 27
Dependent Claim 15 words
A silicone paper release article prepared according to the process as defined in claim 19.
Claim 28
Dependent Claim 15 words
A silicone paper release article prepared according to the process as defined in claim 21.
Claim 29
Dependent Claim 15 words
A silicone paper release article prepared according to the process as defined in claim 23.

References Cited (Backward Citations)

US2413973A Cited
US3096303A Cited
US2940875A Cited
US3076726A Cited
US3157560A Cited
US3385727A Cited
US3527659A Cited
US3436252A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-04-09 1976-10-09 1977-04-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-04-09 1980-10-09 1981-04-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-04-09 1984-10-09 1985-04-10 $7700.00 Window Closed / Lapsed

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