US3725306A
Expired / Lapsed
US
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Nickel carbonyl complex catalyst
Assignee: Atlantic Richfield Co
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Filing: 1970-06-25
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Granted: 1973-04-03
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Expires: 1990-06-25
Abstract
Abstract Novel heterogeneous, nickel-containing catalysts comprising A. A nickel carbonyl complex, and B. An acidic, solid, silica-based material are active in numerous reactive environments such as oligomerization, including homo- and co-dimerization, and polymerization of various olefins. In specific aspects, bis (triphenylphosphine) nickel dicarbonyl supported on an acidic, calcined, silica-alumina support containing a separate alumina phase, is active in, for instance, the oligomerization, particularly dimerization, of ethylene and propylene, the codimerization of a conjugated diene and an alphaolefin and the polymerization of conjugated dienes.
Inventors
- 👤 J Yoo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 09:47
CPC Classifications
B; B01; B01J; B01J31/00; B01J31/16; B01J31/18; B01J31/1616; B01J31/20; B01J31/24; B01J31/2404; C; C07; C07C; C07C2/00; C07C2/02; C07C2/04; C07C2/06; C07C2/08; C07C2/26; C07C2/36; C08; C08F; C08F36/00; C08F36/02; C08F36/04; B01J21/00; B01J21/06; B01J21/08; B01J21/12; B01J2231/00; B01J2231/10; B01J2231/12; B01J2231/20; B01J2231/30; B01J2231/32; B01J2231/323; B01J2531/00; B01J2531/80; B01J2531/84; B01J2531/847; C07C2521/00; C07C2521/06; C07C2521/08; C07C2521/12; C07C2531/00; C07C2531/16; C07C2531/22; C07C2531/24; Y; Y10; Y10S; Y10S585/00; Y10S585/8995; Y10S585/906
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
20 words
A catalyst composition of claim 1 wherein the weight ratio of (b) to (a) is from about 2 to 2000:1.
Claim 2
Dependent Claim
18 words
A catalyst composition of claim 1 wherein the nickel complex is a bis(tertiary, hydrocarbyl-substituted monophosphine) nickel dicarbonyl complex.
Claim 3
Dependent Claim
24 words
A catalyst composition of claim 3 wherein each hydrocarbyl substituent of the monophosphine is a hydrocarbyl group of up to about 20 carbon atoms.
Claim 4
Dependent Claim
12 words
A catalyst composition of claim 4 wherein each hydrocarbyl group is phenyl.
Claim 5
Dependent Claim
20 words
A catalyst composition of claim 5 wherein the weight ratio of (b) to (a) is from about 5 to 200:1.
Claim 6
Dependent Claim
20 words
A catalyst composition of claim 1 wherein the silica-based support material is calcined and has a separate, additional alumina phase.
Claim 7
Dependent Claim
33 words
A catalyst composition of claim 6 wherein the silica-based support material is calcined, has a separate, additional alumina phase and has a surface area of about 150 to 400 square meters per gram.
Claim 8
Dependent Claim
46 words
A catalyst composition of claim 1 wherein the support is comprised of about 45 to 95 weight percent amorphous silica-alumina and about 5 to 55 weight percent of a separate alumina phase, the total alumina content of said support being about 20 to 70 weight percent.
Claim 9
Dependent Claim
30 words
A catalyst composition of claim 9 wherein said alumina results from the calcination of a member selected from the group consisting of amorphous hydrous alumina, alumina monohydrate and mixtures thereof.
Claim 10
Dependent Claim
46 words
A catalyst composition of claim 2 wherein the support is comprised of about 45 to 95 weight percent amorphous silica-alumina and about 5 to 55 weight percent of a separate alumina phase, the total alumina content of said support being about 20 to 70 weight percent.
Claim 11
Dependent Claim
30 words
A catalyst composition of claim 11 wherein said alumina results from the calcination of a member selected from the group consisting of amorphous hydrous alumina, alumina monohydrate and mixtures thereof.
Claim 12
Dependent Claim
46 words
A catalyst composition of claim 3 wherein the support is comprised of about 45 to 95 weight percent amorphous silica-alumina and about 5 to 95 weight percent of a separate alumina phase, the total alumina content of said support being about 20 to 70 WEIGHT percent.
Claim 13
Dependent Claim
30 words
A catalyst composition of claim 13 wherein said alumina results from the calcination of a member selected from the group consisting of amorphous hydrous alumina, alumina monohydrate and mixtures thereof.
Claim 14
Dependent Claim
46 words
A catalyst composition of claim 5 wherein the support is comprised of about 45 to 95 weight percent amorphous silica-alumina and about 5 to 55 weight percent of a separate alumina phase, the total alumina content of said support being about 20 to 70 weight percent.
Claim 15
Dependent Claim
30 words
A catalyst composition of claim 15 wherein said alumina results from the calcination of a member selected from the group consisting of amorphous hydrous alumina, alumina monohydrate and mixtures thereof.
Claim 16
Dependent Claim
46 words
A catalyst composition of claim 6 wherein the support is comprised of about 45 to 95 weight percent amorphous silica-alumina and about 5 to 55 weight percent of a separate alumina phase, the total alumina content of said support being about 20 to 70 weight percent.
Claim 17
Dependent Claim
30 words
A catalyst composition of claim 17 wherein said alumina results from the calcination of a member selected from the group consisting of amorphous hydrous alumina, alumina monohydrate and mixtures thereof.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1976-04-02 | 1976-10-02 | 1977-04-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1980-04-02 | 1980-10-02 | 1981-04-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1984-04-02 | 1984-10-02 | 1985-04-03 | $7700.00 | Window Closed / Lapsed |