US3722977A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Optical scattering filter
Assignee: Beckman Coulter Inc
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Filing: 1971-08-30
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Granted: 1973-03-27
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Expires: 1991-08-30
Abstract
Abstract Long pass optical filters for the infrared region and methods of making the same are disclosed which utilize a transmitting matrix of high and low refractive index materials for selectively scattering all wavelengths shorter than a critical wavelength and which have a relatively sharp cut-on front. By the inclusion of materials having absorption bands at wavelengths longer than the cut-on wavelength of the scattering medium, the cut-on front may be sharpened and positioned over a wide range to provide a filter having a preselected cut-on wavelength and cut-on front.
Inventors
- 👤 H Sloane
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 11:47
CPC Classifications
G; G02; G02B; G02B5/00; G02B5/20; G02B5/206; G02B5/22
Claims Analysis
Total Claims: 32
Claim 1
Independent Claim
99 words
An optical filter having relatively high transmission to infrared radiation comprising: a thin transmitting wafer comprising a microporous material producing selective scattering of all wavelengths shorter than a selected wavelength, said wafer (i) having a relatively sharp cut-on front, (ii) being substantially opaque to radiation of wavelengths shorter than said selected wavelength and (iii) being highly transmissive to radiation of wavelengths longer than said cut-on front; and at least one absorbing material having an absorption band in the shorter wavelength transmission region of said wafer, said material absorbing at least a portion of the energy transmitted by said wafer.
Claim 2
Dependent Claim
99 words
An optical filter having relatively high transmission to infrared radiation comprising: a thin transmitting wafer comprising a microporous material producing selective scattering of all wavelengths shorter than a selected wavelength, said wafer (i) having a relatively sharp cut-on front, (ii) being substantially opaque to radiation of wavelengths shorter than said selected wavelength and (iii) being highly transmissive to radiation of wavelengths longer than said cut-on front; and at least one absorbing material having an absorption band in the shorter wavelength transmission region of said wafer, said material absorbing at least a portion of the energy transmitted by said wafer.
Claim 3
Dependent Claim
63 words
An optical filter having relatively high transmission to infrared radiation comprising: a thin transmitting wafer comprising a microporous material producing selective scattering of all wavelengths shorter than a selected wavelength; and at least one absorbing material having an absorption band in the shorter wavelength transmission region of said wafer, said material absorbing at least a portion of the energy transmitted by said wafer.
Claim 4
Dependent Claim
63 words
An optical filter having relatively high transmission to infrared radiation comprising: a thin transmitting wafer comprising a microporous material producing selective scattering of all wavelengths shorter than a selected wavelength; and at least one absorbing material having an absorption band in the shorter wavelength transmission region of said wafer, said material absorbing at least a portion of the energy transmitted by said wafer.
Claim 5
Dependent Claim
70 words
An optical filter having relatively high transmission to infrared radiation comprising: a polyethylene matrix having micron size pores of substantially uniform diameter substantially evenly distributed therethrough, said matrix being substantially opaque to all wavelengths shorter than a first wavelength; and at least one material having an absorption band in the shorter wavelength transmission region of said matrix and absorbing at least a portion of the energy transmitted by said matrix.
Claim 6
Dependent Claim
70 words
An optical filter having relatively high transmission to infrared radiation comprising: a polyethylene matrix having micron size pores of substantially uniform diameter substantially evenly distributed therethrough, said matrix being substantially opaque to all wavelengths shorter than a first wavelength; and at least one material having an absorption band in the shorter wavelength transmission region of said matrix and absorbing at least a portion of the energy transmitted by said matrix.
Claim 7
Dependent Claim
132 words
An optical filter having relatively high transmission to infrared radiation comprising: a polyethylene matrix having substantially evenly distributed pores therein of substantially uniform diameters, said matrix being substantially opaque to radiation of wavelengths shorter than a first wavelength and having a relatively sharp cut-on front and being highly transmissive to radiation of wavelengths longer than said cut-on front; and a plurality of absorbing materials having overlapping absorption bands of such intensity that the region from a second wavelength to a third wavelength is substantially opaque, said second wavelength being shorter than said first wavelength and said third wavelength being longer than said first wavelength such that said filter is substantially opaque to radiation of wavelengths shorter than said third wavelength, said materials positioned to absorb radiation between said second and third wavelengths.
Claim 8
Dependent Claim
132 words
An optical filter having relatively high transmission to infrared radiation comprising: a polyethylene matrix having substantially evenly distributed pores therein of substantially uniform diameters, said matrix being substantially opaque to radiation of wavelengths shorter than a first wavelength and having a relatively sharp cut-on front and being highly transmissive to radiation of wavelengths longer than said cut-on front; and a plurality of absorbing materials having overlapping absorption bands of such intensity that the region from a second wavelength to a third wavelength is substantially opaque, said second wavelength being shorter than said first wavelength and said third wavelength being longer than said first wavelength such that said filter is substantially opaque to radiation of wavelengths shorter than said third wavelength, said materials positioned to absorb radiation between said second and third wavelengths.
Claim 9
Dependent Claim
135 words
An optical filter having relatively high transmission to infrared radiation comprising the combination of: a first matrix of polyethylene having micron size pores of substantially uniform diameter suBstantially evenly distributed therethrough, said matrix being substantially opaque to radiation of wavelengths shorter than a first wavelength; having a relatively sharp cut-on front and being highly transmissive to radiation longer than said cut-on front; and at least a second matrix having at least one finely divided material evenly distributed therethrough, said finely divided material having an absorption band that is substantially opaque between a first and second wavelength, said second wavelength being shorter than said first wavelength and said third wavelength being longer than said first wavelength, said second matrix having no significant absorption bands in the region from said third wavelength to at least 300 microns.
Claim 10
Dependent Claim
135 words
An optical filter having relatively high transmission to infrared radiation comprising the combination of: a first matrix of polyethylene having micron size pores of substantially uniform diameter suBstantially evenly distributed therethrough, said matrix being substantially opaque to radiation of wavelengths shorter than a first wavelength; having a relatively sharp cut-on front and being highly transmissive to radiation longer than said cut-on front; and at least a second matrix having at least one finely divided material evenly distributed therethrough, said finely divided material having an absorption band that is substantially opaque between a first and second wavelength, said second wavelength being shorter than said first wavelength and said third wavelength being longer than said first wavelength, said second matrix having no significant absorption bands in the region from said third wavelength to at least 300 microns.
Claim 11
Dependent Claim
115 words
An optical filter having relatively high transmission to infrared radiation comprising: a polyethylene matrix having micron size pores of substantially uniform diameter substantially evenly dispersed therethrough; at least a second matrix; and a plurality of absorbing materials having overlapping absorption bands of intensity such that the region between a second wavelength and a third wavelength is substantially opaque, said second wavelength being shorter than said first wavelength and said third wavelength being longer than said first wavelength, each of said plurality of absorbing materials being finely divided and substantially evenly dispersed throughout said second matrix, said second matrix having no significant absorption bands in the region from said third wavelength to at least 300 microns.
Claim 12
Dependent Claim
115 words
An optical filter having relatively high transmission to infrared radiation comprising: a polyethylene matrix having micron size pores of substantially uniform diameter substantially evenly dispersed therethrough; at least a second matrix; and a plurality of absorbing materials having overlapping absorption bands of intensity such that the region between a second wavelength and a third wavelength is substantially opaque, said second wavelength being shorter than said first wavelength and said third wavelength being longer than said first wavelength, each of said plurality of absorbing materials being finely divided and substantially evenly dispersed throughout said second matrix, said second matrix having no significant absorption bands in the region from said third wavelength to at least 300 microns.
Claim 13
Dependent Claim
107 words
An optical filter having relatively high transmission to infrared radiation and a cut-on wavelength in the region from approximately 14 to 150 microns comprising: a matrix having micron size pores of substantially uniform diameter substantially evenly distributed therethrough for scattering radiation of wavelengths shorter than a preselected wavelength and transmitting radiation longer than said preselected wavelength; and at least one material having an absorption band in the region of wavelengths longer than said preselected wavelength selected from the group BaCO3, BaF2, BeO, CaCO3, Li2CO3, LiF, SrF2, TiO2 and freshly smoked MgO, said material positioned to absorb radiation in the region of wavelengths longer than said preselected wavelength.
Claim 14
Dependent Claim
107 words
An optical filter having relatively high transmission to infrared radiation and a cut-on wavelength in the region from approximately 14 to 150 microns comprising: a matrix having micron size pores of substantially uniform diameter substantially evenly distributed therethrough for scattering radiation of wavelengths shorter than a preselected wavelength and transmitting radiation longer than said preselected wavelength; and at least one material having an absorption band in the region of wavelengths longer than said preselected wavelength selected from the group BaCO3, BaF2, BeO, CaCO3, Li2CO3, LiF, SrF2, TiO2 and freshly smoked MgO, said material positioned to absorb radiation in the region of wavelengths longer than said preselected wavelength.
Claim 15
Dependent Claim
120 words
An optical filter having relatively high transmission to infrared radiation and a cut-on wavelength in the region from approximately 14 to 150 microns comprising: a matrix having micron size pores of substantially uniform diameter substantially evenly distributed therethrough for scattering wavelengths shorter than a preselected wavelength and transmitting radiation longer than said preselected wavelength; and a plurality of absorbing materials having absorption bands in the region of wavelengths longer than said preselected wavelength, said materials being substantially evenly distributed throughout a matrix, at least one of said materials selected from the group BaCO3, BaF2, BeO, CaCO3, Li2CO3, LiF, SrF2, TiO2 and freshly smoked MgO, said materials positioned to absorb radiation in the region of wavelengths longer than said preselected wavelength.
Claim 16
Dependent Claim
120 words
An optical filter having relatively high transmission to infrared radiation and a cut-on wavelength in the region from approximately 14 to 150 microns comprising: a matrix having micron size pores of substantially uniform diameter substantially evenly distributed therethrough for scattering wavelengths shorter than a preselected wavelength and transmitting radiation longer than said preselected wavelength; and a plurality of absorbing materials having absorption bands in the region of wavelengths longer than said preselected wavelength, said materials being substantially evenly distributed throughout a matrix, at least one of said materials selected from the group BaCO3, BaF2, BeO, CaCO3, Li2CO3, LiF, SrF2, TiO2 and freshly smoked MgO, said materials positioned to absorb radiation in the region of wavelengths longer than said preselected wavelength.
Claim 17
Dependent Claim
109 words
An optical filter having relatively high transmission to infrared radiation and a cut-on wavelength in the region below 150 microns comprising: a polyethylene matrix having micron size pores of substantially uniform diameter substantially evenly dispersed therethrough, said matrix being substantially opaque to all wavelengths shorter than a first wavelength in the regions from approximately 14 to 35 microns; and at least one material having an absorption band in the region of wavelengths longer than said first wavelength selected from the group BaCO3, BaF2, BeO, CaCO3, Li2CO3, LiF, SrF2, TiO2 and freshly smoked MgO, said material positioned to absorb radiation in the region of wavelengths longer than said first wavelength.
Claim 18
Dependent Claim
109 words
An optical filter having relatively high transmission to infrared radiation and a cut-on wavelength in the region below 150 microns comprising: a polyethylene matrix having micron size pores of substantially uniform diameter substantially evenly dispersed therethrough, said matrix being substantially opaque to all wavelengths shorter than a first wavelength in the regions from approximately 14 to 35 microns; and at least one material having an absorption band in the region of wavelengths longer than said first wavelength selected from the group BaCO3, BaF2, BeO, CaCO3, Li2CO3, LiF, SrF2, TiO2 and freshly smoked MgO, said material positioned to absorb radiation in the region of wavelengths longer than said first wavelength.
Claim 19
Dependent Claim
77 words
An optical filter having relatively high transmission to infrared radiation comprising: a thin transmitting wafer comprising a matrix having micron size pores of substantially uniform diameter substantially evenly distributed therethrough, said wafer producing selective scattering of all wavelengths shorter than a selected wavelength; and at least one non-hygroscopic absorbing material having an absorption band in the shorter wavelength transmission region of said wafer, said material absorbing at least a portion of the energy transmitted by said wafer.
Claim 20
Dependent Claim
77 words
An optical filter having relatively high transmission to infrared radiation comprising: a thin transmitting wafer comprising a matrix having micron size pores of substantially uniform diameter substantially evenly distributed therethrough, said wafer producing selective scattering of all wavelengths shorter than a selected wavelength; and at least one non-hygroscopic absorbing material having an absorption band in the shorter wavelength transmission region of said wafer, said material absorbing at least a portion of the energy transmitted by said wafer.
Claim 21
Dependent Claim
21 words
An optical filter according to claim 10 wherein said absorbing materials are substantially evenly distributed through a second thin transmitting wafer.
Claim 22
Dependent Claim
12 words
An optical filter according to claim 10 wherein said matrix is polyethylene.
Claim 23
Dependent Claim
75 words
An optical filter according to claim 8 wherein: said preselected wavelength is in the region from approximately 10 to 35 microns; and said plurality of absorbing materials have overlapping absorption bands of intensity such that the region between said preselected wavelength and about 46 microns is substantially opaque, said plurality of absorbing materials including SrF2, BeO, LiF and freshly smoked MgO, said materials positioned to absorb radiation between said preselected wavelength and about 46 microns.
Claim 24
Dependent Claim
34 words
An optical filter according to claim 13 wherein said plurality of absorbing materials include approximately 24.4 mg/in2 of SrF2, 7.3 mg/in2 of BeO, 4.1 mg/in2 of LiF, and 12.2 mg/in2 of freshly smoked MgO.
Claim 25
Dependent Claim
76 words
An optical filter according to claim 8 wherein: said preselected wavelength is in the region from approximately 10 to 35 microns; and said plurality of absorbing materials have overlapping absorption bands of intensity such that the region between said preselected wavelength and about 53 microns is substantially opaque, said plurality of absorbing materials including BaF2, SrF2, LiF, BeO, and freshly smoked MgO, said materials positioned to absorb radiation between said preselected wavelength and about 53 microns.
Claim 26
Dependent Claim
34 words
An optical filter according to claim 15 wherein: said plurality of absorbing materials include 26.9 mg/in2 of BaF2, 65 mg/in2 of SrF2, 8.2 mg/in2 LiF and BeO and 12.2 mg/in2 of freshly smoked MgO.
Claim 27
Dependent Claim
54 words
An optical filter according to claim 2 wherein: said preselected wavelength is in the region from approximately 10 to 35 microns; and said one absorbing material comprises a sufficient quantity of TiO2 evenly distributed over an area in sufficient quantity to render the region between said preselected wavelength and about 37 microns substantially opaque.
Claim 28
Dependent Claim
16 words
An optical filter according to claim 17 wherein: said quantity of TiO2 is approximately 18.3 mg/in2.
Claim 29
Dependent Claim
51 words
An optical filter according to claim 2 wherein: said preselected wavelength is in the region from approximately 10 to 20 microns; and said one absorbing material comprises a sufficient quantity of freshly smoked MgO in such concentration to render the region between said preselected wavelength and about 26 microns substantially opaque.
Claim 30
Dependent Claim
18 words
An optical filter according to claim 19 wherein: said concentration of freshly smoked MgO is approximately 30 mg/in2.
Claim 31
Dependent Claim
72 words
An optical filter according to claim 8 wherein: said preselected wavelength is in the region from approximately 10 to 20 microns; and said plurality of absorbing materials have overlapping absorption bandS of intensity such that the region between said preselected wavelength and about 26 microns is substantially opaque, said plurality of absorbing materials including BeO and freshly smoked MgO and positioned to absorb radiation between said preselected wavelength and about 26 microns.
Claim 32
Dependent Claim
25 words
An optical filter according to claim 21 wherein: said plurality of absorbing materials include 4.1 mg/in2 of BeO and 30 mg/in2 of freshly smoked MgO.
References Cited (Backward Citations)
US3034916A
Cited
US3279938A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1976-03-26 | 1976-09-25 | 1977-03-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1980-03-26 | 1980-09-25 | 1981-03-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1984-03-26 | 1984-09-25 | 1985-03-27 | $7700.00 | Window Closed / Lapsed |