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US3720862A Expired / Lapsed US ⏱️ 0.0 years remaining

Capacitor with high k dielectric materials

Assignee: OI Glass Inc
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Filing: 1972-01-27
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Granted: 1973-03-13
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Expires: 1992-01-27
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Abstract

Abstract Unique dielectric compositions may be used to formulate thick film pastes for printing microelectronic capacitors. The resulting dielectrics exhibit dielectric constants greater than about 500 and capacitances greater than about 80,000 picofarads per square inch at a thickness of at least about 1.0 mils. The unique dielectric compositions comprise about 55-76 percent by weight of a ferroelectric material and 45-24 percent of a glass binder. The glass binder employed comprises a lead barium borosilicate glass and a ferroelectric material previously dissolved therein. The composition is formulated into a printing paste by first dissolving 20-30 percent by weight ferroelectric into 70-80 percent by weight lead barium borosilicate glass binder, cooling the newly formed glass to a solid state, comminuting the glass to a particle size of less than about 1 micron and thereafter admixing the comminuted glass with the same particulate ferroelectric in an amount as indicated. This admixture is then added to a liquid organic carrier vehicle to formulate the printing paste. The printing paste is then printed into a chosen design and fired at a temperature of approximately 1,000*-1,050* C. to produce a highly dense, uniform, and substantially crack-free dielectric material.

Inventors

  • 👤 D Mason

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 21:27
CPC Classifications
H; H01; H01G; H01G4/00; H01G4/002; H01G4/018; H01G4/06; H01G4/08; H01G4/12; H01G4/129; C; C03; C03C; C03C3/00; C03C3/04; C03C3/062; C03C3/07; C03C3/072; C03C3/074; C03C8/00; C03C8/02; C03C8/10; C03C8/12; C03C8/14; C03C8/20; H01B; H01B3/00; H01B3/02; H01B3/08; H01B3/085; H01G4/1209; H01G4/1236; H01G4/1245

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 60 words
A capacitor comprised of at least two conductors bonded to a lamina therebetween which comprises 72-76 percent by weight of particles of a ferroelectric material dispersed in 28-24 percent by weight of a continuous phase of a substantially homogeneous non-crystalline glass binder comprising by weight about 70-80 percent lead barium borosilicate glass and about 20-30 percent ferroelectric material dissolved therein.
Claim 2
Dependent Claim 60 words
A capacitor comprised of at least two conductors bonded to a lamina therebetween which comprises 72-76 percent by weight of particles of a ferroelectric material dispersed in 28-24 percent by weight of a continuous phase of a substantially homogeneous non-crystalline glass binder comprising by weight about 70-80 percent lead barium borosilicate glass and about 20-30 percent ferroelectric material dissolved therein.
Claim 3
Dependent Claim 37 words
A capacitor as defined in claim 1, wherein said lead barium borosilicate glass comprises by weight about 5-25 percent SiO2, about 5-20 percent B2O3, about 25-50 percent PbO, about 10-30 percent BaO, and about 10-25 percent ZnO.
Claim 4
Dependent Claim 46 words
A capacitor as defined in claim 2, wherein said lead barium borosilicate glass consists essentially of 15 percent by weight of SiO2, 10 percent by weight of B2O3, 40 percent by weight PbO, 20 percent by weight of BaO and 15 percent by weight of ZnO.
Claim 5
Dependent Claim 23 words
A capacitor as defined in claim 1, wherein said lamina comprises about 55-76 percent by weight of total particulate and dissolved ferroelectric material.
Claim 6
Dependent Claim 32 words
A capacitor as defined in claim 4, wherein said lamina comprises about 32.5 percent by weight of glass binder and about 67.5 percent by weight of total particulate and dissolved ferroelectric material.
Claim 7
Dependent Claim 21 words
A capacitor as defined in claim 1, wherein said ferroelectric material comprises a mixture of metallic titanates, zirconates, niobates and ceriates.
Claim 8
Dependent Claim 88 words
A capacitor as defined in claim 6, wherein said mixture of metallic titanates, zirconates, niobates and ceriates has a metal analysis of about 0.5 percent by weight of Al, about 0.15 percent by weight of Ca, about 1.0 percent by weight of Ce, about 0.05 percent by weight of Mg, about 0.5 percent by weight of Nb, about 0.15 percent by weight of Si, about 0.3 percent by weight of Sr, greater than about 10 percent by weight of Ti and about 5.0 percent by weight of Zr.
Claim 9
Dependent Claim 19 words
A capacitor as defined in claim 1, wherein said dielectric lamina has a dielectric constant greater than about 500.
Claim 10
Dependent Claim 29 words
A capacitor as defined in claim 1, wherein said lamina for about 1.0 mil thickness exhibits a dielectric constant of about 800 and a capacitance of about 200,000 picofarads/in.2.

References Cited (Backward Citations)

US3609482A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-03-12 1976-09-11 1977-03-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-03-12 1980-09-11 1981-03-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-03-12 1984-09-11 1985-03-13 $7700.00 Window Closed / Lapsed

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