Abstract A tri-layer laminated article, having utility as a packaging material, is prepared by forming an inner layer of a dispersion of solid polymer particles in molten wax adjacent to and between two outer cellulosic layers. The subsequent application of heat and pressure to the resulting composite causes the wax to impregnate the cellulosic material while the polymer particles form a molten middle layer. Upon cooling the polymer solidifies resulting in an article having two outer cellulosic layers of which at least one is wax impregnated and a middle polymeric layer. Said polymer is insoluble in molten wax at a temperature below the polymer''s melting point and has a melting point between the melting point of the wax and 300*C.
Method of preparing a tri-layer laminated article having two outer cellulosic layers and a middle thermoplastic polymeric layer comprising: a. establishing a heterogeneous composite of thermoplastic polymer in finely divided form and molten wax, said polymer having a melting point between the melting point of the wax and 300*C., and being substantially insoluble in molten wax at a temperature below the melting point of the polymer; b. forming an inner layer of said heterogeneous composite adjacent to and between two cellulosic layers, at least one of said cellulosic layers being porous and the amount of said heterogeneous composite bein regulated so that substantially all wax therein is absorbable in pores of the cellulosic material and permitting sufficient time to elapse so that substantially all of the wax in said heterogeneous composite is separated from said polymer and absorbed into said porous cellulosic material and then; c. heating the inner layer to a temperature above the melting point of the polymer and pressing the outer layers against the inner layer to form an essentially continuous molten layer; d. and thereafter cooling the molten polymer whereby it solidifies resulting in said article having at least one cellulosic layer impregnated with wax.
Claim 2
Dependent Claim
199 words
Method of preparing a tri-layer laminated article having two outer cellulosic layers and a middle thermoplastic polymeric layer comprising: a. establishing a heterogeneous composite of thermoplastic polymer in finely divided form and molten wax, said polymer having a melting point between the melting point of the wax and 300*C., and being substantially insoluble in molten wax at a temperature below the melting point of the polymer; b. forming an inner layer of said heterogeneous composite adjacent to and between two cellulosic layers, at least one of said cellulosic layers being porous and the amount of said heterogeneous composite bein regulated so that substantially all wax therein is absorbable in pores of the cellulosic material and permitting sufficient time to elapse so that substantially all of the wax in said heterogeneous composite is separated from said polymer and absorbed into said porous cellulosic material and then; c. heating the inner layer to a temperature above the melting point of the polymer and pressing the outer layers against the inner layer to form an essentially continuous molten layer; d. and thereafter cooling the molten polymer whereby it solidifies resulting in said article having at least one cellulosic layer impregnated with wax.
Claim 3
Dependent Claim
31 words
A method according to claim 1 wherein said heterogeneous composite contains 5 to 45 parts by weight of finely divided polymer and 50 to 95 parts by weight of said wax.
Claim 4
Dependent Claim
21 words
A method according to claim 2 wherein all the finely divided polymer is finer than 100 mesh (U. S. Sieve Series).
Claim 5
Dependent Claim
13 words
A method according to claim 3 wherein the wax is a petroleum wax.