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US3715341A Expired / Lapsed US ⏱️ 0.0 years remaining

Modification of carboxyl group containing polymer with aziridinyl substituted unsaturated long chain acyclic hydrocarbons

Assignee: Aerojet Rocketdyne Holdings Inc
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Filing: 1971-01-19
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Granted: 1973-02-06
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Expires: 1991-01-19
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Abstract

Abstract Unsaturated, long chain, acyclic hydrocarbons having one or two aziridinyl substituents are prepared by reaction of an alkylenimino and a long chain alkatriene in the presence of an alkali metal or equivalent catalyst. The resulting aziridinyl products, e.g., the ethylenimine adduct of allocimene, contain at least three reactive groups, i.e., a combination of two aziridinyl groups and one olefinic unsaturation or one aziridinyl group and two olefinic unsaturations.

Inventors

  • 👤 H Uelzmann

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 00:10
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/50; C08G59/5046; C08G59/5053; C08G59/506; C08G59/5066; C08C; C08C19/00; C08C19/30; C08C19/34; C08C19/36

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 108 words
Cross-linked or chain-extended polymer compositions made by the process which comprises: a. forming a mixture of a major portion of a carboxyl group containing polymer and a minor portion of an unsaturated acyclic aziridinyl hydrocarbon of the formula: R1-CnH2n x-R2 wherein: R2 is hydrogen or R1, R3, R4, R5 and R6 are hydrogen or 1 to 4 carbon atom alkyl radicals, n is an integer from 10 to 20, and x is the integer 3 when R2 is hydrogen and the integer 2 when R2 is R1, and b. heating the resulting mixture to an elevated temperature sufficient to produce reaction between said polymer and said aziridinyl hydrocarbon.
Claim 2
Dependent Claim 108 words
Cross-linked or chain-extended polymer compositions made by the process which comprises: a. forming a mixture of a major portion of a carboxyl group containing polymer and a minor portion of an unsaturated acyclic aziridinyl hydrocarbon of the formula: R1-CnH2n x-R2 wherein: R2 is hydrogen or R1, R3, R4, R5 and R6 are hydrogen or 1 to 4 carbon atom alkyl radicals, n is an integer from 10 to 20, and x is the integer 3 when R2 is hydrogen and the integer 2 when R2 is R1, and b. heating the resulting mixture to an elevated temperature sufficient to produce reaction between said polymer and said aziridinyl hydrocarbon.
Claim 3
Dependent Claim 16 words
A composition of claim 1 wherein said carboxyl group containing polymer is carboxyl-terminated conjugated diolefin polymer.
Claim 4
Dependent Claim 13 words
A composition of claim 2 wherein said carboxyl-terminated diolefin polymer is dicarboxyl polybutadiene.
Claim 5
Dependent Claim 15 words
A composition of claim 1 wherein said aziridinyl hydrocarbon is the ethylenimine diadduct of allo-ocimene.

References Cited (Backward Citations)

US3434990A Cited
US3492289A Cited
US3507837A Cited
US3544541A Cited
US3600272A Cited
US3576786A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-02-06 1976-08-07 1977-02-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-02-06 1980-08-07 1981-02-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-02-06 1984-08-07 1985-02-06 $7700.00 Window Closed / Lapsed

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