US3714153A
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Novel cyclopropanecarboxylic acids
Assignee: Sanofi Aventis France
•
Filing: 1970-06-22
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Granted: 1973-01-30
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Expires: 1990-06-22
Abstract
Abstract Novel 3,3-dimethyl-2-(2''-oxo-3''-x-cyclopentylidenemethyl)-1cyclopropanecarboxylic acids of a cis or trans structure, in the form of racemic mixtures or optically active isomers of the formula WHEREIN X is selected from the group consisting of oxygen, sulfur and imino and R is selected from the group consisting of hydrogen, lower alkyl of one to six carbons, a radical of the formula WHEREIN Y3 is aryl such as phenyl, and a radical of the formula WHEREIN Z is alkenyl or alkadienyl such as allyl, butenyl and pentadienyl and their preparation and intermediates therefor.
Inventors
- 👤 J Martel
- 👤 J Buendia
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 21:10
CPC Classifications
C; C07; C07D; C07D307/00; C07D307/02; C07D307/34; C07D307/38; C07D307/40; C07D307/42; C07D207/00; C07D207/02; C07D207/30; C07D207/34; C07D207/36; C07D207/38; C07D307/54; C07D307/56; C07D307/58; C07D333/00; C07D333/02; C07D333/04; C07D333/26; C07D333/30; C07D333/32
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
19 words
A compound selected from the group consisting of optically active and racemic mixtures of a compound of the formula
Claim 2
Dependent Claim
19 words
A compound selected from the group consisting of optically active and racemic mixtures of a compound of the formula
Claim 3
Dependent Claim
9 words
A compound of claim 1 wherein X is oxygen.
Claim 4
Dependent Claim
27 words
A compound of claim 1 selected from the group consisting of trans 3,3-dimethyl-2-(2''-oxo-3''-oxa-cyclopentylidenemethyl)-1 -cyclopropanecarboxylic (1R, 2R) or (1S, 2S) acid and a racemic mixture of said acids.
Claim 5
Dependent Claim
27 words
A compound of claim 1 selected from the group consisting of cis 3,3-dimethyl-2-(2''-oxo-3''-oxa-cyclopentylidenemethyl)-1 -cyclopropanecarboxylic (1R, 2S) or (1S, 2R) acid and a racemic mixture of said acids.
Claim 6
Dependent Claim
24 words
A compound of claim 1 selected from the group consisting of cis-3,3-dimethyl-2-(2''-oxo-3''-thiacyclopentylidenemethyl)-1 -cyclopropanecarboxylic (1R,2S) or (1S,2R) acid and a racemic mixture of said acids.
Claim 7
Dependent Claim
27 words
A compound of claim 1 selected from the group consisting of trans 3,3-dimethyl-2-(2''-oxo-3''-thia-cyclopentylidenemethyl)-1 -cyclopropanecarboxylic (1R, 2R) or (1S, 2S) acid and a racemic mixture of said acids.
Claim 8
Dependent Claim
16 words
A compound of claim 1 which is the 5-benzyl-3-furyl-methyl ester of trans 3,3-dimethyl-2-(2''-oxo-3''-oxa-cyclopentylidenemethyl)-1-cyclopropanecarboxylic (1R, 2R) acid.
Claim 9
Dependent Claim
16 words
A compound of claim 1 which is the 5-benzyl-3-furyl-methyl ester of cis 3,3-dimethyl-2-(2''-oxo-3''-oxacyclopentylidenemethyl)-1 -cyclopropanecarboxylic (1R,2S) acid.
Claim 10
Dependent Claim
18 words
A compound of claim 1 which is the dl allethrolone ester of trans 3,3-dimethyl-2-(2''-oxo-3''-oxa-cyclopentylidenemethyl)-1 -cyclopropanecarboxylic (1R, 2R) acid.
Claim 11
Dependent Claim
16 words
A compound of claim 1 which is dl-allethrolone ester of cis 3,3-dimethyl-2-(2''-oxo-3''-oxa-cyclopentylidenemethyl)-1 -cyclopropanecarboxylic (1R, 2S) acid.
Claim 12
Dependent Claim
17 words
A compound of claim 1 which is the 5-benzyl-3-furyl-methyl ester of cis 3,3-dimethyl-2-(2''-oxo-3''-thiacyclopentylidene-methyl)-1 -cyclopropanecarboxylic (1R, 2S) acid.
Claim 13
Dependent Claim
16 words
A compound of claim 1 which is the 5-benzyl-3-furyl-methyl-ester of trans 3,3-dimethyl-2-(2''-oxo-3''-thia-cyclopentylidenemethyl)-1 -cyclopropanecarboxylic (1R, 2R) acid.
Claim 14
Dependent Claim
24 words
A compound of claim 1 which is the potassium salt of cis 3, 3-dimethyl-2-(2''-oxo-3''-oxa-cyclopentylidenemethyl-1-cyclopropanecarboxylic (1R, 2S) or (1S, 2R) acid and racemic mixtures thereof.
Claim 15
Dependent Claim
23 words
A compound of claim 1 which is potassium salt of trans 3,3-dimethyl-2-(2''-oxo-3''-oxa-cyclopentylidenemethyl)-1 -cyclopropanecarboxylic (1R, 2R) or (1S, 2S) acid and racemic mixtures thereof.
Claim 16
Dependent Claim
14 words
Cis 3,3-dimethyl-2-(2''-oxo-3''-oxa-cyclopentylidenemethyl)-1 -cyclopropanecarboxylic (1R, 2S) or (1S, 2R) acid chloride and racemic mixtures thereof.
Claim 17
Dependent Claim
14 words
Cis 3,3-dimethyl-2-(2''-oxo-3''-oxa-cyclopentylidenemethyl)-1 -cyclopropanecarboxylic (1R, 2S) or (1S, 2R) acid chloride and racemic mixtures thereof.
Claim 18
Dependent Claim
14 words
Trans 3,3-dimethyl-2-(2''-oxo-3''-oxa-cyclopentylidenemethyl)-1 -cyclopropanecarboxylic (1R, 2R) or (1S, 2S) acid chloride and racemic mixtures thereof.
Claim 19
Dependent Claim
14 words
Trans 3,3-dimethyl-2-(2''-oxo-3''-oxa-cyclopentylidenemethyl)-1 -cyclopropanecarboxylic (1R, 2R) or (1S, 2S) acid chloride and racemic mixtures thereof.
Claim 20
Dependent Claim
14 words
Cis 3,3-dimethyl-2-(2''-oxo-3''-thia-cyclopentylidenemethyl)-1 -cyclopropanecarboxylic (1R, 2S) or (1S, 2R) acid chloride and racemic mixtures thereof.
Claim 21
Dependent Claim
14 words
Cis 3,3-dimethyl-2-(2''-oxo-3''-thia-cyclopentylidenemethyl)-1 -cyclopropanecarboxylic (1R, 2S) or (1S, 2R) acid chloride and racemic mixtures thereof.
References Cited (Backward Citations)
FR1505423A
Cited
FR94309E
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1976-01-30 | 1976-07-31 | 1977-01-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1980-01-30 | 1980-07-31 | 1981-01-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1984-01-30 | 1984-07-31 | 1985-01-30 | $7700.00 | Window Closed / Lapsed |