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US3707296A Expired / Lapsed US ⏱️ 0.0 years remaining

Modified phenolic resin system and laminates made therefrom

Assignee: Westinghouse Electric Corp
•
Filing: 1970-01-09
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Granted: 1972-12-26
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Expires: 1990-01-09
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Abstract

Abstract A laminate, that can be used as an exterior, refinishable surface for snow skis, comprises a plurality of plastic resin impregnated bonded paper sheets, each having been impregnated with a solution of a melamine-formaldehyde, phenol-formaldehyde resinous admixture which contains from about 10 to 70 weight percent melamine-formaldehyde resin solids based on phenolformaldehyde resin solids.

Inventors

  • 👤 Salvatore E Palazzolo
  • 👤 Harold O Mccaskey

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 14:54
CPC Classifications
A; A63; A63C; A63C5/00; A63C5/12

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 60 words
The resin solution of claim 1 wherein the catalyst is selected from the group consisting of ammonia, calcium carbonate and sodium hydroxide, the solvent is selected from the group consisting of methanol, ethanol and isopropyl alcohol, the melamine resin being present in the amount of from about 20 to 40 weight percent melamine-formaldehyde resin solids based on phenol-formaldehyde resin solids.
Claim 2
Dependent Claim 20 words
impregnating paper sheets with a solution of the admixture to a resin to paper ratio of between 0.75:1 to 2:1;
Claim 3
Dependent Claim 13 words
preparing a stacked assembly comprising a plurality of said resin impregnated sheets; and
Claim 4
Dependent Claim 51 words
A refinishable laminate comprising a plurality of bonded, resin impregnated paper sheets, impregnated with a catalyzed melamine-formaldehyde resin, phenol-formaldehyde resin admixture, said admixture comprising from 10 to 70 weight percent melamine-formaldehyde resin solids based on phenol-formaldehyde resin solids, wherein the weight percent resin: paper is a ratio between 0.75 to 2.0:1.0.
Claim 5
Dependent Claim 10 words
heat and pressure consolidating the assembly into a unitary structure.
Claim 6
Dependent Claim 25 words
The refinishable laminate of claim 3 wherein the admixture comprises from about 20 to 40 weight percent melamine-formaldehyde resin solids based on phenol-formaldehyde resin solids.
Claim 7
Dependent Claim 57 words
The refinishable laminate of claim 4 wherein the paper sheets are color pigmented kraft paper sheets, the catalyst in the admixture is selected from the group consisting of ammonia, calcium carbonate and sodium hydroxide and the melamine-formaldehyde resin comprises a resin having a mole ratio of formaldehyde : melamine of from about 1.5 :1to 2 : 1.
Claim 8
Independent Claim 17 words
A method of making a refinishable laminate comprising a plurality of bonded sheets comprising the steps of:
Claim 9
Dependent Claim 82 words
The method of claim 6 wherein the resin to paper ratio is between about 1.25 : 1 to 1.75 : 1, the admixture comprises from about 20 to 40 weight percent melamine-formaldehyde resin solids based on phenol-formaldehyde resin solids, the catalyst in the resin admixture is selected from the group consisting of ammonia, calcium carbonate and sodium hydroxide and the melamine-formaldehyde resin comprises a resin having a mole ratio of formaldehyde : melamine of from about 1.5 : 1 to 2 :
Claim 10
Dependent Claim 28 words
The method of claim 7 wherein the admixture contains ammonia catalyst and the stacked assembly is consolidated at between about 1,200 to 1,500 psi and 250* to 325*F.
Claim 11
Dependent Claim 36 words
The method of claim 7 wherein the admixture is in a solution of a solvent selected from the group consisting of methanol, ethanol and isopropyl alcohol and the paper sheets are color pigmented kraft paper sheets.
Claim 12
Dependent Claim 81 words
A snow ski comprising a flexible core surrounded by a laminated top surface, base surface, and sidewalls between the top surface and base surface, the improvement being refinishable top surface and sidewall laminations comprising a plurality of bonded, resin impregnated paper sheets impregnated with a catalyzed, melamine-formaldehyde resin, phenol-formaldehyde resin admixture, said resin aDmixture comprising from 10 to 70 weight percent melamine-formaldehyde resin solids based on phenol-formaldehyde resin solids and the weight percent resin:paper is a ratio between 0.75 to 2.0:1.0.
Claim 13
Dependent Claim 55 words
The snow ski of claim 10 also having a refinishable base surface comprising a plurality of bonded, resin impregnated paper sheets, the sheets of the top surface, base surface and sidewall being impregnated with the admixture, wherein the admixture comprises from about 20 to 40 weight percent melamine-formaldehyde resin solids based on phenol-formaldehyde resin solids.
Claim 14
Dependent Claim 55 words
The snow ski of claim 10 wherein the paper sheets are color pigmented kraft paper sheets, the catalyst in the resin admixture is selected from the group consisting of ammonia, calcium carbonate and sodium hydroxide and the melamine-formaldehyde resin comprises a resin having a mole ratio of formaldehyde: melamine of from about 1.5:1 to 2:1.

References Cited (Backward Citations)

US2331744A Cited
US2387256A Cited
US2801198A Cited
US3070572A Cited
FR1299263A Cited
CH390760A Cited
FR1457826A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-12-26 1976-06-26 1976-12-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-12-26 1980-06-26 1980-12-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-12-26 1984-06-26 1984-12-26 $7700.00 Window Closed / Lapsed

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