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US3702564A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for determining aqueous activity of subsurface formations

Assignee: ExxonMobil Upstream Research Co
•
Filing: 1970-05-04
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Granted: 1972-11-14
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Expires: 1990-05-04
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Abstract

Abstract Shaley earth formations are drilled or otherwise treated with reduced difficulty through the use of water-in-oil invert emulsion fluids wherein the aqueous phases of the emulsions possess particular water vapor pressures relative to the formations which they contact. The aqueous vapor pressure of an oil-base fluid containing dispersed water is controlled to prevent damage to water-sensitive shale formations by monitoring the vapor pressure of the aqueous phase of the fluid and maintaining a vapor pressure depressant in the aqueous phase in a concentration sufficient to substantially prevent the migration of water from the fluid to the formations. The aqueous vapor pressure of an earth formation is determined. A method and apparatus are disclosed for determining the compatibility of a well fluid with a water-sensitive subsurface formation wherein a substantially unaltered sample of the formation is immersed in the fluid and the direction and extent of water migration between the well fluid and the sample are logged. Improved water-in-oil invert emulsion fluid compositions for drilling and other oil field uses are obtained wherein the aqueous phases of the emulsions possess particular water vapor pressures relative to the formations which they contact.

Inventors

  • 👤 Martin E Chenevert

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 21:25
CPC Classifications
E; E21; E21B; E21B49/00; E21B49/02; C; C09; C09K; C09K8/00; C09K8/02; C09K8/32; C09K8/36; C09K8/60; C09K8/62; C09K8/64; G; G01; G01N; G01N7/00; G01N7/14

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 17 words
a method as defined in claim 1 in which the atmospheres comprise air of different relative humidities.
Claim 2
Independent Claim 62 words
A method of determining the aqueous activity of an earth formation having a known natural subsurface water content which comprises exposing at least one sample of the formation to gaseous atmospheres having different water vapor pressures and determining the atmosphere in which the sample will exhibit its natural subsurface water content after substantial equilibrium is attained between the sample and the atmosphere.
Claim 3
Dependent Claim 17 words
A method as defined in claim 3 in which the atmospheres comprise air of different relative humidities.
Claim 4
Independent Claim 120 words
A method of determining the aqueous activity of a subsurface earth formation which comprises: a. determining the natural subsurface water content of said formation; b. exposing at least one sample of the formation to gaseous atmospheres having different water vapor pressures until each said sample is in substantial equilibrium with each said atmosphere; c. weighing each said equilibrated sample; d. removing substantially all of the water contained in each said equilibrated sample; and thereafter e. weighing each resulting dried sample and comparing the water contents of such samples at such water vapor pressures to the natural water content of the earth formation whereby the aqueous activity of the earth formation at its natural in situ water content can be determined.
Claim 5
Dependent Claim 17 words
A method as defined in claim 5 in which said atmospheres comprise air at different relative humidities.
Claim 6
Independent Claim 36 words
A method of determining the aqueous activity of a premeable subsurface earth formation penetrated by a well wherein said formation contains argillaceous material and saline connate water, which comprises obtaining a sample of said water sample.
Claim 7
Dependent Claim 32 words
A method as defined by claim 7 in which the aqueous vapor pressure of said water sample is determined by measuring the relative humidity of an atmosphere in contact with said sample.
Claim 8
Dependent Claim 23 words
A method as defined by claim 8 in which the atmosphere in contact with said sample is substantially in equilibrium with said sample.
Claim 9
Independent Claim 121 words
A method of determining the concentration of an aqueous vapor pressure depressant within the aqueous phase of a water-in-oil emulsion fluid required to substantially prevent migration of water from the emulsion fluid to a water-sensitive formation upon contact therebetween comprising obtaining a sample of said formation having substantially its natural subsurface water content, determining the degree of attraction which said sample of said formation exhibits for water within said emulsion fluid upon contact therewith, and determining the concentration of the aqueous vapor pressure depressant required in the aqueous phase of said emulsion fluid to substantially prevent migration of water from the aqueous phase of said emulsion fluid to the sample when said sample exhibits the said degree of attraction for water.
Claim 10
Dependent Claim 18 words
A method as defined in claim 10 in which the water-sensitive formation is a hard, argillaceous shale formation.

References Cited (Backward Citations)

US1806538A Cited
US2330721A Cited
US3348140A Cited
US3350789A Cited
US3477282A Cited
US3463000A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-11-14 1976-05-15 1976-11-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-11-14 1980-05-15 1980-11-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-11-14 1984-05-15 1984-11-14 $7700.00 Window Closed / Lapsed

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