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US3698384A Expired / Lapsed US ⏱️ 0.0 years remaining

Oxygen consumption rate monitor

Assignee: Westinghouse Electric Corp
•
Filing: 1970-11-03
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Granted: 1972-10-17
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Expires: 1990-11-03
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Abstract

Abstract The disclosure relates to a system for monitoring the oxygen consumption rate of a process and includes a dual solid electrolyte electrochemical cell combination in which one cell is utilized as an oxygen measuring cell operating in a null mode, while the second cell is utilized as an oxygen pump which is responsive to a signal developed by the measuring cell. A gas source derived from the process provides a reference for the null measuring cell and also serves as a source of oxygen for the pump cell. Flow control means, including a flow splitter and a fluid dilution circuit, is provided to sample the process fluid and to maintain the sample flow and reference gas flow through the dual cell combination relatively constant.

Inventors

  • 👤 William J Jones

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 22:48
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/416; G01N27/417

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 368 words
Apparatus for determining the oxygen consumption rate of a process having an input source of oxygen and an exhaust, comprising in combination, a first solid electrolyte electrochemical cell having a first electrically conductive electrode and a second electrically conductive electrode, means for maintaining an oxygen reference media of known oxygen concentration at said second electrode, means for supplying a sample of said process exhaust gas to said first electrode, said first solid electrolyte electrochemical cell generating an EMF as a function of the difference in oxygen concentration between the oxygen reference media and the sample exhaust gas, a second solid electrolyte electrochemical cell having a first electrically conductive electrode and a second electrically conductive electrode, means for providing an oxygen containing media at said second electrode of said second electrochemical cell, means for supplying said sample exhaust gas to said first electrode of said second electrochemical cell prior to supplying said sample exhaust gas to said first electrochemical cell, and a feedback circuit means operatively connected between the electrodes of said first solid electrolyte electrochemical cell and the electrodes of said second solid electrolyte electrochemical cell to apply the EMF signal generated by said first solid electrolyte electrochemical cell as an excitation signal across the electrodes of said second solid electrolyte electrochemical cell, said second solid electrolyte electrochemical cell operating as an oxygen ion pump, the current generated by said second solid electrolyte electrochemical cell as a result of the applied excitation from said feedback circuit changing the oxygen concentration of the sample exhaust gas until the oxygen concentration of the sample exhaust gas substantially equals the oxygen concentration of the oxygen reference media of said first solid electrolyte electrochemical cell thereby resulting in an EMF signal output of approximately zero from said first solid electrolyte electrochemical cell, said current flow in said second solid electrolyte electrochemical cell being an indication of the oxygen consumption rate of said process, and blower means including a variable speed blower and a blower speed control circuit means operatively coupled between said second solid electrolyte electrochemical cell and said variable speed blower to control the speed of the blower as a function of the current generated by said solid electrolyte electrochemical cell.
Claim 2
Dependent Claim 368 words
Apparatus for determining the oxygen consumption rate of a process having an input source of oxygen and an exhaust, comprising in combination, a first solid electrolyte electrochemical cell having a first electrically conductive electrode and a second electrically conductive electrode, means for maintaining an oxygen reference media of known oxygen concentration at said second electrode, means for supplying a sample of said process exhaust gas to said first electrode, said first solid electrolyte electrochemical cell generating an EMF as a function of the difference in oxygen concentration between the oxygen reference media and the sample exhaust gas, a second solid electrolyte electrochemical cell having a first electrically conductive electrode and a second electrically conductive electrode, means for providing an oxygen containing media at said second electrode of said second electrochemical cell, means for supplying said sample exhaust gas to said first electrode of said second electrochemical cell prior to supplying said sample exhaust gas to said first electrochemical cell, and a feedback circuit means operatively connected between the electrodes of said first solid electrolyte electrochemical cell and the electrodes of said second solid electrolyte electrochemical cell to apply the EMF signal generated by said first solid electrolyte electrochemical cell as an excitation signal across the electrodes of said second solid electrolyte electrochemical cell, said second solid electrolyte electrochemical cell operating as an oxygen ion pump, the current generated by said second solid electrolyte electrochemical cell as a result of the applied excitation from said feedback circuit changing the oxygen concentration of the sample exhaust gas until the oxygen concentration of the sample exhaust gas substantially equals the oxygen concentration of the oxygen reference media of said first solid electrolyte electrochemical cell thereby resulting in an EMF signal output of approximately zero from said first solid electrolyte electrochemical cell, said current flow in said second solid electrolyte electrochemical cell being an indication of the oxygen consumption rate of said process, and blower means including a variable speed blower and a blower speed control circuit means operatively coupled between said second solid electrolyte electrochemical cell and said variable speed blower to control the speed of the blower as a function of the current generated by said solid electrolyte electrochemical cell.
Claim 3
Dependent Claim 71 words
Apparatus as claimed in claim 1 including pump means for drawing said sample exhaust gas by said first electrodes of said first and second solid electrolyte electrochemical cell at a predetermined flow rate, and a sample exhaust gas dilution means for supplementing said sample exhaust gas flow rate in the event the sample exhaust gas flow rate decreases below said predetermined level in order to reestablish said predetermined gas flow rate.
Claim 4
Dependent Claim 62 words
Apparatus as claimed in claim 2 wherein said oxygen media supplied to said second electrodes of sAid first and second solid electrolyte electrochemical cell is the oxygen containing gas supplied to said process inlet from said source of oxygen, said pump means drawing said oxygen containing gas by said second electrodes at the predetermined flow rate established for said sample exhaust gas.
Claim 5
Dependent Claim 35 words
Apparatus as claimed in claim 3 wherein said sample exhaust gas dilution means supplements said sample exhaust gas flow rate with the oxygen containing gas supplied to said process inlet from said source of oxygen.

References Cited (Backward Citations)

DE865777C Cited
US3045665A Cited
US3006339A Cited
US3358683A Cited
US3514377A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-10-17 1976-04-17 1976-10-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-10-17 1980-04-17 1980-10-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-10-17 1984-04-17 1984-10-17 $7700.00 Window Closed / Lapsed

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