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US3691145A Expired / Lapsed US ⏱️ 0.0 years remaining

Production of polyethylene by the high pressure process using a mixture of tertiary butyl hydroperoxide and oxygen as the initiator

Assignee: BASF SE
•
Filing: 1970-08-06
•
Granted: 1972-09-12
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Expires: 1990-08-06
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Abstract

Abstract Production of polyethylene by polymerizing ethylene at elevated temperatures and elevated pressure under the action of a polymerization initiator, consisting of oxygen and t-butyl hydroperoxide, and of a polymerization regulator. The process of the invention is characterized in that temperature ranging from 310* to 400*C are used and that the polymerization initiator consists of from 1 to 12 molar parts of oxygen and from 1 to 5 molar parts of t-butyl hydroperoxide per million molar parts of the ethylene being polymerized. The process of the invention is preferably carried out continuously in a tubular reactor. The process permits easy control of the reaction with high yields and provides products with high flexibility and elongation.

Inventors

  • 👤 Volker Gierth
  • 👤 Hans Gropper
  • 👤 Franc Georg Mietzner
  • 👤 Friedrich Urban

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 16:50
CPC Classifications
C; C08; C08F; C08F10/00

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 15 words
A process as in claim 1 which is continuously carried out in a tubular reactor.
Claim 2
Dependent Claim 16 words
A process as in claim 1 wherein said temperature range is from 330* to 370* C.
Claim 3
Dependent Claim 18 words
A process as in claim 3 wherein the amount of oxygen is from 3 to 12 molar parts.
Claim 4
Dependent Claim 20 words
A process as in claim 4 wherein the amount of tertiary butyl hydroperoxide is from 2 to 4 molar parts.

References Cited (Backward Citations)

GB870043A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-09-12 1976-03-13 1976-09-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-09-12 1980-03-13 1980-09-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-09-12 1984-03-13 1984-09-12 $7700.00 Window Closed / Lapsed

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