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US3686326A Expired / Lapsed US ⏱️ 0.0 years remaining

Allylic sulfide reaction products

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1970-02-11
•
Granted: 1972-08-22
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Expires: 1990-02-11
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Abstract

Abstract Open-chain, bis- and tris-sulfides are synthesized by the free radical, liquid phase addition of simple thiols to diallylic sulfides. Similarly, addition of thiol acids results in the corresponding mono- and di-thiol esters, and the poly addition of dithiols to diallylic sulfides yields terminally difunctional polythioethers. The mono- and diadduct compositions are useful as pesticides, while the poly adducts are useful in the preparation of polymers, particularly as basic ingredients for mastics compositions.

Inventors

  • 👤 Alexis Oswald
  • 👤 Daniel N Hall
  • 👤 Karl Griesbaum

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 05:22
CPC Classifications
C; C07; C07C; C07C327/00; C07C321/00; C07F; C07F9/00; C07F9/02; C07F9/06; C07F9/16; C07F9/165; C07F9/1651; C08; C08G; C08G75/00; C08G75/02; C08G75/04; C08G75/045; C08K; C08K5/00; C08K5/36; C08K5/37; C08K5/372

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 9 words
The product of claim 1 wherein R is methyl.
Claim 2
Dependent Claim 11 words
The product of claim 1 wherein T and U are hydrogen.
Claim 3
Dependent Claim 13 words
The product of claim 1, wherein R'''' is 2-butene-1,4-ylene, 2-butyne-1,4-ylene, p-xylylene, or p-bis-dimethylenebenzene.
Claim 4
Dependent Claim 9 words
A radical type polyaddition product having the general formula
Claim 5
Dependent Claim 13 words
The product of claim 5, wherein R'''' is 2-butene-1,4-ylene, 2-butyne-1,4-ylene, p-xylylene, or p-bis-dimethylenebenzene.
Claim 6
Dependent Claim 61 words
A radical type polyaddition product having the general formula wherein R is selected from the group consisting of hydrogen and methyl; and R'''' is trimethylene or thio-bis-trimethylene n is an integer; and T and U are each selected from the group consisting of hydrogen, 3-allylthiopropyl, 3-methally-2-methylthiopropyl, and mixtures thereof; said product having a molecular weight of about 500 to about 5,000.
Claim 7
Dependent Claim 8 words
A radical-type polyaddition product having the general formula
Claim 8
Dependent Claim 9 words
The product of claim 8 wherein R'''' is trimethylene.

References Cited (Backward Citations)

US2998346A Cited
US3405181A Cited
US3403187A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-08-22 1976-02-21 1976-08-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-08-22 1980-02-21 1980-08-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-08-22 1984-02-21 1984-08-22 $7700.00 Window Closed / Lapsed

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