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US3681416A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the production of metal chelates

Assignee: Novartis Corp
•
Filing: 1968-10-29
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Granted: 1972-08-01
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Expires: 1988-10-29
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Abstract

Abstract Method for the production of metal chelates by reacting an amino nitrile with sodium or potassium hydroxide and a metal oxide, or metal hydroxide. The metal chelates thus obtained are useful in correcting soil deficiencies and as nutrients for plants.

Inventors

  • 👤 Ralph Miller
  • 👤 Jorg H Hoffmann

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 16:38
CPC Classifications
F; F16; F16B; F16B37/00; F16B37/04; H; H01; H01R; H01R4/00; H01R4/28; H01R4/30

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 18 words
A process according to claim 1, wherein the reaction is conducted at a temperature of about 85* C.
Claim 2
Dependent Claim 17 words
A process according to claim 1, wherein the metal oxide used is zinc oxide or copper oxide.
Claim 3
Dependent Claim 14 words
A process according to claim 1, wherein the metal hydroxide used is calcium hydroxide.
Claim 4
Dependent Claim 29 words
A process according to claim 1, wherein disodium zinc ethylenediamino tetraacetate is obtained by hydrolyzing ethylenediamine tetraacetonitrile with sodium hydroxide followed by reacting the hydrolysis product with zinc oxide.
Claim 5
Dependent Claim 29 words
A process according to claim 1, wherein disodium calcium ethylenediamino tetraacetate is obtained by hydrolyzing ethylenediamine tetraacetonitrile with sodium hydroxide followed by reacting the hydrolysis product with calcium hydroxide.
Claim 6
Dependent Claim 90 words
A process for the preparation of bivalent metal chelates of di-alkali metal salts of ethylenediamine tetraacetic acid which comprises reacting: a. ethylenediamine tetraacetonitrile with b. sodium or potassium hydroxide and c. the oxide or hydroxide of a bivalent metal, said metal being selected from the group consisting of copper, iron, magnesium, manganese, zinc, calcium, nickel and cobalt; the molar ratio of (a):(b):(c) being essentially 1:2:1 and the reaction being effected in an aqueous medium at a temperature of the order of 100*C and being continued to completion of ammonia evolution.

References Cited (Backward Citations)

US3078289A Cited
US3409666A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-08-01 1976-01-31 1976-08-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-08-01 1980-01-31 1980-08-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-08-01 1984-01-31 1984-08-01 $7700.00 Window Closed / Lapsed

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