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US3679944A Expired / Lapsed US ⏱️ 0.0 years remaining

Solid capacitor with electrolyte containing organic material and method for producing same

Assignee: Panasonic Holdings Corp
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Filing: 1971-09-20
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Granted: 1972-07-25
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Expires: 1991-09-20
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Abstract

Abstract A capacitor and method for preparing the same, which includes a solid electrolyte containing a 7,7,8,8-tetracyanoquinodimethane complex and a polymer which does not dissolve the 7,7,8,8tetracyanoquinodimethane complex but disperses the same. The capacitor comprises an oxide coated anode electrode, a cathode electrode spaced from the oxide coated anode electrode and a solid electrolyte containing the 7,7,8,8-tetracyanoquinodimethane complex, and the polymer up to 40 percent by weight of the solid electrolyte and having the 7,7,8,8-tetracyanoquinodimethane complex dispersed therein. The method comprises the steps of preparing an electrode having a dielectric oxide film on its surface and a second electrode, pulverizing a 7,7,8,8tetracyanoquinodimethane complex into fine particles having particle size of 0.1 to 1 Mu m, mixing the fine particles of the 7,7,8,8-tetracyanoquinodimethane complex and a solvent for the polymer for dispersing the fine particles of the tetracyanoquinodimethane complex into a solution by a suitable method, coating the oxide film with the dispersed solution, evaporating the solvent for forming a solid electrolyte layer on the film, and contacting the second electrode to the solid electrolyte layer.

Inventors

  • 👤 Susumu Yoshimura
  • 👤 Yoshimasa Ito
  • 👤 Shirow Asakawa
  • 👤 Katsue Hasegawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 22:30
CPC Classifications
H; H01; H01G; H01G9/00; H01G9/004; H01G9/022; H01G9/025; H01G9/028; H01G11/00; H01G11/22; H01G11/30; H01G11/48; H01G11/54; H01G11/56; Y; Y02; Y02E; Y02E60/00; Y02E60/13

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 18 words
An electrolytic capacitor according to claim 1, wherein said electrolyte further comprises fine particles of a conductive material.
Claim 2
Dependent Claim 14 words
An electrolytic capacitor according to claim 2, wherein said conductive material is carbon black.
Claim 3
Dependent Claim 28 words
An electrolytic capacitor according to claim 1, wherein said 7,7,8,8-tetracyanoquinodimethane complex is in the form of fine particles having particle size of from 0.1 to 1 Mu .
Claim 4
Dependent Claim 24 words
An electrolytic capacitor according to claim 1, wherein said 7,7,8,8-tetracyanoquinodimethane complex is selected from the group consisting of benzidine-7,7,8,8-tetracyanoquinodimethane, p-phenylenediamine-7,7,8,8-tetracyanoquinodimethane, triethylammonium-(7,7,8,8-tetracyanoquinodimethane)2, quinolinium-(7,7,8,8-tetracyanoquinodimethane)2 and methylphenazinium-7,7,8,8-tetracyanoquinodimethane.
Claim 5
Dependent Claim 31 words
An electrolytic capacitor according to claim 1, wherein said polymer is selected from the group consisting of 6-nylon, polyvinylpyrrolidone, cellulose acetate, cellulose propionate, cellulose butylate, polyvinylacetate, polyvinylchloride, polymethylmethacrylate, polybutadiene and polychloroprene.
Claim 6
Independent Claim 115 words
A method for preparing a solid electrolyte capacitor comprising the steps of: preparing an anode electrode having a dielectric film on its surface and a cathode electrode; pulverizing a 7,7,8,8-tetracyanoquinodimethane complex into fine particles having particle sizes of 0.1 to 1 Mu ; mixing the fine particles of the 7,7,8,8-tetracyanoquinodimethane complex, a polymer capable of dispersing the fine particles of the 7,7,8,8-tetracyanoquinodimethane complex and a solvent for the polymer for dispersing the fine particles of the 7,7,8,8-tetracyanoquinodimethane complex into a solution by a suitable method; coating the oxide film with the dispersed solution; evaporating the solvent for forming a solid electrolyte layer on the film; and contacting the cathode electrode to the solid electrolyte layer.
Claim 7
Dependent Claim 64 words
A method according to claim 7, wherein the step of pulverizing the 7,7,8,8-tetracyanoquinodimethane complex comprises: preparing the 7,7,8,8-tetracyanoquinodimethane complex of purified crystals; dissolving the 7,7,8,8-tetracyanoquinodimethane complex in a suitable solvent; heating the solution up to a predetermined temperature; dropping the heated solution into cool liquid of for re-crystallizing the solution; and grinding the resultant crystals into fine particules of 0.1 to 1 Mu sizes.
Claim 8
Dependent Claim 23 words
A method according to claim 7, wherein said 7,7,8,8-tetracyanoquinodimethane complex, polymer and solvent are compoSed of a combination of quinolinium-(7,7,8,8-tetracyanoquinodimethane)2, 6-nylon and ethanol.
Claim 9
Dependent Claim 24 words
A method according to claim 7, wherein said 7,7,8,8-tetracyanoquinodimethane complex, polymer and solvent are composed of a combination of 7,7,8,8-tetracyanoquinodimethane complex, polyvinylpyrrolidone and water.
Claim 10
Dependent Claim 24 words
A method according to claim 7, wherein said 7,7,8,8-tetracyanoquinodimethane complex, polymer and solvent are composed of a combination of 7,7,8,8-tetracyanoquinodimethane complex, polyvinylpyrrolidone and methanol.

References Cited (Backward Citations)

US3214648A Cited
US3214650A Cited
US3483438A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-07-25 1976-01-24 1976-07-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-07-25 1980-01-24 1980-07-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-07-25 1984-01-24 1984-07-25 $7700.00 Window Closed / Lapsed

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