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US3676522A Expired / Lapsed US ⏱️ 0.0 years remaining

Disproportionation and isomerization for isopentane production

Assignee: Chevron USA Inc
•
Filing: 1971-01-18
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Granted: 1972-07-11
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Expires: 1991-01-18
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Abstract

Abstract A process for producing isopentane which comprises: (a) disproportionating a normal butane-rich fraction in a C4 disproportionation zone to obtain C3 and n-pentane; (b) disproportionating a normal hexane-rich fraction in a C6 disproportionation zone to obtain n-pentane and C7; (c) fractionating the C3, nC5 effluent and the nC5, C7 effluent to obtain nC5; and (d) isomerizing at least a portion of the normal pentane from both steps (a) and (b) in an isomerization zone to obtain isopentane. It is preferred to further integrate the disproportionation zones with the isomerization zone using common fractionation facilities.

Inventors

  • 👤 Robert P Sieg

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 11:53
CPC Classifications
C; C07; C07C; C07C9/00; C07C9/14; C07C9/16; C07C9/18; C07C5/00; C07C5/22; C07C5/27; C07C5/2767; C07C5/277; C07C5/2791; C07C6/00; C07C6/08; C07C6/10

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 28 words
A process in accordance with claim 1 wherein common fractionation facilities are used at least in part for effluent hydrocarbons from the disproportionation zones and the isomerization zone.
Claim 2
Dependent Claim 40 words
A process in accordance with claim 1 wherein the same fractionation column is used for the fractionation of normal pentane from C6 alkanes present as a mixture in effluent hydrocarbons from both the isomerization zone and the C6 disproportionation zone.
Claim 3
Dependent Claim 19 words
A process in accordance with claim 1 wherein the isomerization catalyst comprises palladium or platinum with a crystalline aluminosilicate.
Claim 4
Dependent Claim 31 words
A process in accordance with claim 1 wherein the isomerization catalyst comprises 0.05 to 5.0 weight percent palladium and 0.05 to 5.0 weight percent chromium on a layered clay-type crystalline aluminosilicate.
Claim 5
Dependent Claim 49 words
A process in accordance with claim 1 wherein the normal butane and the normal hexane disproportionation reactions are carried out at a temperature between 400* and 850* F. using a catalyst comprising a noble metal on an alumina support and a Group VIB metal compound on a silica support.
Claim 6
Dependent Claim 61 words
A process in accordance with claim 1 wherein the normal butane and normal hexane disproportionation reactions are carried out by a process comprising contacting the C6 alkanes with a catalytic mass comprising platinum on alumina and tungsten or tungsten oxide on silica at a temperature between about 650* and 850* F. and a pressure between about 100 psia and 1,500 psia.
Claim 7
Dependent Claim 23 words
A process in accordance with claim 7 wherein the olefin concentration in the disproportionation reaction zone is maintained below about 5 volume percent.

References Cited (Backward Citations)

US3140253A Cited
US3392212A Cited
US3409682A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-07-11 1976-01-10 1976-07-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-07-11 1980-01-10 1980-07-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-07-11 1984-01-10 1984-07-11 $7700.00 Window Closed / Lapsed

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