Patent FR436123A successfully refreshed from Google Patents.
US3674825A
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Halo(aryl)metal compounds and method of preparation
Assignee: Union Carbide Corp
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Filing: 1969-09-30
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Granted: 1972-07-04
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Expires: 1989-09-30
Abstract
Abstract Halo(aryl)metal compounds are readily produced when a Group VIII metal or a compound or complex of a Group VIII metal is reacted with an aryl halide substituted with electron-withdrawing groups. The compounds have utility as catalysts for the oxidation of methyl benzenes and as intermediates in the arylation of olefins.
Inventors
- 👤 Peter S Fitton
- 👤 Edward A Rick
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 21:07
CPC Classifications
C; C07; C07F; C07F15/00; C07F15/04; B; B01; B01J; B01J31/00; B01J31/16; B01J31/18; B01J31/1845; B01J31/185; B01J31/1865; B01J31/1875; B01J31/24; B01J31/2404; C07F15/0006; C07F15/006; B01J2531/00; B01J2531/80; B01J2531/82; B01J2531/824
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
157 words
A method for producing a halo (aryl) palladium (II) complex having the following structural formula: wherein X is selected from the group consisting of chlorine, bromine, and iodine; L and L'' are the same or different monodentate or bidentate ligands containing phosphorus in the form of phosphine, phosphinite, phosphonite or phosphite radicals, each ligand having up to 36 carbon atoms; a is an integer from 1 to 5 and R is a radical selected from the group consisting of hydrogen, alkyl, alkoxy, aryloxy, amino, nitro, nitroso, cyano, carbonyl, carboalkoxy, carboxamide, N,N-dialkylcarboxamide, N,N-diarylcarboxamide, aryl, aroyl, and halo wherein each R radical can be the same or different with the proviso that the net effect of the R radicals is to lower the electron density of the ring comprising reacting a palladium (O) complex which will provide the ligands defined above with an aryl halide having the following structural formula: wherein X, R, and a are as defined above.
Claim 2
Independent Claim
157 words
A method for producing a halo (aryl) palladium (II) complex having the following structural formula: wherein X is selected from the group consisting of chlorine, bromine, and iodine; L and L'' are the same or different monodentate or bidentate ligands containing phosphorus in the form of phosphine, phosphinite, phosphonite or phosphite radicals, each ligand having up to 36 carbon atoms; a is an integer from 1 to 5 and R is a radical selected from the group consisting of hydrogen, alkyl, alkoxy, aryloxy, amino, nitro, nitroso, cyano, carbonyl, carboalkoxy, carboxamide, N,N-dialkylcarboxamide, N,N-diarylcarboxamide, aryl, aroyl, and halo wherein each R radical can be the same or different with the proviso that the net effect of the R radicals is to lower the electron density of the ring comprising reacting a palladium (O) complex which will provide the ligands defined above with an aryl halide having the following structural formula: wherein X, R, and a are as defined above.
Claim 3
Dependent Claim
10 words
The method of claim 1 wherein said ligand is triphenylphosphine.
Claim 4
Dependent Claim
12 words
The method of claim 1 wherein said aryl halide contains nitro groups.
Claim 5
Dependent Claim
12 words
The method of claim 1 wherein said aryl halide contains nitrile groups.
Claim 6
Dependent Claim
13 words
The method of claim 1 wherein said aryl halide contains additional halo groups.
Claim 7
Dependent Claim
14 words
The method of claim 1 wherein said aryl halide contains carboalkoxy or carboaryloxy groups.
Claim 8
Dependent Claim
14 words
The method of claim 1 wherein said aryl halide contains alkanoyl or aroyl groups.
Claim 9
Dependent Claim
29 words
A complex having the following structural formula: wherein X is selected from the group consisting of chlorine, bromine and iodine and R is selected from the group consisting of
Claim 10
Dependent Claim
29 words
A complex having the following structural formula: wherein X is selected from the group consisting of chlorine, bromine and iodine and R is selected from the group consisting of
Claim 11
Dependent Claim
13 words
A complex according to claim 8 wherein X is chlorine and R is
Claim 12
Dependent Claim
13 words
A complex according to claim 8 wherein X is chlorine and R is
Claim 13
Dependent Claim
13 words
A complex according to claim 8 wherein X is chlorine and R is
Claim 14
Dependent Claim
13 words
A complex according to claim 8 wherein X is chlorine and R is
Claim 15
Dependent Claim
13 words
A complex according to claim 8 wherein X is chlorine and R is
Claim 16
Dependent Claim
13 words
A complex according to claim 8 wherein X is chlorine and R is
Claim 17
Dependent Claim
13 words
A complex according to claim 8 wherein X is chlorine and R is
Claim 18
Dependent Claim
13 words
A complex according to claim 8 wherein X is chlorine and R is
Claim 19
Dependent Claim
13 words
A complex according to claim 8 wherein X is chlorine and R is
Claim 20
Dependent Claim
13 words
A complex according to claim 8 wherein X is chlorine and R is
Claim 21
Dependent Claim
13 words
A complex according to claim 8 wherein X is bromine and R is
Claim 22
Dependent Claim
13 words
A complex according to claim 8 wherein X is bromine and R is
Claim 23
Dependent Claim
13 words
A complex according to claim 8 wherein X is bromine and R is
Claim 24
Dependent Claim
13 words
A complex according to claim 8 wherein X is iodine and R is
References Cited (Backward Citations)
No citation records indexed.
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1975-07-04 | 1976-01-03 | 1976-07-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1979-07-04 | 1980-01-03 | 1980-07-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1983-07-04 | 1984-01-03 | 1984-07-04 | $7700.00 | Window Closed / Lapsed |