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US3674722A Expired / Lapsed US ⏱️ 0.0 years remaining

Microporous structure and method of making the same

Assignee: Philip Morris USA Inc
•
Filing: 1970-08-10
•
Granted: 1972-07-04
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Expires: 1990-08-10
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Abstract

Abstract This disclosure relates to a novel process and to a novel product produced thereby. The product comprises a vinyl chloride polymer having an improved microporous structure and is made by a process which involves dispersing a vinyl chloride polymer latex, i.e., an aqueous suspension of a vinyl chloride polymer, in an organic liquid which is a non-solvent for the polymer, preferably removing most of the water, and heating the resulting dispersion to sinter the vinyl chloride polymer particles to form a microreticulated microporous structure. The vinyl chloride polymer latex may, for example, be a colloidal suspension of polyvinyl chloride particles in water. Such a latex may be obtained commercially or may be prepared by conventional methods. The non-solvent organic liquids should be water-miscible and should have a boiling point above 130* C. and exhibit substantially no solvating or swelling effect on the vinyl chloride polymer. The improved microporous structure of this invention is particularly useful as a filter material. The process of the invention is especially suited for the formation of shaped porous articles which are useful as filters.

Inventors

  • 👤 Norman B Rainer
  • 👤 Peter A Wilson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 13:19
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/28; A; A24; A24D; A24D3/00; A24D3/06; A24D3/08; B; B01; B01D; B01D39/00; B01D39/02; B01D39/04; B01D39/14; B01D39/16; B01D39/1638; B01D39/1653; B01D39/1661; C08J2327/00; Y; Y10; Y10S; Y10S264/00; Y10S264/60

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 37 words
The process of claim 1 wherein said non-solvent is miscible with water and is further characterized by the formula: 1.40 - P1/M < 2.0 wherein P1 and M are the density and viscosity, respectively, of said non-solvent.
Claim 2
Dependent Claim 21 words
The process of claim 1, wherein the nonsolvent is a water-soluble, organic polyhydroxy compound having a boiling point above 130* C.
Claim 3
Dependent Claim 10 words
The process of claim 3, wherein the non-solvent is glycerine.
Claim 4
Dependent Claim 11 words
The process of claim 3, wherein the non-solvent is ethylene glycol.
Claim 5
Dependent Claim 11 words
The process of claim 3, wherein the non-solvent is propylene glycol.
Claim 6
Dependent Claim 11 words
The process of claim 1, wherein the polymer is polyvinyl chloride.
Claim 7
Dependent Claim 31 words
The process of claim 1, wherein the polymer is a copolymer of vinyl chloride and a second vinyl monomer, said copolymer containing at least 60 percent by weight of vinyl chloride.
Claim 8
Dependent Claim 26 words
The process of claim 1, wherein the dispersion contains between 0.3 percent and 8 percent water and between 3 percent and 70 percent vinyl chloride polymer.
Claim 9
Dependent Claim 61 words
The process of claim 1, wherein the water content of the dispersion is reduced by pLacing the dispersion in an environment maintained at a pressure below about 2 mm. of mercury and the resulting dispersion is heated at a temperature of from about 130* C. to about 185* C. for about 15 minutes to about 100 minutes to sinter the resin.
Claim 10
Dependent Claim 27 words
The process of claim 1 wherein the non-solvent is removed from said microporous product by extraction with an aqueous medium in which said water-soluble non-solvent is soluble.

References Cited (Backward Citations)

No citation records indexed.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-07-04 1976-01-03 1976-07-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-07-04 1980-01-03 1980-07-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-07-04 1984-01-03 1984-07-04 $7700.00 Window Closed / Lapsed

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