US3668136A
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Compatible anionic-catonic surfactant compositions
Assignee: Witco Corp
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Filing: 1969-07-07
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Granted: 1972-06-06
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Expires: 1989-07-07
Abstract
Abstract Novel surfactant compositions comprising an anionic surfactant and certain cationic surfactants compatible with same and in the form of quaternary ammonium compounds containing polyoxypropylene groups, said compositions exhibiting imprsved foam and solubilizing characteristics.
Inventors
- 👤 Graham Barker
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 03:30
CPC Classifications
C; C11; C11D; C11D10/00; C11D10/04; C11D10/047; A; A61; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/46; A61K8/463; A61K8/55; A61K8/556; A61K8/72; A61K8/84; A61K8/86; A61Q; A61Q5/00; A61Q5/02; C11D1/00; C11D1/38; C11D1/65; A61K2800/00; A61K2800/40; A61K2800/59; A61K2800/596; C11D1/02; C11D1/04; C11D1/12; C11D1/14; C11D1/22; C11D1/62; Y; Y10; Y10S; Y10S516/00; Y10S516/01; Y10S516/03; Y10S516/05
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
26 words
A composition according to claim 1 wherein the anionic surfactant is selected from the group consisting of alkyl sulfates, alkylaryl sulfonates and fatty carboxylic acid soaps.
Claim 2
Dependent Claim
27 words
A composition according to claim 2 wherein the anionic surfactant is an alkali metal alkyl sulfate wherein the alkyl group contains from eight to 18 carbon atoms.
Claim 3
Dependent Claim
28 words
A composition according to claim 2 wherein the anionic surfactant is an alkali metal alkyl benzene sulfonate wherein the alkyl group contains from eight to 18 carbon atoms.
Claim 4
Dependent Claim
37 words
A composition according to claim 1 in which the R2 radical of said cationic surfactant compound contains a polyoxyethylene radical in which the ethylene oxide constitutes not more than 20 percent by weight of said R2 radical.
Claim 5
Dependent Claim
78 words
A composition according to claim 1 in which the R and R1 radicals of said quaternary ammonium compound are joined togeTher to form with the N atom a cyclic amine containing not more than six carbon atoms, with the proviso that the total number of carbon atoms in R and R1 does not exceed 6; and R2 is polyoxyalkylene containing at least 18 carbon atoms and derived from an Alpha -epoxide containing from three to six carbon atoms.
Claim 6
Dependent Claim
84 words
A composition consisting essentially of a water-soluble anionic surfactant being a member selected from the group consisting of fatty acid soaps, alkyl sulfates, sulfates of polyhydric alcohols partially esterified with a fatty acid, sulfated and sulfonated fatty acid amides and alkanolamides, alkane-sulfonates, ester-, ether- and amide-linked sulfonates, alkylaryl sulfonates and phosphates of aliphatic alcohols and alkyl phenols and from about 20 to 40 percent by weight of a cationic surfactant, based on the weight of combined cationic and anionic surfactants, corresponding to the formula
Claim 7
Dependent Claim
84 words
A composition consisting essentially of a water-soluble anionic surfactant being a member selected from the group consisting of fatty acid soaps, alkyl sulfates, sulfates of polyhydric alcohols partially esterified with a fatty acid, sulfated and sulfonated fatty acid amides and alkanolamides, alkane-sulfonates, ester-, ether- and amide-linked sulfonates, alkylaryl sulfonates and phosphates of aliphatic alcohols and alkyl phenols and from about 20 to 40 percent by weight of a cationic surfactant, based on the weight of combined cationic and anionic surfactants, corresponding to the formula
Claim 8
Dependent Claim
84 words
A composition consisting essentially of a water-soluble anionic surfactant being a member selected from the group consisting of fatty acid soaps, alkyl sulfates sulfates of polyhydric alcohols partially esterified with a fatty acid, sulfated and sulfonated fatty acid amides and alkanolamides, alkane-sulfonates, ester-, ether- and amide-linked sulfonates, alkylaryl sulfonates and phosphates of aliphatic alcohols and alkyl phenols and from about 20 to 40 percent by weight of a cationic surfactant, based on the weight of combined cationic and anionic surfactants, corresponding to the formula
Claim 9
Dependent Claim
84 words
A composition consisting essentially of a water-soluble anionic surfactant being a member selected from the group consisting of fatty acid soaps, alkyl sulfates, sulfates of polyhydric alcohols partially esterified with a fatty acid, sulfated and sulfonated fatty acid amides and alkanolamides, alkane-sulfonates, ester-, ether- and amide-linked sulfonates, alkylaryl sulfonates and phosphates of aliphatic alcohols and alkyl phenols and from about 20 to 40 percent by weight of a cationic surfactant, based on the weight of combined cationic and anionic surfactants, corresponding to the formula
Claim 10
Dependent Claim
84 words
A composition consisting essentially of a water-soluble anionic surfactant being a member selected from the group consisting of fatty acid soaps, alkyl sulfates, sulfates of polyhydric alcohols partially esterified with a fatty acid, sulfated and sulfonated fatty acid amides and alkanolamides, alkane-sulfonates, ester-, ether- and amide-linked sulfonates, alkylaryl sulfonates and phosphates of aliphatic alcohols and alkyl phenols and from about 20 to 40 percent by weight of a cationic surfactant, based on the weight of combined cationic and anionic surfactants, corresponding to the formula
Claim 11
Dependent Claim
84 words
A composition consisting essentially of a water-soluble anionic surfactant being a member selected from the group consisting of fatty acid soaps, alkyl sulfates, sulfates of polyhydric alcohols partially esterified with a fatty acid, sulfated and sulfonated fatty acid amides and alkanolamides, alkane-sulfonates, ester-, ether- and amide-linked sulfonates, alkylaryl sulfonates and phosphates of aliphatic alcohols and alkyl phenols and from about 20 to 40 percent by weight of a cationic surfactant, based on the weight of combined cationic and anionic surfactants, corresponding to the formula
Claim 12
Dependent Claim
226 words
A composition consisting essentially of a water insoluble anionic surfactant being a member selected from the group consisting of fatty acid soaps, alkyl sulfates, sulfates of polyhydric alcohols partially esterified with a fatty acid, sulfated and sulfonated fatty acid amides and alkanolamides, alkane-sulfonates, ester-, ether- and amide-linked sulfonates, alkylaryl sulfonates and phosphates of aliphatic alcohols and alkyl phenols and from about 20 to 40 percent by weight of a cationic surfactant, based on the weight of combined cationic and anionic surfactants, corresponding to the formula where R and R1 are the same or dissimilar alkyls each containing from one to three carbon atoms, R2 is where R3 is alkyl containing from one to four carbon atoms, n is a number up to and including 60, the total number of carbon atoms is R2 being at least 18, v is a number at least 1 with the proviso that the weight ratio of (C2H4-0-)v to R2 is not greater than one to four, X is a member selected from the group consisting of (1) alkyl and alkenyl containing from one to four carbon atoms, and (2) benzene; lower alkyl benzenes in which the lower alkyl contain from one to four carbon atoms, and their methyl and ethyl nuclearly substituted derivatives; and the mono-halo, mono-nitro and mono-sulfonic nuclearly substituted derivatives of the foregoing; and A is an anion.
Claim 13
Dependent Claim
217 words
A composition consisting essentially of a water-soluble anionic surfactant being a member selected from the group consisting of fatty acid soaps, alkyl sulfates, sulfates of polyhydric alcohols partially esterified with a fatty acid, sulfated and sulfonated fatty acid amides and alkanolamides, alkane-sulfonates, ester-, ether- and amide-linked sulfonates, alkylaryl sulfonates and phosphates of aliphatic alcohols and lakyl phenols and from about 20 to alkyl percent by weight of a cationic surfactant, based on the weight of combined cationic and anionic surfactants, corresponding to the formula where R is alkyl containing from one to three carbon atoms, R2 is where R3 is alkyl containing from one to four carbon atoms, n is a number up to and including 60, the total number of carbon atoms in R2 being at least 18, v is a number at least 1 with the proviso that the weight ratio of (C2H4-O-)v to R2 is not greater than one to four, X is a member selected from the group consisting of (1) alkyl and alkenyl containing from one to four carbon atoms, and benzene; lower alkyl benzenes in which the lower alkyls contain from one to four carbon atoms, and their methyl and ethyl nuclearly substituted derivatives; and the mono-halo, mono-nitro and mono-sulfonic nuclearly substituted derivatives of the foregoing; and A is an anion.
Claim 14
Dependent Claim
201 words
A composition consisting essentially of a water-soluble anionic surfactant being a member selected from the group consisting of fatty acid soaps, alkyl sulfates, sulfates of polyhydric alcohols partially esterified with a fatty acid, sulfated and sulfonated fatty acid amides and alkanolamides, alkane-sulfonates, ester-, ether- and amide-linked sulfonates, alkYlaryl sulfonates and phosphates of aliphatic alcohols and alkyl phenols and from about 20 to 40 percent by weight of a cationic surfactant, based on the weight of combined cationic and anionic surfactants, corresponding to the formula where R and R1 are the same or dissimilar alkyls each containing from 1 to 3 carbon atoms, R4-O-R5 is polyoxyethylene-polyoxypropylene containing at least 6 oxypropylene groups and where the weight ratio of the polyoxyethylene to the polyoxypropylene is not greater than one to four, the total number of oxypropylene groups not exceeding 60, X is a member selected from the group consisting of (1) alkyl and alkenyl containing from one four carbon atoms, and (2) benzene; lower alkyl benzenes in which the lower alkyls contain from one to four carbon atoms, and their methyl and ethyl nuclearly substituted derivatives; and the mono-halo, mono-nitro and mono-sulfonic nuclearly substituted derivatives of the foregoing; and A is an anion.
Claim 15
Dependent Claim
194 words
A composition consisting essentially of a water-soluble anionic surfactant being a member selected from the group consisting of fatty acid soaps, alkyl sulfates, sulfates of polyhydric alcohols partially esterified with a fatty acid, sulfated and sulfonated fatty acid amides and alkanolamides. alkane-sulfonates, ester-, ether- and amide-linked sulfonates, alkylaryl sulfonates and phosphates of aliphatic alcohols and alkyl phenols and from about 20 to 40 percent by weight of a cationic surfactant, based on the weight of combined cationic and anionic surfactants, corresponding to the formula where R is alkyl containing from one to three carbon atoms, R4-O-R5 is polyoxyethylene-polyoxypropylene containing at least 6 oxypropylene groups and where the weight ratio of the polyoxyethylene to the polyoxypropylene is not greater than one to four, the total number of oxypropylene groups not exceeding 60, X is a member selected from the group consisting of (1) alkyl and alkenyl containing from one to four carbon atoms, and benzene; lower alkyl benzenes in which the lower alkyls contain from one to four carbon atoms, and their methyl and ethyl nuclearly substituted derivatives; and the mono-halo, mono-nitro and mono-sulfonic nuclearly substituted derivatives of the foregoing; and A is an anion.
Claim 16
Dependent Claim
98 words
A composition consisting essentially of a water-soluble anionic surfactant being a member selected from the group consisting of fatty acid soaps, alkyl sulfates, sulfates of polyhydric alcohols partially esterified with a fatty acid, sulfated and sulfonated fatty acid amides and alkanolamides, alkane-sulfonates, ester-, ether- and amide-linked sulfonates, alkylaryl sulfonates and phosphates of aliphatic alcohols and alkyl phenols and from about 20 to 40 percent by weight of a cationic surfactant, based on the weight of combined cationic and anionic surfactants, corresponding to the formula where R is an alkyl containing from one to three carbon atoms R2 is
Claim 17
Dependent Claim
170 words
A composition consisting essentially of a water-soluble anionic surfactant being a member selected from the group consisting of fatty acid soaps, alkyl sulfates, sulfates of polyhydric alcohols partially esterified with a fatty acid, sulfated and sulfonated fatty acid amides and alkanolamides, alkane-sulfonates, ester-, ether- and amide-linked sulfonates, alkylaryl sulfonates and phosphates of aliphatic alcohols and alkyl phenols and from about 20 to 40 percent by weight of a cationic surfactant, based on the weight of combined cationic and anionic surfactants, corresponding to the formula where R is alkyl containing from one to three carbon atoms, R2 is and n totals a number from 8 to 30, X is a member selected from the group consisting of (1) alkyl and alkenyl containing from one to four carbon atoms, and (2) benzene; lower alkyl benzenes in which the lower alkyls contain from one to four carbon atoms, and their methyl and ethyl nuclearly substituted derivatives; and the mono-halo, mono-nitro and mono-sulfonic nuclearly substituted derivatives of the foregoing; and A is an anion.
Claim 18
Dependent Claim
179 words
A composition consisting essentially of a water-soluble anionic surfactant being a member selected from the group consisting of fatty acid soaps, alkyl sulfates, sulfates of polyhydric alcohols partially esterified with a fatty acid, sulfated and sulfonated fatty acid amides and alkanolamides, alkane-sulfonates, ester-, ether- and amide-linked sulfonates, alkylaryl sulfonates and phosphates of aliphatic alcohols and alkyl phenols and from about 20 to 40 percent by weight of a cationic surfactant, based on the weight of combined cationic and anionic surfactants, corresponding to the formula where R is alkyl containing from one to three carbon atoms, R2 alkyl containing from one to three carbon atoms, R2 is and n totals a number from 8 to 30, X is a member selected from the group consisting of (1) alkyl and alkenyl containing from one to four carbon atoms, and (2) benzene; lower alkyl benzenes in which the lower alkyls contain from one to four carbon atoms, and their methyl and ethyl nuclearly substituted derivatives; and the mono-halo, mono-nitro and mono-sulfonic nuclearly substituted derivatives of the foregoing; and A is an anion.
Claim 19
Dependent Claim
84 words
A composition consisting essentially of a water-soluble anionic surfactant being a member selected from the group consisting of fatty acid soaps, alkyl sulfates, sulfates of polyhydric alcohols partially esterified with a fatty acid, sulfated and sulfonated fatty acid amides and alkanolamides, alkane-sulfonates, ester-, ether- and amide-linked sulfonates, alkylaryl sulfonates and phosphates of aliphatic alcohols and alkyl phenols and from about 20 to 40 percent, by weight of a cationic surfactant, based on the weight of combined cationic and anionic surfactants, corresponding to the formula
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1975-06-06 | 1975-12-06 | 1976-06-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1979-06-06 | 1979-12-06 | 1980-06-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1983-06-06 | 1983-12-06 | 1984-06-06 | $7700.00 | Window Closed / Lapsed |