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US3661592A Expired / Lapsed US ⏱️ 0.0 years remaining

Photographic fine grain silver halide materials

Assignee: Agfa Gevaert NV
•
Filing: 1970-10-02
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Granted: 1972-05-09
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Expires: 1990-10-02
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Abstract

Abstract A method of preparing a photographic fine-grain silver halide emulsion is described wherein precipitation of the silver halide occurs in the presence of a compound corresponding to the formula: WHEREIN Z represents the atoms necessary to complete an imidazole, benzimidazole or naphthimidazole nucleus; Q is sulphur or selenium; R is hydrogen, C1-C4 alkyl or aryl, A is alkylene, which may be interrupted by hetero atoms, -S-alkylene which may be interrupted by hetero atoms, or arylene and X is alkyl, alkenyl or aryl or A and X together with Q represent the atoms necessary to complete a non-nitrogen containing heterocycle. By the presence of these compounds during precipitation of the silver halide homogeneous Lippmann-emulsions can be prepared with an average grain-size of less than 50 nm.

Inventors

  • 👤 Herman Adelbert Philippaerts
  • 👤 Robert Joseph Pollet
  • 👤 Jozef Frans Williems
  • 👤 Frans Henri Claes

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 14:47
CPC Classifications
C; C07; C07D; C07D235/00; C07D235/02; C07D235/04; C07D235/06; C07D235/18; C07D235/24; C07D235/28; G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/08; G03C1/09; G03C1/34; G03C1/346

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 36 words
Method according to claim 1, wherein said compound is present in the aqueous hydrophilic colloid medium into which the silver halide is precipitated in an amount sufficient to effectively restrain growth of the silver halide grains.
Claim 2
Dependent Claim 28 words
Method according to claim 1 wherein the emulsion is a silver bromide, silver chloride or a silver chlorobromide emulsion which may comprise a minor amount of silver iodide.
Claim 3
Dependent Claim 29 words
A photographic fine-grain silver halide emulsion prepared by precipitating the silver halide in an aqueous hydrophilic colloid medium in the presence of a compound corresponding to the formula :

References Cited (Backward Citations)

US3156564A Cited
US3255202A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-05-09 1975-11-08 1976-05-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-05-09 1979-11-08 1980-05-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-05-09 1983-11-08 1984-05-09 $7700.00 Window Closed / Lapsed

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