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US3659652A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid explosive for well fracturing

Assignee: Talley Frac Corp
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Filing: 1971-01-27
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Granted: 1972-05-02
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Expires: 1991-01-27
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Abstract

Abstract A cap insensitive liquid explosive is described which is particularly useful for fracturing a formation containing a network of narrow fissures adjacent a well bore in order to bring in a well or to increase its productivity, which includes a nitroparaffin compound, preferably nitromethane, capable of dissolving substantial amounts of high explosive compounds, and one or more of certain high explosive compounds dissolved therein. The high explosive compounds are of a kind and are present in an amount capable of rendering the liquid explosive sufficiently diameter insensitive to permit propagation of an explosion throughout a substantial portion of such network of narrow fissures when the liquid explosive is placed therein or in such other environment as it is to be used. Preferred high explosives are RDX, HMX and mixtures thereof. TNT, PETN or any other high explosive organic nitro compound may be included in an amount sufficient to render the liquid explosive less sensitive to detonation, such that it is not cap detonable, at the same time enhancing its explosive power and reliability. For certain applications, ammonium nitrate may be added to achieve desired explosive effects, as well as finely divided reactive metal to increase the brisance of the explosive. A gelling agent such as nitrocellulose is included to maintain the resulting uniform dispersion for long periods of time. A method of pressuretransferring a liquid explosive into the well bore and pressuring it back into the productive formation is described in which the explosive is injected through a tube into the well bore directly adjacent the formation to be fractured, the tube having first been cleared of air, by placing the liquid explosive in one or more tanks connected to the injection tube at the well surface and which are subjected to air pressure to force the explosive into the well. Further, a well fracturing method which is self cleaning, rendering unnecessary the usual cleaning step which follows fracturing, is disclosed in which the well bore is restricted above the level of the explosion and is closed above the restriction with sand or the like such that sufficient back pressure is maintained in the well for satisfactory fracturing, while the resultant gases are subsequently vented through the restriction, blowing the sand or other ballast as well as the rubble generated by the explosion out of the well bore.

Inventors

  • 👤 Leonard N Roberts

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 21:35
CPC Classifications
E; E21; E21B; E21B43/00; E21B43/25; E21B43/26; E21B43/263; C; C09; C09K; C09K8/00; C09K8/60; C09K8/80

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 241 words
A method of safely pressure-transferring a liquid explosive into a well bore for explosively fracturing the productive strata of the well, such that the liquid explosive is not subject to the possibility of accidental detonation by contact with pumps and similar machinery, comprising placing the liquid explosive in a tank located at the surface and connected to communicate directly with the well bore through an injection tube which extends down into the well bore terminating at a point adjacent the formation to be fractured so as to prevent globulation and mixing of the explosive with well fluids in the bore; and applying pressure over the liquid explosive within the tank greater than the pressure exerted by the well tending to force explosive upward into said tank by an amount sufficient to force the liquid explosive through the injection tube into the well bore; said method including the provision of a second tank connected to the injection tube and the provision of valves between each tank and the injection tube, including filling the second tank with liquid explosive while the first tank is being emptied of its contents, and then disconnecting the first tank from the injection tube and connecting the second tank to the injection tube by their respective valves and applying pressure over the liquid explosive in the second tank to force it down through the injection tube into the well bore, while refilling the first tank with liquid explosive.
Claim 2
Dependent Claim 77 words
A method as defined in claim 2 wherein the outlet end of the injection tube is closed, the sides of the tube adjacent said end being provided with slits permitting outflow from the injection tube of liquid explosive, including placing a wiper plug having a length substantially less than the length of said slits in the injection tube before injecting liquid explosive therethrough in order to prevent mixing between air or well fluids and the liquid explosive.
Claim 3
Dependent Claim 137 words
A method as defined in claim 3 for pressurizing the liquid explosive back into the productive strata, which strata have been hydraulically or similarly fractured to create a network of fine fissures therein, including after the liquid explosive has been pressure-transferred into the well bore, disconnecting said tanks from the injection tube; inserting into the injection tube a second wiper plug such that the combined lengths of the first and second wiper plugs are greater than the length of the slits at the outlet end of the injection tube; seating a packing plug in the well bore above the productive strata in order to seal off the well bore; and pumping water into the injection tube under pressure sufficient to force the liquid explosive through the injection tube and back into the fissures in the productive strata.
Claim 4
Dependent Claim 60 words
A method as defined in claim 4 including removing said packing plug, after the pressures within the well bore have substantially attained equilibrium; placing a timed explosive detonator within the liquid explosive remaining in the well bore; and sealing the well bore by seating a packing plug therein and filling the bore with water above and below the packing plug.
Claim 5
Dependent Claim 126 words
A self cleaning method for explosively fracturing a well as defined in claim 4, comprising filling the well bore above the liquid explosive with enough water to substantially counterbalance the bottom pressure existing in the well; placing a restriction in the well bore above the level of said water; sealing said restriction from above in order to prevent matter from falling down therethrough; and loading ballast into the well bore above the restriction, the amount of ballast and the size of the restriction being such as to create sufficient pressure within the well bore, upon detonation, to achieve the desired fracturing while permitting gases generated by the explosion to blow the rubble created thereby as well as the ballast up and out of the well bore.
Claim 6
Dependent Claim 189 words
A self cleaning method of explosively fracturing a well in order to bring in the well or to increase its productivity, the productive strata of said well having been hydraulically or similarly fractured in order to create a network of fine fissures therein, comprising: loading liquid explosive into the well bore and pressuring a portion thereof back into the productive strata; placing an explosive detonator within the liquid explosive remaining in the well bore; filling the well bore above the liquid explosive with water in an amount sufficient to balance the bottom pressure of the well; placing a restriction in the well bore above the level of said water; placing a seal above said restriction in order to prevent material from falling down therethrough; and loading ballast into the well bore above the restriction, the size of the restriction and the amount of ballast being such that, upon detonation, sufficient pressure is developed within the productive strata to achieve the desired fracturing, yet the gases generated by the explosion are capable of forcing the rubble created thereby as well as the ballast up and out of the well bore.
Claim 7
Dependent Claim 91 words
Apparatus for pressure-transferring liquid explosive into a well bore to fracture the productive strata thereof, comprising: an injection tube extending down into the well bore to the level of the productive strata; at least two pressure tanks at the surface of the well, each pressure tank being connected through a valve to the injection tube; and means including an air pressure source connectable to each pressure tank for selectively placing said source in communication with each tank to force liquid explosive placed therein through the injection tube into the productive strata.
Claim 8
Dependent Claim 58 words
Apparatus as defined in claim 8, said injection tube being closed at its lower end and having slots in its periphery about said lower end to permit flow therethrough of liquid explosive, said slits being sufficiently long to permit flow of liquid explosive after a wiper plug has been lodged in the lower end of the injection tube.
Claim 9
Dependent Claim 159 words
A self-cleaning method of explosively fracturing a well in order to bring in the well or to increase its productivity, the productive strata of said well having been hydraulically or similarly fractured in order to create a network of fine fissures therein, comprising: loading liquid explosive into the well bore and pressuring a portion thereof back into the productive strata; placing an explosive detonator within the liquid explosive remaining in the well bore; filling the well bore above the liquid explosive with fluid; and placing a tamp in the well bore above the level of the liquid explosive, which tamp includes a supporting bridge in the well bore and ballast supported thereon, said bridge and ballast being such as to create sufficient pressure within the productive strata, upon detonation, to achieve the desired fracturing while permitting gases generated by the explosion to blow the rubble created thereby as well as the ballast up and out of the well bore.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-05-02 1975-11-01 1976-05-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-05-02 1979-11-01 1980-05-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-05-02 1983-11-01 1984-05-02 $7700.00 Window Closed / Lapsed

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