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US3653833A Expired / Lapsed US ⏱️ 0.0 years remaining

Processing of sulfur dioxide

Assignee: Honeywell International Inc
•
Filing: 1969-12-09
•
Granted: 1972-04-04
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Expires: 1989-12-09
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Abstract

Abstract Invention relates to a method for the reduction of sulfur dioxide with a reducing gas to elemental sulfur and/or other gaseous sulfur compounds in the presence of a catalyst and at a temperature within the range from 1,000* to 2,400* F., by passing a gaseous reaction mixture of a sulfur-dioxide containing gas with a reducing gas first through a contact chamber maintained at a temperature sufficient to raise the temperature of the mixture to 1,000* to 2,400* F., passing said heated gaseous reaction mixture through a reaction chamber containing a catalyst to produce a mixture comprising hydrogen sulfide, sulfur dioxide and sulfur, passing said product through a contact chamber containing contact means sufficient to absorb heat from said product stream to reduce the temperature of the product stream to about 700* to 800* F. and recovering the cooled product stream; said contact chambers being subjected to continuous alternating heat absorbing cycles while maintaining during the alternating cycles of the contact chambers the passage of the gaseous reaction mixture through the reaction chamber in the same direction through the catalyst bed.

Inventors

  • 👤 William E Watson
  • 👤 Donald A Aubrecht

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 13:54
CPC Classifications
C; C01; C01B; C01B17/00; C01B17/02; C01B17/04; C01B17/0473; B; B01; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/8603; B01D53/8609

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 35 words
The process of claim 1 wherein said gaseous reaction mixture increases in temperature up to about 300* F. as it passes through the reaction chamber during conversion of the mixture to an equilibrium product stream.
Claim 2
Dependent Claim 15 words
The process of claim 1 wherein the cycles alternate about every 100 to 3,000 seconds.
Claim 3
Dependent Claim 34 words
The process of claim 1 wherein the conditions in the reaction chamber are sufficient to effect chemical equilibrium and to produce an equilibrium product stream consisting essentially of hydrogen sulfide, sulfur dioxide and sulfur.
Claim 4
Dependent Claim 12 words
The process of claim 1 wherein the reducing catalyst is calcium aluminate.
Claim 5
Dependent Claim 31 words
The process of claim 1 wherein the gaseous reducing agent is selected from the group consisting of hydrogen, carbon monoxide, a mixture of hydrogen and carbon monoxide and a gaseous hydrocarbon.
Claim 6
Dependent Claim 12 words
The process of claim 6 wherein the reducing agent is carbon monoxide.
Claim 7
Dependent Claim 33 words
The process of claim 6 wherein the reducing agent is a gaseous hydrocarbon selected from the group consisting of natural gas and a low molecular weight hydrocarbon of one to four carbon atoms.
Claim 8
Dependent Claim 12 words
The process of claim 8 wherein the gaseous hydrocarbon is natural gas.
Claim 9
Dependent Claim 11 words
The process of claim 8 wherein the gaseous hydrocarbon is methane.
Claim 10
Dependent Claim 23 words
The process of claim 10 wherein the ratio of sulfur dioxide to methane is in the range of 1.33 to 2.0 to 1.
Claim 11
Dependent Claim 43 words
The process of claim 4 wherein the gaseous reaction mixture is passed through the catalyst in the reaction chamber at a superficial linear gas velocity of from 1/3 to 30 feet per second and a contact time of about 1/4 to 7 seconds.
Claim 12
Dependent Claim 23 words
The process of claim 1 wherein the temperature in the reaction chamber is maintained within the range of about 1,500* to 2,400* F.
Claim 13
Dependent Claim 252 words
A continuous method for the preparation of the equilibrium products of the reduction of sulfur dioxide with a gaseous reducing agent which comprises the steps of heating a gaseous reaction mixture comprising a sulfur dioxide-containing gas and a gaseous reducing agent selected from the group coNsisting of hydrogen, carbon monoxide, a mixture of hydrogen and carbon monoxide, and a gaseous hydrocarbon to a temperature of from 1, 000* to 2,400* F. by passing said gaseous reaction mixture through a first contact chamber wherein said gaseous mixture is heated by a contact mass in said chamber maintained at a temperature sufficient to raise the temperature of said gaseous mixture to about 1,000* to 2,400* F., passing said heated gaseous reaction mixture through a reaction chamber containing a catalytic material at a superficial linear gas velocity through the catalyst of from 1/3 to 30 feet per second and a contact time of about 1/4 to 7 seconds to produce an equilibrium product stream consisting essentially of hydrogen sulfide, sulfur dioxide and sulfur, passing said equilibrium product stream through a second contact chamber containing contact means sufficient to absorb heat from said product stream to reduce the temperature of the product stream to about 700* to 800* F., and recovering said cooled equilibrium product stream; said contact chambers being subjected to continuous alternating heat absorbing cycles while maintaining during the alternating cycles of the contact chambers the passage of the gaseous reaction mixture through the reaction chamber in the same direction through the catalyst bed.

References Cited (Backward Citations)

US2050708A Cited
US2431236A Cited
US2672671A Cited
US3199955A Cited
US3495941A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-04-04 1975-10-04 1976-04-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-04-04 1979-10-04 1980-04-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-04-04 1983-10-04 1984-04-04 $7700.00 Window Closed / Lapsed

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