US3644446A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Preparation of rhodium and iridium hydride carbonyl complexes
Assignee: Union Oil Company of California
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Filing: 1969-07-01
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Granted: 1972-02-22
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Expires: 1989-07-01
Abstract
Abstract HYDRIDE CARBONYL COMPLEXES OF RHODIUM AND IRIDIUM WITH BIPHYLIC LIGANDS ARE PREPARED BY TREATMENT OF RHODIUM OR IRIDIUM, COMPLEXES OR SALTS THEREOF WITH AN ALKALI METAL HYDROXIDE, ALKOXIDE OR ARYLOXIDE AND A BIPHYLLIC LIGAND AND A MIDL REDUCING AGENT. IN A TYPICAL SYNTHESIS A RHODIUM CARBONYL SALT IS CONTACTED WITH AN ALKALI METAL ALKOXIDE IN THE PRESENCE OF THE LIGAND AND THE HYDRIDE IS FORMED BY SUBSEQUENT OR SIMULTANEOUS CONTACTING WITH A REDUCING AGENT SUCH AS HYDROGEN, CARBON MONOXIDE OR AN OXIDIZABLE ALCOHOL. THE COMPOUNDS HAVE UTILITY AS HYDROFORMYLATION CATALYSTS.
Inventors
- 👤 Frank B Booth
- 👤 Donald M Fenton
- 👤 Kenneth L Olivier
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 04:26
CPC Classifications
C; C07; C07C; C07C45/00; C07C45/49; C07C45/50; C07F; C07F15/00; C07F9/00; C07F9/66; C07F9/70; C07F9/90; C07F9/94
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References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1975-02-21 | 1975-08-23 | 1976-02-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1979-02-21 | 1979-08-23 | 1980-02-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1983-02-21 | 1983-08-23 | 1984-02-22 | $7700.00 | Window Closed / Lapsed |